Chemical Communications,
Год журнала:
2019,
Номер
55(53), С. 7599 - 7602
Опубликована: Янв. 1, 2019
Photoredox
catalysis,
using
an
organic
photocatalyst
and
silanol
reagent,
enables
the
metal-free
generation
of
aryl
radicals
to
synthesize
diverse
gem-difluoroalkenes.
Angewandte Chemie International Edition,
Год журнала:
2020,
Номер
60(22), С. 12170 - 12191
Опубликована: Сен. 17, 2020
Due
to
their
unique
properties,
fluorinated
scaffolds
are
pivotal
compounds
in
pharmaceuticals,
agrochemicals,
and
materials
science.
Over
the
last
years,
development
of
versatile
strategies
for
selective
synthesis
molecules
by
direct
C-H
bond
functionalization
has
attracted
a
lot
attention.
In
particular,
design
novel
transformations
based
on
radical
process
was
bottleneck
distal
reactions,
offering
synthetic
solutions
introduction
groups.
This
Minireview
highlights
major
contributions
this
blossoming
field.
The
new
methodologies
remote
aliphatic
derivatives
with
various
groups
1,5-hydrogen
atom
transfer
β-fragmentation
reaction
will
be
showcased
discussed.
Chemical Communications,
Год журнала:
2019,
Номер
55(53), С. 7599 - 7602
Опубликована: Янв. 1, 2019
Photoredox
catalysis,
using
an
organic
photocatalyst
and
silanol
reagent,
enables
the
metal-free
generation
of
aryl
radicals
to
synthesize
diverse
gem-difluoroalkenes.
