Selective production of linear α-olefins via catalytic deoxygenation of fatty acids and derivatives

Catalysis Science & Technology, Год журнала: 2018, Номер 8(6), С. 1487 - 1499

Опубликована: Янв. 1, 2018

Various homogeneous, heterogeneous, and enzyme catalysis strategies for the selective synthesis of linear α-olefins from fatty acids their derivatives are reviewed.

Язык: Английский

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Modular Access to Eight‐Membered N‐Heterocycles by Directed Carbonylative C−C Bond Activation of Aminocyclopropanes

Angewandte Chemie International Edition, Год журнала: 2019, Номер 58(52), С. 18844 - 18848

Опубликована: Окт. 4, 2019

Aminocyclopropanes equipped with pendant nucleophiles undergo carbonylative heterocyclization triggered by C-C bond activation to generate eight-membered N-heterocycles. In these processes, intramolecular "capture" of a rhodacyclopentanone intermediate an aryl or N-based nucleophile is followed C-N bond-forming "collapse" the targets. These studies demonstrate how combination cyclopropane strain release and templating effect catalytically generated metallacycles can be harnessed enable otherwise challenging medium ring closures.

Язык: Английский

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N-Arylation of (hetero)arylamines using aryl sulfamates and carbamatesviaC–O bond activation enabled by a reusable and durable nickel(0) catalyst

New Journal of Chemistry, Год журнала: 2020, Номер 44(31), С. 13266 - 13278

Опубликована: Янв. 1, 2020

An effective and general aryl amination protocol has been developed using a magnetically recoverable Ni(0) based nanocatalyst.

Язык: Английский

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Two-step one-pot Johnson-Claisen rearrangement/hydroformylation of renewable feedstocks

Journal of Catalysis, Год журнала: 2025, Номер 443, С. 115955 - 115955

Опубликована: Янв. 9, 2025

Язык: Английский

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Advances in catalysis using Xantphos-like ligands; simplicity goes a long way

Coordination Chemistry Reviews, Год журнала: 2025, Номер 537, С. 216636 - 216636

Опубликована: Апрель 11, 2025

Язык: Английский

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