Metal-organic
polyhedra
(MOPs)
are
a
subclass
of
coordination
cages
that
can
adsorb
and
host
species
in
solution
permanently
porous
solid-state.
These
characteristics,
together
with
the
recent
development
their
orthogonal
surface
chemistry
assembly
more
stable
cages,
have
awakened
latent
potential
MOPs
to
be
used
as
building
blocks
for
synthesis
extended
networks.
This
review
article
focuses
on
exploring
key
developments
make
extension
possible,
highlighting
most
remarkable
examples
MOP-based
soft
materials
crystalline
frameworks.
Finally,
ventures
offer
future
perspectives
exploitation
fields
still
remain
ripe
toward
use
such
unorthodox
molecular
platforms.
Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(17), С. 10539 - 10553
Опубликована: Янв. 1, 2024
The
effective
containment
and
storage
of
iodine
is
important,
fulfilling
both
the
roles
managing
nuclear
waste
ensuring
safe
utilization
radioactive
isotopes
in
medicine.
Porous
aromatic
frameworks
(PAFs)
are
a
fundamental
group
of
porous
materials
characterized
by
their
distinct
structural
features
and
large
surface
areas.
These
synthesized
from
building
units
linked
strong
carbon–carbon
bonds,
which
confer
exceptional
rigidity
long-term
stability.
PAFs
functionalities
may
arise
directly
the
intrinsic
chemistry
or
through
postmodification
motifs
using
well-defined
chemical
processes.
Compared
to
other
traditional
such
as
zeolites
metallic-organic
frameworks,
demonstrate
superior
stability
under
severe
treatments
due
robust
bonding.
Even
in
challenging
environments,
ease
functionalization
flexibility
specificity.
Research
on
has
significantly
expanded
accelerated
over
past
decade,
necessitating
comprehensive
overview
key
advancements
this
field.
This
review
provides
an
in-depth
analysis
recent
advances
synthesis,
functionalization,
dimensionality
PAFs,
along
with
distinctive
properties
wide-ranging
applications.
explores
innovative
methodologies
strategies
for
functionalizing
structures,
manipulation
tailor
specific
potential
Similarly,
application
areas,
including
batteries,
absorption,
sensors,
CO2
capture,
photo-/electrocatalytic
usages,
supercapacitors,
separation,
biomedical
discussed
detail,
highlighting
versatility
addressing
modern
scientific
industrial
challenges.
International Materials Reviews,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 3, 2025
The
extracellular
matrix
can
be
replicated
by
3D
scaffolds,
providing
a
favorable
environment
for
cell
growth,
proliferation,
and
differentiation.
Despite
their
biocompatibility,
biodegradability,
bioactivity,
the
poor
mechanical
strength
of
scaffolds
limits
use
heavy
loads.
This
creates
bottleneck
in
supply
with
enhanced
all
previously
mentioned
characteristics.
Conjugated
polymers
have
emerged
as
promising
option
scaffold
construction
due
to
electrical
conductivity,
adjustable
surface
qualities,
ability
transfer
bioactive
molecules.
Moreover,
metal-organic
frameworks
(MOFs)
are
rapidly
emerging
class
nanomaterials
uniform
porosity,
excellent
surface-to-volume
ratio,
variable
diverse
configurations,
well
tuanble
chemical
structures.
While
both
conjugated
polymer-based
MOF-based
suffer
from
drawbacks
such
low
stability
possible
toxicity,
combination
is
an
imperative
strategy
construct
desirable
scaffols
biomedical
applications.
Specific
examples
investigated
polymer-MOF
provided
each
area,
along
explanation
synthesis,
fabrication
method,
physicochemical
properties.
Finally,
applications
polymers/MOF
tissue
engineering
cancer
theragnostic
reviewed,
current
challenges
potential
future
directions
discussed.
Journal of Separation Science,
Год журнала:
2021,
Номер
45(1), С. 282 - 304
Опубликована: Ноя. 20, 2021
Abstract
The
materials
used
for
the
fabrication
of
solid‐phase
microextraction
fiber
coatings
in
past
five
years
are
summarized
current
review,
including
carbon,
metal‐organic
frameworks,
covalent
organic
aerogel,
polymer,
ionic
liquids/poly
(ionic
liquids),
metal
oxides,
and
natural
materials.
preparation
approaches
different
coatings,
such
as
sol‐gel
technique,
in‐situ
growth,
electrodeposition,
glue
methods,
briefly
reviewed
together
with
evolution
supporting
substrates.
In
addition,
limitations
future
development
directions
presented.
Advanced Energy Materials,
Год журнала:
2021,
Номер
11(43)
Опубликована: Авг. 1, 2021
Abstract
Solar
energy
conversion
plays
a
very
important
role
in
the
transition
to
more
sustainable
system.
In
this
sense,
so
many
systems
have
been
proposed
drive
artificial
photosynthesis,
most
of
them
based
on
inorganic
semiconductors,
and
achievements
performed
continue
every
day.
However,
these
present
well‐known
shortcomings
as
low
light
absorption,
fast
charge
recombination,
lack
tunability,
thus
limiting
their
efficiency.
The
use
organic
polymers
general
conjugated
porous
(CPPs)
particular,
opens
door
multitude
new
possibilities
when
it
comes
design
selection
suitable
photocatalyst.
CPPs
exhibit
improved
harvesting,
conduction
properties,
high
photochemical
stability,
surface
area
that
make
ideal
for
photocatalytic
applications.
Here,
hybrids
photocatalysts
solar
hydrogen
evolution
reaction
CO
2
reduction
its
photoelectrode
are
reviewed.
properties
focused
upon
here.
photophysics
related
applications
is
also
discussed.
Finally,
perspective
provided,
proposing
an
situ
operando
characterization
methodology
expected
allow
improvements
optoelectronic
thereby
future
applicability.
ACS Applied Materials & Interfaces,
Год журнала:
2022,
Номер
14(5), С. 7369 - 7381
Опубликована: Янв. 28, 2022
Nanostructured
hypercrosslinked
porous
organic
polymers
have
triggered
immense
research
interest
for
a
broad
spectrum
of
applications
ranging
from
catalysis
to
molecular
separation.
However,
it
still
remains
challenge
tune
their
nanoscale
morphology.
Herein,
we
demonstrated
remarkable
variation
morphologies
triptycene-based
microporous
starting
irregular
aggregates
(FCTP)
rigid
spheres
(SCTP)
two-dimensional
nanosheets
(SKTP)
three
distinct
polymerization
methodologies,
Friedel-Crafts
knitting
using
an
external
crosslinker,
Scholl
reaction,
and
solvent
knitting,
respectively.
Further,
the
dramatic
role
reaction
temperatures,
catalysts,
solvents
resulting
in
well-defined
was
elucidated.
Mechanistic
investigations
coupled
with
microscopic
computational
studies
revealed
evolution
2D
highly
solvent-knitted
polymer
(SKTP,
2385
m2
g-1),
sequential
hierarchical
self-assembly
nanospheres
nanoribbons.
A
structure-activity
correlation
sulfonated
counterparts
removal
toxic
polar
micropollutants
water
delineated
based
on
chemical
functionalities,
specific
surface
area,
pore
size
distribution,
dispersity,
Furthermore,
sheet-like
(SKTPS)
exhibited
rapid
adsorption
kinetics
(within
30
s)
large
array
micropollutants,
including
plastic
components,
steroids,
antibiotic
drugs,
herbicides,
pesticides
uptake
capacity
excellent
recyclability.
The
current
study
provides
impetus
designing
morphology-controlled
functionalized
task-specific
applications.
Advanced Functional Materials,
Год журнала:
2021,
Номер
31(33)
Опубликована: Июнь 8, 2021
Abstract
Conjugated
microporous
polymers
(CMPs)
are
a
unique
class
of
porous
materials
that
have
an
integrated
π‐conjugated
system
and
permanent
intrinsic
porosity.
They
great
interest
because
their
outstanding
performance
in
gas
sorption,
photoredox
catalysis,
energy
storage,
organic
light‐emitting
diodes
(OLEDs),
sensing
applications.
However,
conventional
chemically
synthesized
CMPs
solid
powders
poor
solubility,
which
makes
it
difficult
to
process
integrate
devices,
has
become
bottleneck
preventing
practical
Electropolymerization
(EP)
is
simple
efficient
method
for
the
preparation
CMP
films,
simultaneously
completes
material
synthesis
film
processing.
More
importantly,
microstructure
films
can
be
effectively
controlled
by
electrochemical
parameters.
In
this
review,
first,
basic
synthetic
principles
strategies
via
EP
introduced,
allowing
facile
optimization
structure
properties.
Then,
recent
progress
focused
upon
electronics,
sensors,
chemical
capture
separation,
electrocatalysts.
Finally,
challenges
outlook
addressed.
Chemical Society Reviews,
Год журнала:
2022,
Номер
51(3), С. 1124 - 1138
Опубликована: Янв. 1, 2022
A
detailed
physicochemical
explanation
for
experimental
observations
is
provided
POPs
as
powerful
photocatalysts
organic
transformations
and
wastewater
decontamination.
