Advances in Colloid and Interface Science,
Год журнала:
2023,
Номер
314, С. 102864 - 102864
Опубликована: Фев. 26, 2023
Designable
morphology
and
predictable
properties
are
the
most
challenging
goals
in
material
engineering.
Features
such
as
shape,
size,
porosity,
agglomeration
ratio
significantly
affect
final
of
metal-organic
frameworks
(MOFs)
can
be
regulated
throughout
synthesis
parameters
but
require
a
deep
understanding
mechanisms
MOFs
formation.
Herein,
we
systematically
summarize
effects
individual
factors,
pH
reaction
mixture,
including
acidic
or
basic
character
modulators,
temperature,
solvents
types,
surfactants
type
content
ionic
liquids
on
growing
MOFs.
We
identified
main
MOFs'
growth
leading
to
different
particles
next
discuss
effect
miscellaneous
based
related
nucleation,
formation
structure,
coordination
modulation,
protonation/deprotonation
acting
modulation
by
capping
agents.
The
microwaves
ultrasound
employment
during
is
also
considered
due
their
affecting
especially
nucleation
steps
Advanced Materials Technologies,
Год журнала:
2021,
Номер
6(3)
Опубликована: Фев. 4, 2021
Abstract
In
the
era
of
Internet
Things,
wearable
technologies
are
expected
to
become
an
indispensable
part
daily
life.
recent
times,
highly
sensitive,
flexible,
and
stretchable
electronic
gas
sensors
gaining
tremendous
interest
due
their
applicability
in
electronics
applications.
The
construction
reviewed
for
real‐time,
selective
detection
hazardous
gases
at
room
temperature
(RT)
that
can
be
laminated
onto
a
human
body
or
integrated
with
body‐worn
textile
other
consumer
products,
utilizing
carbon
nanomaterials,
conductive
polymers,
2D
nanostructured
materials,
composites.
Sensing
transduction
techniques,
substrates
high‐performance
sensing
discussed
detail.
critical
challenges
future
development
presented.
Wearable
believed
have
great
potential
environmental
monitoring,
healthcare,
public
safety,
security,
as
well
food
quality
monitoring.
Advanced Functional Materials,
Год журнала:
2023,
Номер
33(19)
Опубликована: Март 18, 2023
Abstract
The
excited‐state
tuning
of
luminescent
metal–organic
compounds
has
made
great
progress
in
the
fields
optical
imaging,
photocatalysis,
photodynamic
therapy,
light‐emitting
devices,
sensors,
and
so
on.
Although
with
high
luminescence
efficiency
can
be
realized
via
enhanced
molecular
rigidity
heavy‐atom
effect,
their
corresponding
lifetimes
are
still
limited
on
order
a
nanosecond
to
millisecond,
owing
inherent
competition
between
luminous
lifetime.
Therefore,
advanced
applications
(i.e.,
persistent
afterglow
information
security,
anti‐counterfeiting,
smart
materials,
among
others)
related
long
(LPL,
typically
lifetime
larger
than
millisecond)
seriously
hindered.
This
review
gives
timely
systematic
summary
for
realizing
room‐temperature
phosphorescence
(RTP)‐type
thermally
activated
delayed
fluorescence
(TADF)‐type
LPL
during
last
few
years.
Particularly,
based
perspectives
time,
space,
energy
dimensions,
fundamental
materials
design
coordination
assembly
systematically
described
first
time.
Moreover,
internal
external
factors
influencing
properties
terms
efficiency,
lifetime,
color
illustrated.
Last
but
not
least,
challenges
also
discussed
developing
from
compounds.
Advances in Colloid and Interface Science,
Год журнала:
2023,
Номер
314, С. 102864 - 102864
Опубликована: Фев. 26, 2023
Designable
morphology
and
predictable
properties
are
the
most
challenging
goals
in
material
engineering.
Features
such
as
shape,
size,
porosity,
agglomeration
ratio
significantly
affect
final
of
metal-organic
frameworks
(MOFs)
can
be
regulated
throughout
synthesis
parameters
but
require
a
deep
understanding
mechanisms
MOFs
formation.
Herein,
we
systematically
summarize
effects
individual
factors,
pH
reaction
mixture,
including
acidic
or
basic
character
modulators,
temperature,
solvents
types,
surfactants
type
content
ionic
liquids
on
growing
MOFs.
We
identified
main
MOFs'
growth
leading
to
different
particles
next
discuss
effect
miscellaneous
based
related
nucleation,
formation
structure,
coordination
modulation,
protonation/deprotonation
acting
modulation
by
capping
agents.
The
microwaves
ultrasound
employment
during
is
also
considered
due
their
affecting
especially
nucleation
steps
