Advanced Synthesis & Catalysis,
Год журнала:
2021,
Номер
363(17), С. 4209 - 4215
Опубликована: Июль 15, 2021
Abstract
A
Mn(OAc)
3
⋅
2H
2
O‐catalyzed
aerobic
dehydrogenation
of
five
and
six‐membered
N
‐heterocycles
for
the
synthesis
‐heteroarenes
is
reported.
Of
note,
this
protocol
can
be
applied
to
tertiary
indolines
with
various
electron‐deficient
‐substituents.
Preliminary
mechanistic
investigations
support
that
a
single‐electron
transfer
pathway
might
involved.
magnified
image
Advanced Synthesis & Catalysis,
Год журнала:
2021,
Номер
363(17), С. 4209 - 4215
Опубликована: Июль 15, 2021
Abstract
A
Mn(OAc)
3
⋅
2H
2
O‐catalyzed
aerobic
dehydrogenation
of
five
and
six‐membered
N
‐heterocycles
for
the
synthesis
‐heteroarenes
is
reported.
Of
note,
this
protocol
can
be
applied
to
tertiary
indolines
with
various
electron‐deficient
‐substituents.
Preliminary
mechanistic
investigations
support
that
a
single‐electron
transfer
pathway
might
involved.
magnified
image
