ACS Applied Materials & Interfaces,
Год журнала:
2022,
Номер
14(8), С. 9970 - 9986
Опубликована: Фев. 17, 2022
The
development
of
materials
with
outstanding
performance
for
sensitive
and
selective
detection
multiple
analytes
is
essential
the
human
health
society.
Luminescent
metal-organic
frameworks
(LMOFs)
have
controllable
surface
pore
sizes
excellent
optical
properties.
Therefore,
a
variety
LMOF-based
sensors
diverse
functions
can
be
easily
designed
applied.
Furthermore,
introduction
energy
transfer
(ET)
into
LMOFs
(ET-LMOFs)
could
provide
richer
design
concept
much
more
accurate
sensing
performance.
In
this
review,
we
focus
on
recent
five
years
advances
in
ET-LMOF-based
materials,
an
emphasis
photochemical
photophysical
mechanisms.
We
discuss
detail
possible
processes
within
MOF
structure
or
between
MOFs
guest
materials.
Finally,
applications
are
highlighted.
Chemical Reviews,
Год журнала:
2022,
Номер
122(9), С. 8594 - 8757
Опубликована: Март 3, 2022
A
critical
review
of
different
prominent
nanotechnologies
adapted
to
catalysis
is
provided,
with
focus
on
how
they
contribute
the
improvement
selectivity
in
heterogeneous
catalysis.
Ways
modify
catalytic
sites
range
from
use
reversible
or
irreversible
adsorption
molecular
modifiers
immobilization
tethering
homogeneous
catalysts
and
development
well-defined
solid
surfaces.
The
latter
covers
methods
for
dispersion
single-atom
within
supports
as
well
complex
nanostructures,
it
includes
post-modification
materials
via
processes
such
silylation
atomic
layer
deposition.
All
these
methodologies
exhibit
both
advantages
limitations,
but
all
offer
new
avenues
design
specific
applications.
Because
high
cost
most
fact
that
resulting
may
limited
thermal
chemical
stability,
be
best
aimed
at
improving
selective
synthesis
value-added
chemicals,
incorporated
organic
schemes,
other
applications
are
being
explored
address
problems
energy
production,
instance,
greener
processes.
details
each
approaches
discussed,
representative
examples
provided.
We
conclude
some
general
remarks
future
this
field.
Advanced Functional Materials,
Год журнала:
2021,
Номер
31(32)
Опубликована: Июнь 3, 2021
Abstract
Covalent
organic
frameworks
(COFs)
have
emerged
as
an
exciting
new
class
of
porous
materials
constructed
by
building
blocks
via
dynamic
covalent
bonds.
They
been
extensively
explored
potentially
superior
candidates
for
electrode
materials,
electrolytes,
and
separators,
due
to
their
tunable
chemistry,
tailorable
structures,
well‐defined
pores.
These
features
enable
rational
design
targeted
functionalities,
facilitate
the
penetration
enhance
ion
transport.
This
review
provides
in‐depth
summary
recent
progress
in
development
COFs
diverse
battery
applications,
including
lithium‐ion,
lithium–sulfur,
sodium‐ion,
potassium‐ion,
lithium–CO
2
,
zinc‐ion,
zinc–air
batteries,
etc.
comprehensive
synopsis
pays
particular
attention
structure
chemistry
novel
strategies
that
implemented
improve
performance.
Additionally,
current
challenges,
possible
solutions,
potential
future
research
directions
on
batteries
are
discussed,
laying
groundwork
advances
this
material.
Advanced Materials,
Год журнала:
2022,
Номер
35(43)
Опубликована: Авг. 10, 2022
The
sensing
performances
of
gas
sensors
must
be
improved
and
diversified
to
enhance
quality
life
by
ensuring
health,
safety,
convenience.
Metal–organic
frameworks
(MOFs),
which
exhibit
an
extremely
high
surface
area,
abundant
porosity,
unique
chemistry,
provide
a
promising
framework
for
facilitating
gas-sensor
innovations.
Enhanced
understanding
conduction
mechanisms
MOFs
has
facilitated
their
use
as
gas-sensing
materials,
various
types
have
been
developed
examining
the
compositional
morphological
dependences
implementing
catalyst
incorporation
light
activation.
Owing
inherent
separation
absorption
properties
catalytic
activity,
are
applied
molecular
sieves,
absorptive
filtering
layers,
heterogeneous
catalysts.
In
addition,
oxide-
or
carbon-based
materials
with
complex
structures
composites
can
derived
appropriate
post-treatment
MOFs.
This
review
discusses
effective
techniques
design
optimal
MOFs,
in
terms
computational
screening
synthesis
methods.
Moreover,
through
distinctive
functionalities
heterostructures,
derivatives
incorporated
applications
presented.
Materials Horizons,
Год журнала:
2021,
Номер
8(9), С. 2387 - 2419
Опубликована: Янв. 1, 2021
An
emerging
trend
in
the
application
of
metal–organic
frameworks
is
to
engineer
mobile
devices
possess
chemical
detecting
capabilities
for
environmental
monitoring,
point-of-care
testing,
artificial
intelligence,
food
security
and
defence.
Chemical Society Reviews,
Год журнала:
2022,
Номер
51(19), С. 8300 - 8350
Опубликована: Янв. 1, 2022
This
review
summarizes
recent
advances
in
the
field
of
metal–organic
framework
(MOF)-based
membranes
with
a
special
focus
on
their
design
strategies
and
applications
for
gas
liquid
separations.
International Journal of Energy Research,
Год журнала:
2020,
Номер
45(2), С. 1190 - 1226
Опубликована: Авг. 24, 2020
A
significant
interest
in
the
exploration
of
clean
and
renewable
alternative
energy
resources
has
been
observed
recent
years
to
combat
environmental
pollution
shortages
for
a
sustainable
future.
In
this
regard,
hydrogen
is
clean,
energy-rich
fuel
with
unlimited
potential.
It
can
be
produced
via
water-splitting
process
using
most
abundant
on
earth,
that
is,
water
solar/electrical
energy.
Metal-organic
frameworks
(MOFs)
are
category
porous
crystalline
materials
well-organized
structures
unique
catalytic,
optical,
electrical
properties.
MOFs
MOF-derived
have
proved
excellent
catalysts
both
by
electrochemical
photoelectrochemical
(PEC)
routes.
Furthermore,
photochemical
capabilities
these
fine-tuned
maximize
their
performance
modification
bandgap,
surface
area,
current
density,
active
overpotential,
through
tailoring
organic
ligands
and/or
metal
centers.
number
works
dedicated
quest
resulting
promising
very
effective
results.
Such
as
photoelectrocatalysis,
composite
nanorod
array
TiO2/Co-MOF
acting
photoanode
achieved
one
highest
photocurrent
densities
2.93
mA/cm2
at
1.23
V
(vs
reverse
electrode
[RHE]).
another
study,
Co3C-3/TiO2
attained
density
2.6
vs
RHE.
For
electrocatalysis,
Fe2O3/Ni-MOF-74
exhibited
oxygen
evolution
reaction
overpotential
264
mV
reach
10
low
Tafel
plot
48
mV/dec.
Another
novel
material
derived
from
MOF,
MoO2-PC-rGO
displayed
Plot
41
Even
though
field
its
infancy
phase,
it
attracting
increased
attention
results
suggesting
extraordinary
potential
practical
applications.
Focus
review
article
overview
development
application
electrocatalytic
photoelectrocatalytic
production.
This
intends
provide
timely
reference
insight
advancement
based
PEC
clear
comprehensive
manner.
Starting
brief
introduction,
fundamentals,
factors
affecting
catalytic
efficiency
evaluation
parameters
summarized
followed
synthesis
strategies
progress
made
MOF-based
water-splitting.
