ChemistrySelect,
Год журнала:
2021,
Номер
6(38), С. 10178 - 10181
Опубликована: Окт. 7, 2021
Abstract
An
iridium
catalyzed
selective
B−H/C−H
dehydrogenative
coupling
for
arylation
of
electron
deficient
B(3)‐H
o
‐carborane
with
benzamides
has
been
developed.
A
plausible
mechanism
involving
Ir
III
/Ir
V
BH/CH
activation
was
proposed.
This
work
important
value
functionalization
B(3,6)‐H
bonds
via
coupling.
