Advanced Materials,
Год журнала:
2022,
Номер
34(29)
Опубликована: Март 21, 2022
Abstract
With
the
rising
level
of
atmospheric
CO
2
worsening
climate
change,
a
promising
global
movement
toward
carbon
neutrality
is
forming.
Sustainable
management
based
on
capture
and
utilization
(CCU)
has
garnered
considerable
interest
due
to
its
critical
role
in
resolving
emission‐control
energy‐supply
challenges.
Here,
comprehensive
review
presented
that
summarizes
state‐of‐the‐art
progress
developing
materials
for
sustainable
terms
not
only
capture,
catalytic
conversion
(thermochemistry,
electrochemistry,
photochemistry,
possible
combinations),
direct
utilization,
but
also
emerging
integrated
situ
as
well
artificial‐intelligence‐driven
smart
material
study.
In
particular,
insights
span
multiple
scopes
research
are
offered,
ranging
from
mechanistic
comprehension
reactions,
rational
design
precise
manipulation
key
(e.g.,
nanomaterials,
metal–organic
frameworks,
covalent
organic
zeolites,
ionic
liquids),
industrial
implementation.
This
concludes
with
summary
new
perspectives,
especially
aspects
society,
which
major
difficulties
future
potential
implementing
advanced
technologies
management.
work
may
serve
guideline
road
map
CCU
systems,
benefiting
both
scientists
engineers
working
this
growing
potentially
game‐changing
area.
Chemical Society Reviews,
Год журнала:
2022,
Номер
51(22), С. 9340 - 9370
Опубликована: Янв. 1, 2022
This
review
describes
the
application
of
zeotype
materials
for
capture
CO
2
in
different
scenarios,
critical
parameters
defining
adsorption
performances,
and
challenges
zeolitic
adsorbents
capture.
Macromolecules,
Год журнала:
2021,
Номер
54(12), С. 5866 - 5877
Опубликована: Май 21, 2021
We
describe
the
first
examples
of
benzoxazine
(BZ)-linked
tetraphenylethylene
(TPE)-
and
pyrene
(Py)-containing
conjugated
microporous
organic
polymers
(CMPs)—TPE-TPE-BZ
Py-TPE-BZ,
respectively—having
high
surface
areas
pore
volumes,
prepared
through
multistep
syntheses
(Schiff
base,
reduction,
Mannich,
Sonogashira–Hagihara
coupling),
their
solid-state
transformations
ring-opening
polymerizations
(ROPs)
to
give
BZ
linkages
have
never
been
reported
previously.
The
chemical
structures
and,
particularly,
presence
units
in
TPE-TPE-BZ
Py-TPE-BZ
CMPs
were
confirmed
Fourier
transform
infrared
nuclear
magnetic
resonance
spectroscopic
analyses.
TEP-TPE-BZ
CMP
had
a
BET
specific
area
total
volume
(325
m2
g–1
0.69
cm3
g–1,
respectively).
Because
can
undergo
ROP
simple
thermal
treatment
without
need
for
curing
agent
or
catalyst,
readily
underwent
one-step
solid
state
form
new
featuring
phenolic
OH
Mannich
bridges
as
functional
groups
capable
forming
strong
intermolecular
hydrogen
bonds
and/or
acid/base
interactions
with
molecules
CO2
gas
enhance
uptake
ability.
Chemical Society Reviews,
Год журнала:
2023,
Номер
52(17), С. 5827 - 5860
Опубликована: Янв. 1, 2023
The
shortage
of
freshwater
resources
caused
by
heavy
metal
pollution
is
an
acute
global
issue,
which
has
a
great
impact
on
environmental
protection
and
human
health.
Therefore,
the
exploitation
new
strategies
for
designing
synthesizing
green,
efficient,
economical
materials
detection
removal
ions
crucial.
Among
various
methods
ions,
advanced
functional
systems
including
nanomaterials,
polymers,
porous
materials,
biomaterials
have
attracted
considerable
attention
over
past
several
years
due
to
their
capabilities
real-time
detection,
excellent
efficiency,
anti-interference,
quick
response,
high
selectivity,
low
limit
detection.
In
this
tutorial
review,
we
review
general
design
principles
underlying
aforementioned
in
particular
highlight
fundamental
mechanisms
specific
examples
detecting
removing
ions.
Additionally,
enhance
water
purification
quality
using
these
been
reviewed,
also
current
challenges
opportunities
exciting
field
highlighted,
fabrication,
subsequent
treatment,
potential
future
applications
such
materials.
We
envision
that
will
provide
invaluable
guidance
tailored
towards
metals,
thereby
expediting
development
high-performance
fostering
more
efficient
approaches
remediation.
Green Chemistry,
Год журнала:
2022,
Номер
24(9), С. 3433 - 3460
Опубликована: Янв. 1, 2022
Porous
poly(ionic
liquid)s,
combining
the
features
of
porous
polymers
and
ionic
moieties
resembling
structures
functions
liquids,
have
exhibited
promising
potential
in
CO
2
fixation
via
cycloadditions
with
epoxides.
