In-situ-generation of alkylsilyl peroxides from alkyl hydroperoxides and their subsequent copper-catalyzed functionalization with organosilicon compounds DOI

Weiping Xu,

Wenfeng Zhong,

Qin Yang

и другие.

Tetrahedron Letters, Год журнала: 2021, Номер 75, С. 153144 - 153144

Опубликована: Май 30, 2021

Язык: Английский

Carbon-Chain Elongation by Co-Catalyzed Selective C–C Bond Cleavage and Subsequent Silylperoxylation of Alkene Substrates DOI
Jiahao Xie, Terumasa Kato, Keiji Maruoka

и другие.

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 14754 - 14761

Опубликована: Сен. 20, 2024

Язык: Английский

Процитировано

1
Synthesis of Functionalized Aliphatic Acid Esters via the Generation of Alkyl Radicals from Silylperoxyacetals DOI
Akira Matsumoto,

Yoko Shiozaki,

Shunya Sakurai

и другие.

Chemistry - An Asian Journal, Год журнала: 2021, Номер 16(17), С. 2431 - 2434

Опубликована: Июль 19, 2021

Abstract We describe a catalytic method for the synthesis of variety functionalized aliphatic acid esters using silylperoxyacetals, which are versatile alkyl radical precursors with terminal ester moiety. In presence an appropriate transition‐metal catalyst, in situ generation radicals and subsequent bond‐forming process proceeds smoothly to afford synthetically valuable derivatives. The present can be applied efficient pharmaceutically important 1,1‐diarylalkane motif. addition, novel strategy structurally diverse hydroxy derivatives via C−O bond formation that utilizes TEMPO has been developed.

Язык: Английский

Процитировано

6
A copper-catalyzed direct C(sp2)–H alkylsulfonylation of alkenes using alkylsilyl peroxides and DABCO·(SO2)2 DOI

Xueni Tian,

Lingling Chen,

Tong‐Hao Zhu

и другие.

Organic Chemistry Frontiers, Год журнала: 2023, Номер 10(19), С. 4821 - 4826

Опубликована: Янв. 1, 2023

A copper-catalyzed C(sp 2 )–H alkylsulfonylation of alkenes using alkylsilyl peroxides as the alkyl radical precursors with insertion sulfur dioxide was developed, and shown to provide a convenient route diverse ( E )-alkylsulfonyl alkenes.

Язык: Английский

Процитировано

2
Metal‐Free and Visible Light‐Induced Difunctionalizations of α‐CF3 Styrenes with Aryl Diazonium Salts and Hetero Nucleophiles DOI
Lu Zhang, Shuai Liu, Mingming Ma

и другие.

European Journal of Organic Chemistry, Год журнала: 2023, Номер 26(42)

Опубликована: Сен. 5, 2023

Abstract Metal‐free, visible light‐induced difunctionalizations of α ‐CF 3 styrenes with aryl diazonium salts and various hetero nucleophiles (ROH, H 2 O, N − F ) are described. This concise protocol provided easy access to the tertiary alkyl ethers, alcohol fluorides good yields excellent functional group tolerance. In addition, four‐component “SO ” insertion reaction also worked efficiently produce , β ‐sulfonyl ethers in moderate yields. A radical‐polar crossover coupling pathway was proposed for C−O bond formation.

Язык: Английский

Процитировано

2
In-situ-generation of alkylsilyl peroxides from alkyl hydroperoxides and their subsequent copper-catalyzed functionalization with organosilicon compounds DOI

Weiping Xu,

Wenfeng Zhong,

Qin Yang

и другие.

Tetrahedron Letters, Год журнала: 2021, Номер 75, С. 153144 - 153144

Опубликована: Май 30, 2021

Язык: Английский

Процитировано

5