Abstract
Conductive
polymer
hydrogels
(CPHs)
are
gaining
considerable
attention
in
developing
wearable
electronics
due
to
their
unique
combination
of
high
conductivity
and
softness.
However,
the
absence
interactions,
incompatibility
between
hydrophobic
conductive
polymers
(CPs)
hydrophilic
networks
gives
rise
inadequate
bonding
CPs
hydrogel
matrices,
thereby
significantly
impairing
mechanical
electrical
properties
CPHs
constraining
utility
electronic
sensors.
Therefore,
endow
with
good
performance,
it
is
necessary
ensure
a
stable
robust
network
CPs.
Encouragingly,
recent
research
has
demonstrated
that
incorporating
supramolecular
interactions
into
enhances
interaction,
improving
overall
CPH
performance.
comprehensive
review
focusing
on
(SCPH)
for
sensing
applications
currently
lacking.
This
provides
summary
typical
strategies
employed
development
high‐performance
elucidates
SCPHs
closely
associated
Moreover,
discusses
fabrication
methods
classification
SCPH
sensors,
while
also
exploring
latest
application
scenarios
Finally,
challenges
sensors
offers
suggestions
future
advancements.
Batteries,
Год журнала:
2023,
Номер
9(4), С. 202 - 202
Опубликована: Март 29, 2023
The
enormous
demand
for
energy
due
to
rapid
technological
developments
pushes
mankind
the
limits
in
exploration
of
high-performance
devices.
Among
two
major
storage
devices
(capacitors
and
batteries),
electrochemical
capacitors
(known
as
‘Supercapacitors’)
play
a
crucial
role
supply
conserved
from
various
sustainable
sources.
high
power
density
ultra-high
cyclic
stability
are
attractive
characteristics
supercapacitors.
However,
low
is
downside
them,
which
also
responsible
extensive
research
this
field
help
charge
capabilities
thrive
their
limits.
Discoveries
electrical
double-layer
formation,
pseudocapacitive
intercalation-type
(battery-type)
behaviors
drastically
improved
performances
introduction
nanostructured
active
materials
(carbon-/metal-/redox-active-polymer/metal-organic/covalent-organic
framework-based
electrode
materials),
electrolytes
(conventional
aqueous
unconventional
systems)
with
superior
unprecedented
device
architectures
further
boosted
characteristics.
In
addition,
detailed
investigations
processes
at
electrode–electrolyte
interfaces
enable
us
reinforce
present
techniques
approaches
toward
next-generation
review,
fundamental
concepts
supercapacitor
terms
components,
assembly,
evaluation,
mechanism,
advanced
properties
comprehensively
discussed
representative
examples.
Industrial & Engineering Chemistry Research,
Год журнала:
2022,
Номер
61(49), С. 17915 - 17929
Опубликована: Ноя. 30, 2022
Conductive
hydrogel
strain
sensors
have
triggered
extensive
research
interest
in
artificial
intelligence,
human
motion
detection,
electronic
skin,
and
other
technical
fields.
However,
it
is
still
challenging
work
to
prepare
conductive
hydrogels
integrated
with
good
biocompatibility,
recyclability,
self-healing,
strong
adhesion
properties
both
air
underwater.
Herein,
a
novel,
ultraexcellent
adhesive,
multifunctional
gelatin
composite
was
fabricated
through
simple
rapid
one-pot
method
which
(Gel)
polyvinyl
alcohol
(PVA)
were
used
as
the
polymeric
skeletons,
Tara
tannin
cross-linking
agent,
multiwalled
carbon
nanotubes
(CNTs)
conducting
medium.
Inspired
by
vegetable
tanning
mechanism
chemistry,
multiple
hydrogen
bonding
hydrophobic
interactions
of
Gel
build
network
hydrogel.
The
obtained
GTPC
(Gel-Tara
tannin-PVA-CNTs)
exhibited
considerable
stretchability
(760%),
strength
(16
kPa
pigskin),
high
sensitivity
(gauge
factor
(GF)
=
6.79).
In
particular,
displayed
repeatable
(≥10
times)
self-healing
performance
(HE
(self-healing
efficiency)
>
99%)
formed
sensor
could
accurately
detect
various
signals,
such
finger
bending,
ankle
smiling,
also
sensitively
capture
sensing
signals
body
movements
self-healed
similar
ability
original
one.
This
affords
new
idea
for
design
fabrication
flexible
underwater
performance,
sensitivity,
(in
water)
using
tannin,
promoting
application
diversified
utilization
tannin.
Advanced Functional Materials,
Год журнала:
2022,
Номер
32(31)
Опубликована: Май 18, 2022
Abstract
The
development
of
next‐generation
touch
panels
requires
sensors
that
are
highly
sensitive,
biocompatible,
transparent,
stretchable,
self‐healing,
and
even
anti‐freezing
self‐powered
because
the
traditional
panel
based
on
stiff
brittle
electrodes
faces
many
challenges.
Conductive
hydrogels
hold
great
promise
as
sensing
materials
for
new‐generation
panel.
However,
most
hydrogel‐based
developed
single‐function
gel
with
a
lack
self‐power
capabilities.
Herein,
authors
demonstrate
multi‐functional
surface‐capacitive
triboelectric
nanogenerator
an
instantaneous
peak
power
density
209
mW
m
−2
uses
zwitterionic
network
transparent
(98.1%
transmittance),
ultra‐stretchable
(
>
11
500%
strain),
degradable,
flexible
ionic
conductor.
can
be
utilized
human‐machine
interactive
interface
fast
response,
high
resolution,
low
parasitic
capacitance,
functional
recovery
instantly
upon
damage,
without
sacrificing
its
functionalities
in
stretch
state
(1600%
areal
strain)
at
subzero
environment
<−
20
°
C).
Epidermal
operated
arbitrary
complex
surfaces,
outstanding
input
property
demonstrated
by
writing,
playing
computer
games.
Simultaneously,
multifunctional
is
degradable
phosphate
buffered
saline
solution,
no
pollution
caused.
Progress in Polymer Science,
Год журнала:
2023,
Номер
140, С. 101665 - 101665
Опубликована: Фев. 26, 2023
Nature
endows
numerous
organisms
with
the
ability
to
realize
their
basic
physiological
activities
through
stimulus-responsive
actuation.
Inspired
by
these
interesting
biological
structures,
various
biomimetic
hydrogel
actuators
excellent
controllability,
fast
response,
and
toughness
have
been
developed.
Here,
principles
of
enabling
behavior
in
polymer
materials
are
first
reviewed
for
example
subsequently
recent
progress
implementing
stimuli-response
bioinspired
being
discussed.
Particular
emphasis
is
on
mechanisms
underlying
mechanical
toughening
its
role
applications.
The
goal
highlight
progress,
find
common
threads,
discuss
fundamental
differences
determine
current
challenges
future
directions
this
field.
The Chemical Record,
Год журнала:
2023,
Номер
24(1)
Опубликована: Ноя. 22, 2023
Abstract
Supercapacitors
(SCs)
are
potentially
trustworthy
energy
storage
devices,
therefore
getting
huge
attention
from
researchers.
However,
due
to
limited
capacitance
and
low
density,
there
is
still
scope
for
improvement.
The
race
develop
novel
methods
enhancing
their
electrochemical
characteristics
going
strong,
where
the
goal
of
improving
density
match
that
batteries
by
increasing
specific
raising
working
voltage
while
maintaining
high
power
capability
cutting
cost
production.
In
this
light,
paper
offers
a
succinct
summary
current
developments
fresh
insights
into
construction
SCs
with
which
might
help
new
researchers
in
field
supercapacitor
research.
From
electrolytes,
electrodes,
device
modification
perspectives,
applicable
methodologies
were
emphasized
explored.
When
compared
conventional
SCs,
special
combination
electrode
material/composites
electrolytes
along
fabrication
design
considerably
enhances
performance
SCs.
Emphasis
placed
on
dynamic
mechanical
variables
connected
SCs′
process.
To
point
way
toward
positive
future
high‐energy
potential
difficulties
finally
highlighted.
Further,
we
explore
few
important
topics
densities
supercapacitors,
as
well
some
links
between
major
impacting
factors.
review
also
covers
obstacles
prospects
fascinating
subject.
This
gives
fundamental
understanding
supercapacitors
crucial
principle
next
generation
improved
being
developed
commercial
consumer
use.
Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(16), С. 9371 - 9399
Опубликована: Янв. 1, 2024
We
present
a
comprehensive
review
of
the
recent
research
advances
in
field
sensors
based
on
hydrogels
with
nanofillers.
The
characteristics
and
design
strategies
nanofillers
are
highlighted
multiple
properties
conductive
nanocomposite
described.
Molecules,
Год журнала:
2023,
Номер
28(4), С. 1781 - 1781
Опубликована: Фев. 13, 2023
Presently,
the
rising
concerns
about
fossil
fuel
crisis
and
ecological
deterioration
have
greatly
affected
world
economy
hence
attracted
attention
to
utilization
of
renewable
energies.
Among
energy
being
developed,
supercapacitors
hold
great
promise
in
broad
applications
such
as
electric
vehicles.
main
challenge
facing
is
amount
stored.
This,
however,
does
not
satisfy
increasing
demand
for
higher
storage
devices,
therefore,
intensive
research
undertaken
overcome
challenges
low
density.
The
purpose
this
review
report
on
solid
polymer
electrolytes
(SPEs)
based
polyvinyl
alcohol
(PVA).
discussed
PVA
a
host
SPEs
followed
by
discussion
influence
conducting
salts.
formation
well
ion
transport
mechanism
were
discussed.
application
development
PVA-based
other
devices
elucidated.
fundamentals
electrochemical
characterization
analyzing
supercapacitor
applications,
EIS,
LSV
dielectric
constant,
are
highlighted.
Similarly,
thermodynamic
models
ions
their
temperature
Arrhenius
Vogel-Tammann-Fulcher
(VTF)
analyzed.
Methods
enhancing
performance
reported.
Likely
current
Finally,
directions
present
producing
proposed.
Therefore,
expected
be
source
material
researchers
concerned
with
SPE
material.