Angewandte Chemie International Edition,
Год журнала:
2023,
Номер
62(19)
Опубликована: Март 7, 2023
Recently,
abundant
active
materials
are
developed
to
achieve
the
wearable
detection
of
human
body
humidity.
However,
limited
response
signal
and
sensitivity
restrict
further
application
due
their
moderate
affinity
water.
Herein,
we
propose
a
flexible
COF-5
film
synthesized
by
brief
vapor-assisted
method
at
room
temperature.
Intermediates
calculated
DFT
simulation
investigate
interaction
between
The
adsorption
desorption
water
molecule
result
in
reversible
deformation
COF
layers
while
creating
new
conductive
path
π-π
stacking.
as-prepared
films
applied
humidity
sensors,
exhibiting
resistance
change
4
orders
magnitude
with
remarkable
linear
relation
log
function
relative
(RH)
11
%-98
%
RH
range.
Applications
including
respiratory
monitoring
non-contact
switch
tested,
providing
promising
prospect
for
Journal of Materials Chemistry A,
Год журнала:
2022,
Номер
10(31), С. 16369 - 16389
Опубликована: Янв. 1, 2022
This
paper
discusses
the
challenges
and
solutions
for
zinc–air
batteries
in
practical
mass
production
applications
provides
a
more
reasonable
structure
power
batteries.
Journal of Materials Chemistry A,
Год журнала:
2022,
Номер
11(3), С. 1208 - 1215
Опубликована: Ноя. 18, 2022
A
PTZ-based
D–A
COF
with
low
exciton
binding
energy
and
high
charge
separation
efficiency
exhibited
an
enhanced
photocatalytic
performance
in
oxidative
amine
coupling
cyclization
of
thioamide
reactions.
Angewandte Chemie International Edition,
Год журнала:
2022,
Номер
62(1)
Опубликована: Ноя. 2, 2022
Covalent
organic
frameworks
(COFs)
have
been
extensively
investigated
due
to
their
unique
structure,
porosity,
and
functionality.
However,
at
the
topological
level,
COFs
remain
as
two-dimensional
(2D)
or
three-dimensional
(3D)
structures,
while
with
one-dimensional
(1D)
topology
not
systematically
explored.
In
this
work,
we
proposed
a
synthetic
strategy
for
construction
of
1D-COFs
based
on
non-linear
edges
suitable
high-symmetry
vertices.
Compared
2D-COFs
counterparts,
AIEgens
located
vertex
frame
exhibited
enhanced
fluorescence.
The
density
functional
theory
(DFT)
calculations
revealed
that
dimensional-induced
rotation
restriction
(DIRR)
effect
could
spontaneously
introduce
additional
non-covalent
interactions
between
strip
frames,
which
substantially
diminish
non-radiative
transitions.
This
work
also
provides
protocols
design
guidance
scheme
synthesis
emitting
COFs.
Angewandte Chemie International Edition,
Год журнала:
2023,
Номер
62(19)
Опубликована: Март 7, 2023
Recently,
abundant
active
materials
are
developed
to
achieve
the
wearable
detection
of
human
body
humidity.
However,
limited
response
signal
and
sensitivity
restrict
further
application
due
their
moderate
affinity
water.
Herein,
we
propose
a
flexible
COF-5
film
synthesized
by
brief
vapor-assisted
method
at
room
temperature.
Intermediates
calculated
DFT
simulation
investigate
interaction
between
The
adsorption
desorption
water
molecule
result
in
reversible
deformation
COF
layers
while
creating
new
conductive
path
π-π
stacking.
as-prepared
films
applied
humidity
sensors,
exhibiting
resistance
change
4
orders
magnitude
with
remarkable
linear
relation
log
function
relative
(RH)
11
%-98
%
RH
range.
Applications
including
respiratory
monitoring
non-contact
switch
tested,
providing
promising
prospect
for
