Recent Progress on Heterojunction Engineering in Perovskite Solar Cells DOI
Tianyue Wang, Wenqiu Deng, Jiupeng Cao

и другие.

Advanced Energy Materials, Год журнала: 2022, Номер 13(33)

Опубликована: Сен. 1, 2022

Abstract Metal halide perovskite solar cells (PSCs) have become one of the most promising next‐generation photovoltaic technologies due to their low‐cost fabrication, solution processability, and superior optoelectronic properties. Although state‐of‐art PSCs demonstrate a power conversion efficiency record comparable that silicon cells, there are still many challenges toward commercialization. devices based on various semiconductor heterojunctions all play important roles in device performance. The operation relies combination multiple offer delicate control photocarrier generation, separation, transport respective electrodes. Hence, advanced heterojunction design is crucial for further improvement Notably, records mainly ascribed optimized engineering. Considering significance this topic, comprehensive review recently developed designs presented. Following brief introduction PSC architectures, operation, fundamental theories, recent progress perovskite/electron layer, perovskite/hole perovskite/perovskite engineering elaborated. Finally, conclusions perspectives research field addressed.

Язык: Английский

Redox mediator-stabilized wide-bandgap perovskites for monolithic perovskite-organic tandem solar cells DOI
Shengfan Wu, Yichao Yan, Jun Yin

и другие.

Nature Energy, Год журнала: 2024, Номер 9(4), С. 411 - 421

Опубликована: Янв. 26, 2024

Язык: Английский

Процитировано

67
Highly Efficient Perovskite/Organic Tandem Solar Cells Enabled by Mixed‐Cation Surface Modulation DOI Open Access
Xue Wang, Dong Zhang, Baoze Liu

и другие.

Advanced Materials, Год журнала: 2023, Номер 35(49)

Опубликована: Авг. 7, 2023

Perovskite/organic tandem solar cells (POTSCs) are gaining attention due to their easy fabrication, potential surpass the S-Q limit, and superior flexibility. However, low power conversion efficiencies (PCEs) of wide bandgap (Eg) perovskite (PVSCs) have hindered development. This work presents a novel effective mixed-cation passivation strategy (CE) passivate various types traps in wide-Eg perovskite. The complementary effect 4-trifluoro phenethylammonium (CF3 -PEA+ , denoted as CA+ ) ethylenediammonium (EDA2+ EA2+ reduces both electron/hole defect densities non-radiative recombination rate, resulting record open-circuit voltage (Voc PVSCs (1.35 V) high fill factor (FF) 83.29%. These improvements lead PCE 24.47% when applied fabricated POTSCs, highest date. Furthermore, unencapsulated POTSCs exhibit excellent photo thermal stability, retaining over 90% initial after maximum point (MPP) tracking or exposure 60 °C for 500 h. findings imply that synergic surface passivators is promising achieve high-efficiency stable corresponding POTSCs.

Язык: Английский

Процитировано

59
Rational molecular design of multifunctional self-assembled monolayers for efficient hole selection and buried interface passivation in inverted perovskite solar cells DOI Creative Commons
Wenlin Jiang, Ming Liu, Yanxun Li

и другие.

Chemical Science, Год журнала: 2024, Номер 15(8), С. 2778 - 2785

Опубликована: Янв. 1, 2024

Self-assembled monolayers (SAMs) have been widely employed as the bottom-contact hole-selective layer (HSL) in inverted perovskite solar cells (PSCs). Besides manipulating electrical properties, molecularly engineering SAM provides an opportunity to modulate buried interface. Here, we successfully introduced Lewis-basic oxygen and sulfur heteroatoms through rational molecular design of asymmetric SAMs obtain two novel multifunctional SAMs, CbzBF CbzBT. Detailed characterization single-crystal structures device interfaces shows that enhanced packing, more effective ITO work function adjustment, interface passivation were achieved. Consequently, champion PSC employing CbzBT showed excellent power conversion efficiency (PCE) 24.0% with a high fill factor 84.41% improved stability. This demonstrates feasibility introducing defect-passivating heterocyclic groups into molecules help passivate interfacial defects PSCs. The insights gained from this strategy will accelerate development new HSLs for efficient

Язык: Английский

Процитировано

55
Strain Regulation via Pseudo Halide‐Based Ionic Liquid toward Efficient and Stable α‐FAPbI3 Inverted Perovskite Solar Cells DOI

Xiaofen Jiang,

Xue Wang, Xin Wu

и другие.

Advanced Energy Materials, Год журнала: 2023, Номер 13(23)

Опубликована: Май 1, 2023

Abstract Inverted (p‐i‐n) perovskite solar cells have drawn great attention due to their outstanding stability and low‐temperature processibility. However, power conversion efficiency (PCE) still lags behind conventional (n‐i‐p) devices mainly the lack of strategies stabilize α ‐FAPbI 3 without changing bandgap. In this work, a facile effective strategy is reported regulate residual strain via pseudo halide‐based ionic liquids incorporation in inverted (PVSCs). The employment methylamine formate (MAFa) liquid enables homogenously stronger compressive restrain transition shared‐corner PbI 6 octahedron into shared‐face δ , as well affecting dynamic behavior carriers defects achieve record PCE (24.08%) among FAPbI up now. addition, MAFa results enhanced device stability, unencapsulated PVSC retains over 90% its initial after stored ambient environment (RH:30 ± 5%) for 1000 h. This work provides an efficient realize stable based PVSCs further catch with ones.

Язык: Английский

Процитировано

54
A Comprehensive Review of Organic Hole‐Transporting Materials for Highly Efficient and Stable Inverted Perovskite Solar Cells DOI
Yuwei Duan, Yu Chen, Yihui Wu

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер 34(25)

Опубликована: Фев. 7, 2024

Abstract Inverted perovskite solar cells (IPSCs) have attracted unprecedented attention due to their negligible hysteresis, long‐term operational stability, low temperature, and cost‐effective fabrication process, as well wide applications. The power conversion efficiency (PCE) of IPSCs has skyrocketed from 3.9% in 2013 certified 26.1% 2023, which is over the 25.8% regular counterpart, benefiting emergence a great number organic hole‐transporting materials (HTM). This review provides an overview recent development stability IPSCs, including small molecules conjugated conductive polymers. effective strategies for charge‐transport layer films are also discussed. Finally, prospective further outlined, developing novel fabricating techniques meet requirements commercial application.

Язык: Английский

Процитировано

46
Top‐Down Induced Crystallization Orientation toward Highly Efficient p‐i‐n Perovskite Solar Cells DOI

Xiaofen Jiang,

Baoze Liu, Xin Wu

и другие.

Advanced Materials, Год журнала: 2024, Номер 36(24)

Опубликована: Март 8, 2024

Crystallization orientation plays a crucial role in determining the performance and stability of perovskite solar cells (PVSCs), whereas effective strategies for realizing oriented crystallization is still lacking. Herein, facile efficient top-down strategy reported to manipulate via treating wet film with propylamine chloride (PACl) before annealing. The PA

Язык: Английский

Процитировано

35
Recent advances of polyoxometalate-based materials applied for electron-related devices DOI

Yalun Hu,

Yanying Wang,

Jun‐Wei Zhao

и другие.

Coordination Chemistry Reviews, Год журнала: 2024, Номер 506, С. 215724 - 215724

Опубликована: Фев. 24, 2024

Язык: Английский

Процитировано

24
Boosting Efficiency and Stability of NiOx‐Based Inverted Perovskite Solar Cells Through D–A Type Semiconductor Interface Modulation DOI
Xianglang Sun, Chunlei Zhang, Danpeng Gao

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер 34(25)

Опубликована: Янв. 9, 2024

Abstract NiO x is one of the promising inorganic hole transporting materials in inverted perovskite solar cells (PSCs), however, its device efficiency and stability are still limited by energy level mismatch, low intrinsic conductivity, high interface defect density, complex active species. Herein, use an imide‐based donor–acceptor type semiconductor (BTF14) as interlayer between proposed, which facilitates extraction transfer, reduces density at film bulk, further concentration Ni >3+ species to stabilize heterointerface. As a result, power conversion PSCs can be significantly boosted from 22.11% 24.20% /BTF14. Moreover, /BTF14 based devices also exhibit negligible hysteresis excellent long‐term stability, with over 77% their initial remaining after continuous operation 60 °C for 1000 h under 1 sun illumination.

Язык: Английский

Процитировано

21
Spin‐Coated and Vacuum‐Processed Hole‐Extracting Self‐Assembled Multilayers with H‐Aggregation for High‐Performance Inverted Perovskite Solar Cells DOI Creative Commons
Wenlin Jiang, Deng Wang,

Wansong Shang

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(45)

Опубликована: Июль 24, 2024

Abstract We report a highly crystalline self‐assembled multilayer (SAMUL) that is fundamentally different from the conventional monolayer or disordered bilayer used for hole‐extraction in inverted perovskite solar cells (PSCs). The SAMUL can be easily formed on ITO substrate to establish better surface coverage enhance performance and stability of PSCs. A detailed structure‐property‐performance relationship molecules established through systematic study their crystallinity, molecular packing, hole‐transporting properties. These SAMULs are rationally optimized by varying structures deposition methods thermal evaporation spin‐coating fabricating CbzNaphPPA‐based was chosen PSCs due it exhibiting highest crystallinity hole mobility which derived ordered H‐aggregation. This resulted remarkably high fill factor 86.45 %, enables very impressive power conversion efficiency (PCE) 26.07 % achieved along with excellent device (94 its initial PCE retained after continuous operation 1200 h under 1‐sun irradiation at maximum point 65 °C). Additionally, record‐high 23.50 could adopting thermally evaporated SAMUL. greatly simplifies broadens scope SAM large‐area devices diverse substrates.

Язык: Английский

Процитировано

21
Surface chemistry-engineered perovskite quantum dot photovoltaics DOI

Xuliang Zhang,

Hehe Huang, Chenyu Zhao

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review summarizes the progress and provides perspectives on perovskite quantum dot photovoltaics, with a focus surface chemistry engineering, paving new direction for large-area low-cost PV technology to address major energy challenges.

Язык: Английский

Процитировано

4