Materials Science and Engineering R Reports,
Год журнала:
2024,
Номер
159, С. 100797 - 100797
Опубликована: Май 4, 2024
We
conducted
a
comprehensive
literature
review
of
LiFePO4
(LFP)
and
LiMnxFe1-xPO4
(x=0.1–1)
(LMFP)-based
lithium-ion
batteries
(LIBs),
focusing
mostly
on
electric
vehicles
(EVs)
as
primary
application
LIBs.
Although
numerous
individual
research
studies
exist,
unified
coordinated
covering
the
subject
from
mine
to
chassis
has
not
yet
been
presented.
Accordingly,
our
encompasses
entire
LIB
development
process.
I)
Initial
resources,
including
lithium,
iron,
manganese,
phosphorous;
their
global
reserves;
mining
procedures;
demand
for
production.
II)
The
main
Fe-
Mn-containing
precursors,
Fe0,
FexOy,
FePO4,
FeSO4,
MnSO4,
preparation
methods,
use
in
LIBs,
effect
electrochemical
performance
final
active
cathode
materials.
III)
Use
precursors
synthesis
materials
pioneering
methods
olivine
production
lines,
particularly
hydrothermal
liquid-state
synthesis,
molten-state
solid-state
synthesis.
IV)
Electrode
engineering
design
optimization
electrolytes.
V)
Production
cells,
modules,
packs.
(VI)
Highlights
challenges
associated
with
widespread
utilization
olivines
emphasizing
safety,
cost,
energy
efficiency,
carbon
emissions.
In
conclusion,
offers
overview
process
involved
fabrication
LFP/LMFP-based
initial
elements
assembly
packs
that
power
EVs.
Nature Energy,
Год журнала:
2023,
Номер
8(11), С. 1284 - 1295
Опубликована: Сен. 28, 2023
Abstract
Due
to
the
rapidly
increasing
demand
for
electric
vehicles,
need
battery
cells
is
also
considerably.
However,
production
of
requires
enormous
amounts
energy,
which
expensive
and
produces
greenhouse
gas
emissions.
Here,
by
combining
data
from
literature
own
research,
we
analyse
how
much
energy
lithium-ion
(LIB)
post
(PLIB)
cell
on
macro-economic
levels,
currently
in
future
(until
2040).
On
level,
find
that
PLIB
require
less
than
LIB
per
produced
energy.
consumption
global
will
be
130,000
GWh
if
no
measures
are
taken.
Yet,
it
possible
optimize
save
up
66%
this
demand.
Advanced Materials,
Год журнала:
2022,
Номер
34(52)
Опубликована: Март 25, 2022
Abstract
It
has
long
been
a
global
imperative
to
develop
high‐energy‐density
lithium‐ion
batteries
(LIBs)
meet
the
ever‐growing
electric
vehicle
market.
One
of
most
effective
strategies
for
boosting
energy
density
LIBs
is
increase
output
voltage,
which
largely
depends
upon
cathode
materials.
As
most‐promising
cathodes
high‐voltage
(>4
V
vs
Li/Li
+
),
four
major
categories
including
lithium‐rich
layered
oxides,
nickel‐rich
spinel
and
polyanionic
compounds
still
encounter
severe
challenges
realize
improvement
voltage
while
maintaining
high
capacity,
fast
rate
capability,
service
life.
This
review
focuses
on
key
links
in
development
materials
from
lab
industrialization.
First,
failure
mechanisms
kinds
are
clarified,
optimization
strategies,
particularly
solutions
that
easy
large‐scale
production,
considered.
Then,
bridge
gap
between
industry,
cost
management,
safety
assessment,
practical
battery‐performance
evaluation,
sustainability
battery
technologies,
discussed.
Finally,
tough
promising
commercialization
summarized
promote
application
with
densities.
Advanced Materials,
Год журнала:
2022,
Номер
35(43)
Опубликована: Сен. 14, 2022
Lithium-metal
batteries
(LMBs)
are
representative
of
post-lithium-ion
with
the
great
promise
increasing
energy
density
drastically
by
utilizing
low
operating
voltage
and
high
specific
capacity
metallic
lithium.
LMBs
currently
stand
at
a
point
transition
which
accumulation
knowledge
from
fundamental
research
is
being
translated
into
large-scale
commercialization.
This
review
summarizes
available
strategies
for
addressing
intrinsic
shortcomings
LMBs,
such
as
suppression
dendritic
growth
parasitic
reactions
material
to
electrode
cell
level.
The
discussion
pertaining
level
includes
efforts
concerns
relating
scaling
up
established
expertise
view
intends
encourage
researchers
in
both
institutions
industry
make
synergistic
effort
share
their
views
comprehensively
ensure
that
LMB
technology
continues
evolve
harmony
become
mature
technology.
Nature Communications,
Год журнала:
2022,
Номер
13(1)
Опубликована: Апрель 7, 2022
The
use
of
inorganic
solid-state
electrolytes
is
considered
a
viable
strategy
for
developing
high-energy
Li-based
metal
batteries.
However,
suppression
parasitic
interfacial
reactions
and
growth
unfavorable
Li
depositions
upon
cycling
are
challenging
aspects
not
yet
fully
addressed.
Here,
to
better
understand
these
phenomena,
we
investigate
various
sulfide
solid
(SEs),
i.e.,
Li7-xPS6-xClx
(x
=
0.6,
1.0,
1.3,
1.45,
1.6),
via
ex
situ
in
physicochemical
electrochemical
measurements.
We
found
that
the
Cl
distribution
cooling
process
applied
during
SE
synthesis
strongly
influence
evolution
Li|SE
interface
terms
microstructure,
interphase
composition,
morphology.
Indeed,
with
moderate
chlorine
content
(i.e.,
x
1.3)
obtained
slow
after
sintering,
atoms
located
on
surface
grains
as
interconnected
LiCl
nanoparticles
form
an
extended
LiCl-based
framework.
This
peculiar
microstructure
facilitates
migration
ions
cycling,
thus,
favouring
formation
LiCl-rich
layer
capable
improving
battery
performances.
Interdisciplinary materials,
Год журнала:
2022,
Номер
1(3), С. 417 - 433
Опубликована: Июнь 20, 2022
Abstract
The
accelerating
electrification
has
sparked
an
explosion
in
lithium‐ion
batteries
(LIBs)
consumption.
As
the
lifespan
declines,
substantial
LIBs
will
flow
into
recycling
market
and
promise
to
spawn
a
giant
system.
Nonetheless,
since
lack
of
unified
guiding
standard
nontraceability,
end‐of‐life
fallen
dilemma
low
rate,
poor
efficiency,
insignificant
benefits.
Herein,
tapping
summarizing
analyzing
current
status
challenges
LIBs,
this
outlook
provides
insights
for
future
course
full
lifecycle
management
proposing
gradient
utilization
recycling‐target
predesign
strategy.
Further,
we
acknowledge
some
recommendations
waste
anticipate
collaborative
effort
advance
sustainable
reliable
routes.
Technological Forecasting and Social Change,
Год журнала:
2023,
Номер
192, С. 122574 - 122574
Опубликована: Апрель 14, 2023
Hydrogen
can
be
recognized
as
the
most
plausible
fuel
for
promoting
a
green
environment.
Worldwide,
developed
and
developing
countries
have
established
their
hydrogen
research,
investment,
policy
frameworks.
This
analysis
of
610
peer-reviewed
journal
articles
from
last
50
years
provides
quantitative
impartial
insight
into
economy.
By
2030,
academics
business
professionals
believe
that
will
complement
other
renewable
energy
(RE)
sources
in
revolution.
study
conducts
an
integrative
review
by
employing
software
such
Bibliometrix
R-tool
VOSviewer
on
socio-economic
consequences
literature
derived
Scopus
database.
We
observed
research
focuses
multidisciplinary
concerns
generation,
storage,
transportation,
application,
feasibility,
development.
also
present
conceptual
framework
in-depth
well
interlinkage
concepts,
themes,
aggregate
dimensions,
to
highlight
hotspots
emerging
patterns.
In
future,
factors
permeation
leakage
management,
efficient
risk
assessment
studies,
blending,
techno-economic
feasibility
shall
play
critical
role
aspects
research.
Abstract
Lithium‐ion
batteries
(LIBs)
are
undoubtedly
the
current
working‐horse
in
almost
all
portable
electronic
devices,
electric
vehicles,
and
even
large‐scale
stationary
energy
storage.
Given
problems
faced
by
LIBs,
a
big
question
arises
as
to
which
battery(ies)
would
be
“Beyond
LIBs”
batteries.
Among
front‐runners,
lithium‐sulfur
(LSBs)
have
been
extensively
pursued
owing
their
intrinsically
high
density
extremely
low
cost.
Despite
steady
sometimes
exciting
progress
reported
on
sulfur
chemistry
cell
performance
at
laboratory
scales
over
past
decade,
one
of
major
bottlenecks
is
poor
cyclability.
In
this
perspective,
we
examine
key
challenges
opportunities
LSBs,
well
approaches
materials,
electrode/electrolyte
integration
levels
that
can
taken
transform
LSBs
from
front‐runner
real
leading
champion
pursuit
LIBs”.
While
new
mechanistic
insights
very
important,
propose
set
near‐future
research
directions
for
both
liquid
solid
state
where
currently
on‐going
parallel
pursuits
will
converging.
The
“liquid
current”
gradually
“solid
future”
expected
commercialization
coming
decade.
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