Light-Induced 1,3-Thiosulfonylation of β,γ-Unsaturated Ketones with Thiosulfonates

Organic Letters, Год журнала: 2024, Номер 26(32), С. 6798 - 6802

Опубликована: Авг. 7, 2024

Sulfur-containing compounds exhibit potent significance in drug molecules. Thiosulfonates as 1,3-thiosulfonylation reactants to olefins have yet be investigated. Herein, we report photoinduced 1,3-difunctionalization of β,γ-unsaturated ketones with thiosulfonates, which undergo a radical 1,2-acyl shift. The protocol features mild conditions, high regioselectivity, and 100% atom economy.

Язык: Английский

Silver-Catalyzed 1,2-Thiosulfonylation of Alkenes: Development of a Nucleophilic d₃-Methylthiolating Reagent

The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Сен. 25, 2024

Development of robust

Язык: Английский