Synthesis of 4‐Cyclobutene‐Isoquinolines From Aryl Imidates by Ru(II)‐Catalyzed Domino C–H Activation/Cyclization DOI

Min Wang,

Lei Gao, Maozhong Miao

и другие.

Applied Organometallic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 13, 2024

ABSTRACT A highly regioselective approach for constructing 4‐cyclobutene‐isoquinoline derivatives through ruthenium‐catalyzed domino C–H activation/cyclization of aryl imidates has been demonstrated. This new transformation tolerates various substituted functional groups on and propargylic monofluoroalkynes, resulting in the corresponding products being delivered moderate yields.

Язык: Английский

Synthesis of 3,4,5-trisubstituted phenols via Rh(iii)-catalyzed alkenyl C–H activation assisted by phosphonium cations DOI

Yan Mao,

Wenxi Chen, Changchang Li

и другие.

Chemical Communications, Год журнала: 2023, Номер 59(25), С. 3775 - 3778

Опубликована: Янв. 1, 2023

An efficient method for the construction of various 3,4,5-trisubstituted phenol derivatives has been achieved via Rh(III)-catalyzed coupling phosphonium cations with internal alkynes. This protocol shows good substrate compatibility, as an array structurally and electronically diverse compounds react efficiently up to 87% yield.

Язык: Английский

Процитировано

7
Synthetic Routes to Imidates and Their Applications in Organic Transformation: Recent Progress DOI Creative Commons
Andriani G. Chaidali, Ioannis N. Lykakis

European Journal of Organic Chemistry, Год журнала: 2023, Номер 26(39)

Опубликована: Авг. 29, 2023

Abstract Recent synthetic approaches and diverse applications of imidates are presented in this review. These motifs successfully used as intermediates organic transformations, such the synthesis N ‐heterocycles, natural products metal complexes with a potential catalytic effect. Consequently, many attempts have been made for development efficient facile methods past few years, continuum previous paths. A wide range compounds can be starting materials these syntheses, including nitriles, isocyanides, amides etc. which through simple flexible processes converted to desired imidates. Herein, an exploration recent routes their transformations has categorized summarized.

Язык: Английский

Процитировано

6
Tunable Rh(III)-Catalyzed C(sp2)–H Bond Functionalization of Aryl Imidates with Cyclic 1,3-Diones: Strategic Use of Directing Groups DOI

E Junnan,

Luohe Wang,

Jing Zeng

и другие.

Organic Letters, Год журнала: 2024, Номер 26(37), С. 7885 - 7890

Опубликована: Сен. 6, 2024

A tunable Rh(III)-catalyzed C(sp

Язык: Английский

Процитировано

1
Synthesis of 4‐Cyclobutene‐Isoquinolines From Aryl Imidates by Ru(II)‐Catalyzed Domino C–H Activation/Cyclization DOI

Min Wang,

Lei Gao, Maozhong Miao

и другие.

Applied Organometallic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 13, 2024

ABSTRACT A highly regioselective approach for constructing 4‐cyclobutene‐isoquinoline derivatives through ruthenium‐catalyzed domino C–H activation/cyclization of aryl imidates has been demonstrated. This new transformation tolerates various substituted functional groups on and propargylic monofluoroalkynes, resulting in the corresponding products being delivered moderate yields.

Язык: Английский

Процитировано

0