Angewandte Chemie,
Год журнала:
2024,
Номер
136(14)
Опубликована: Янв. 5, 2024
Abstract
Mechanochemical
reactions
offer
methodological
and
environmental
advantages
for
chemical
synthesis,
constantly
attracting
attention
within
the
scientific
community.
Besides
unmistakable
sustainability
advantages,
conditions
under
which
mechanochemical
occur,
namely
solventless
conditions,
sometimes
facilitate
isolation
of
otherwise
labile
or
inaccessible
products.
Despite
these
limited
knowledge
exists
regarding
mechanisms
types
intermediates
involved.
Nevertheless,
in
an
expanding
number
cases,
ex
situ
monitoring
techniques
have
allowed
observation,
characterization,
reaction
transformations.
In
this
Minireview,
we
present
a
series
examples
reactive
been
detected
spanning
organic,
organometallic,
inorganic,
materials
chemistry.
Many
were
stabilized
by
non‐covalent
interactions,
played
pivotal
role
guiding
We
believe
that
uncovering
understanding
such
instances,
growing
mechanochemistry
community
could
find
novel
opportunities
catalysis
discover
new
while
achieving
simplification
design.
Journal of Chemical Research,
Год журнала:
2025,
Номер
49(3)
Опубликована: Май 1, 2025
Mechanochemistry,
a
branch
of
chemistry
that
involves
the
application
mechanical
energy
to
induce
chemical
reactions,
has
garnered
significant
attention
for
its
unique
approach
synthesis
and
materials
processing.
This
review
explores
fundamental
principles
mechanochemistry,
including
impact
forces
on
crystalline
structures
resultant
transformations.
Recent
advancements
highlight
field’s
potential
in
reducing
reliance
hazardous
solvents,
improving
efficiency,
supporting
sustainable
practices.
Mechanochemistry’s
applications
extend
recycling
resource
recovery,
particularly
context
valuable
metals
materials,
aligning
with
green
circular
economy.
Despite
benefits,
field
faces
challenges
related
scalability,
process
control,
material
limitations.
Future
directions
include
integrating
advanced
technologies,
exploring
new
applications,
enhancing
understanding
address
these
challenges.
Mechanochemistry
stands
as
transformative
evolving
area
research
implications
scientific
progress
industrial
promising
drive
innovation
sustainability
various
sectors.
Angewandte Chemie,
Год журнала:
2024,
Номер
136(14)
Опубликована: Янв. 5, 2024
Abstract
Mechanochemical
reactions
offer
methodological
and
environmental
advantages
for
chemical
synthesis,
constantly
attracting
attention
within
the
scientific
community.
Besides
unmistakable
sustainability
advantages,
conditions
under
which
mechanochemical
occur,
namely
solventless
conditions,
sometimes
facilitate
isolation
of
otherwise
labile
or
inaccessible
products.
Despite
these
limited
knowledge
exists
regarding
mechanisms
types
intermediates
involved.
Nevertheless,
in
an
expanding
number
cases,
ex
situ
monitoring
techniques
have
allowed
observation,
characterization,
reaction
transformations.
In
this
Minireview,
we
present
a
series
examples
reactive
been
detected
spanning
organic,
organometallic,
inorganic,
materials
chemistry.
Many
were
stabilized
by
non‐covalent
interactions,
played
pivotal
role
guiding
We
believe
that
uncovering
understanding
such
instances,
growing
mechanochemistry
community
could
find
novel
opportunities
catalysis
discover
new
while
achieving
simplification
design.
