Photothermal Catalysts, Light and Heat Management: From Materials Design to Performance Evaluation DOI Open Access
Enrique V. Ramos‐Fernández, Alejandra Rendón‐Patiño, Diego Mateo

и другие.

Advanced Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 21, 2025

Abstract Photothermal catalysis, a frontier in heterogeneous combines light‐driven and thermally enhanced chemical reactions to optimize energy use reaction efficiencies at catalytic active sites. By leveraging photothermal conversion, this approach links renewable sources with industrial processes, offering significant potential for sustainable applications. This review categorizes catalysis into three types: thermocatalysis, photocatalysis, photo‐thermo coupling catalysis. Each category is analyzed, emphasizing mechanisms, performance factors, the role of advanced materials such as plasmonic nanoparticles, semiconductors, hybrid composites enhancing light absorption, thermal distribution, stability. Key challenges include achieving uniform photonic distributions within reactors developing accurate evaluation metrics. Applications CO₂ reduction, ammonia synthesis, plastic upcycling highlight environmental relevance technology. The identifies limitations suggests innovations design energy‐storing mechanisms enable continuous processes. Future directions emphasize catalysis's transform systems advance green production. synthesis aims guide research foster practical adoption technologies an scale.

Язык: Английский

Inverse design workflow discovers hole-transport materials tailored for perovskite solar cells DOI
Jianchang Wu, Luca Torresi, Manli Hu

и другие.

Science, Год журнала: 2024, Номер 386(6727), С. 1256 - 1264

Опубликована: Дек. 12, 2024

The inverse design of tailored organic molecules for specific optoelectronic devices high complexity holds an enormous potential but has not yet been realized. Current models rely on large data sets that generally do exist specialized research fields. We demonstrate a closed-loop workflow combines high-throughput synthesis semiconductors to create datasets and Bayesian optimization discover new hole-transporting materials with properties solar cell applications. predictive were based molecular descriptors allowed us link the structure these their performance. A series high-performance identified from minimal suggestions achieved up 26.2% (certified 25.9%) power conversion efficiency in perovskite cells.

Язык: Английский

Процитировано

29

Dual‐Strategy Tailoring Molecular Structures of Dopant‐Free Hole Transport Materials for Efficient and Stable Perovskite Solar Cells DOI
Gang Xie,

Wang Jing,

Shun‐Gao Yin

и другие.

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(20)

Опубликована: Март 19, 2024

Abstract Dopant‐free hole transport materials (HTMs) are ideal for highly efficient and stable n‐i‐p perovskite solar cells (PSCs), but most current design strategies tailoring the molecular structures of HTMs limited to single strategy. Herein, four based on dithienothiophenepyrrole (DTTP) core devised through dual‐strategy methods combining conjugate engineering side chain engineering. DTTP‐ThSO with ester alkyl that can form six‐membered ring by S⋅⋅⋅O noncovalent conformation lock thiophene in backbone shows good planarity, high‐quality film, matching energy level high mobility, as well strong defect passivation ability. Consequently, a remarkable power conversion efficiency (PCE) 23.3 % nice long‐term stability is achieved dopant‐free DTTP‐ThSO‐based PSCs, representing one highest values un‐doped organic PSCs. Especially, fill factor (FF) 82.3 value small HTMs‐based PSCs date. Moreover, devices have an excellent PCE 20.9 large‐area (1.01 cm 2 ) devices. This work clearly elucidates structure‐performance relationships offers practical approach designing high‐performance

Язык: Английский

Процитировано

19

Recent Progress and Advances of Perovskite Crystallization in Carbon‐Based Printable Mesoscopic Solar Cells DOI Open Access
Junwei Xiang,

Chuanzhou Han,

Yanjie Cheng

и другие.

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 15, 2025

Carbon-based printable mesoscopic solar cells (p-MPSCs) offer significant advantages for industrialization due to their simple fabrication process, low cost, and scalability. Recently, the certified power conversion efficiency of p-MPSCs has exceeded 22%, drawing considerable attention from community. However, key challenge in improving device performance is achieving uniform high-quality perovskite crystallization within mesoporous structure. This review highlights recent advancements p-MPSCs, with an emphasis on controlling kinetics regulating morphology confined mesopores. It first introduces offering a solid foundation understanding behavior. Additionally, summarizes mechanisms crystal nucleation growth, explaining how these processes influence quality perovskites. Furthermore, commonly applied strategies enhancing quality, such as additive engineering, solvent evaporation controlling, post-treatment techniques, are also explored. Finally, proposes several potential suggestions aimed at further refining crystallization, inspiring continued innovation address current limitations advance development p-MPSCs.

Язык: Английский

Процитировано

6

Delafossite as hole transport layer a new pathway for efficient perovskite-based solar sells: Insight from experimental, DFT and numerical analysis DOI
Amal Bouich, Joeluis Cerutti Torres, Hasnae Chfii

и другие.

Solar Energy, Год журнала: 2022, Номер 250, С. 18 - 32

Опубликована: Дек. 26, 2022

Язык: Английский

Процитировано

46

Side‐Chain Methylthio‐Based Position Isomerism of Hole‐Transport Materials for Perovskite Solar Cells: From Theoretical Simulation to Experimental Characterization DOI
Ruiqin Wang, Chengyu Wu, Jiayi Qi

и другие.

Advanced Functional Materials, Год журнала: 2023, Номер 33(14)

Опубликована: Янв. 18, 2023

Abstract Hole transporting materials (HTMs) are imperative for promoting the development of perovskite solar cells (PSCs). Herein, three isomers RQ4, RQ5, and RQ6 constructed by methylthio (‐SMe) group in para, meta, adjacent sites terminal benzene on side‐chain carbazole‐arylamine derivatives based HTMs, investigated means theoretical simulation experimental characterization. As a result simulation, isomeric HTMs RQ4‐RQ6 exhibit appropriate highest occupied molecular orbital /lowest unoccupied energy levels good optical properties. However, comparison with RQ4 better planar configuration closer stacking may be beneficial to promote hole coupling, interface interaction, charge transfer at perovskite/HTMs interface. In order verify accuracy model, designed synthesized used assemble PSCs devices. (20.07%) RQ5 (18.18%) devices, devices has higher power conversion efficiency 21.03% because its high mobility, film formation ability, large The results confirm reliability provide an effective strategy obtain potential through isomerization functional groups.

Язык: Английский

Процитировано

33

A hot carrier perovskite solar cell with efficiency exceeding 27% enabled by ultrafast hot hole transfer with phthalocyanine derivatives DOI

Shaokuan Gong,

Geping Qu,

Ying Qiao

и другие.

Energy & Environmental Science, Год журнала: 2024, Номер 17(14), С. 5080 - 5090

Опубликована: Янв. 1, 2024

Illustration of hot hole transfer through interfacial S–Pb interactions, and a peak efficiency 27.30% was achieved under 5.9 suns via ultrafast extraction.

Язык: Английский

Процитировано

17

Advanced technical strategies for upscaling perovskite photovoltaics from cells to modules DOI
Xiaojia Zhao, Weiyin Gao, He Dong

и другие.

Nano Energy, Год журнала: 2024, Номер 128, С. 109933 - 109933

Опубликована: Июнь 29, 2024

Язык: Английский

Процитировано

17

Decoding Polymeric Additive‐Driven Self‐Healing Processes in Perovskite Solar Cells from Chemical and Physical Bonding Perspectives DOI
Jeong‐Seok Nam, Jinmyung Choi, Jang Woo Lee

и другие.

Advanced Energy Materials, Год журнала: 2024, Номер 14(12)

Опубликована: Янв. 26, 2024

Abstract This review addresses the self‐healing effects in perovskite solar cells (PSCs), emphasizing significance of chemical and physical bonding as core mechanisms. Polymeric additives play a vital role inducing phenomena along with intrinsic properties materials, both which are discussed herein. As relatively underexplored area, effect induced by polymeric PSCs is reviewed from perspective. The bonds involved include isocyanate, disulfide, carboxylic acid groups. related to primarily hydrogen chelation. Self‐healing flexible devices extends their lifespan improves mechanical robustness against environmental stressors. discussion delves into initiation methods for self‐healing, conditions required, recovery‐rate profiles. not only catalogs various approaches but also considers fundamental limitations potential this phenomenon PSCs. In addition, insights an outlook on perovskite‐based optoelectronics provided, offering guidance future research applications.

Язык: Английский

Процитировано

15

Interfacial Layer Materials with a Truxene Core for Dopant‐Free NiOx‐Based Inverted Perovskite Solar Cells DOI

Rajarathinam Ramanujam,

Hsiang‐Lin Hsu,

Zhong‐En Shi

и другие.

Small, Год журнала: 2024, Номер 20(33)

Опубликована: Март 7, 2024

Nickel oxide (NiO

Язык: Английский

Процитировано

13

Perovskite photovoltaic interface: From optimization towards exemption DOI
Feifei Zhang,

Dexu Zheng,

Dongqi Yu

и другие.

Nano Energy, Год журнала: 2024, Номер 124, С. 109503 - 109503

Опубликована: Март 16, 2024

Язык: Английский

Процитировано

13