Radical-mediated carboselenation of terminal alkynes under mild conditions DOI

Chixiao Ma,

Jingli Xie,

Xianghua Zeng

и другие.

Organic Chemistry Frontiers, Год журнала: 2022, Номер 9(16), С. 4441 - 4446

Опубликована: Янв. 1, 2022

Metal-free radical carboselenation of terminal alkynes is developed for the synthesis ( E )-γ-seleno-substituted allyl nitriles with excellent regioselectivity and stereoselectivity.

Язык: Английский

Synthesis of β‐Hydroxyselenides via Electrochemical Hydroxyselenenylation of Alkenes with Diselenides and H2O DOI
Weiwei Li, Yingyuan Hu,

Junsheng Hou

и другие.

ChemistrySelect, Год журнала: 2024, Номер 9(5)

Опубликована: Фев. 2, 2024

Abstract A practical electrochemical method for the synthesis of β‐hydroxyselenides has been developed under an external oxidant‐free condition at room temperature air from alkenes with diselenides and H 2 O. radical mechanism is proposed this transformation gram‐scale reactions demonstrate practicability reaction.

Язык: Английский

Процитировано

3
Electrochemical direct C–H mono and bis-chalcogenation of indolizine frameworks under oxidant-free conditions DOI

Amreen Chouhan,

Kusum Ucheniya,

Lalit Yadav

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2023, Номер 21(37), С. 7643 - 7653

Опубликована: Янв. 1, 2023

Herein, we disclosed a sustainable electrochemical approach for site-selective C-H mono and bis-chalcogenation (sulfenylation or selenylation) of indolizine frameworks. Diversely functionalized disulfides diselenides possessing EDGs EWGs were successfully reacted with variety indolizines to directly access sulfenylated/selenylated in 40-96% yields. A mechanistic radical pathway was also validated control experiments cyclic voltammogram data.

Язык: Английский

Процитировано

7
Ferrocene-Mediated Electrochemical Polycyclization of Malonates DOI

Antoine Lefevre,

Régis Guillot,

C. Kouklovsky

и другие.

Organic Letters, Год журнала: 2024, Номер 26(35), С. 7403 - 7407

Опубликована: Авг. 27, 2024

We report access to the core of biologically relevant aromatic abietane diterpenoids and formal synthesis podocarpic lambertic acids or γ-lactones via an electrochemical bicyclization process initiated by ferrocene-mediated anodic oxidation a malonate single electron-transfer. This approach permits escaping use excess oxidants such as Mn(OAc)3 associated complicated purification.

Язык: Английский

Процитировано

2
Photocatalytic synthesis of 10-phenanthrenolsviaintramolecular cycloaromatization under oxidant-free conditions DOI
Junli Li, Xiaoying Niu, Yifan Song

и другие.

Organic Chemistry Frontiers, Год журнала: 2022, Номер 9(22), С. 6156 - 6164

Опубликована: Янв. 1, 2022

A novel tandem photocycloaddition/dehydrogenative aromatization with hydrogen evolution of ortho biaryl-appended 1,3-dicarbonyl compounds for the synthesis 10-phenanthrenol via cobaloxime catalysis is disclosed.

Язык: Английский

Процитировано

12
Radical-mediated carboselenation of terminal alkynes under mild conditions DOI

Chixiao Ma,

Jingli Xie,

Xianghua Zeng

и другие.

Organic Chemistry Frontiers, Год журнала: 2022, Номер 9(16), С. 4441 - 4446

Опубликована: Янв. 1, 2022

Metal-free radical carboselenation of terminal alkynes is developed for the synthesis ( E )-γ-seleno-substituted allyl nitriles with excellent regioselectivity and stereoselectivity.

Язык: Английский

Процитировано

10