Recent advances in the (3+2) cycloaddition of azomethine ylide
New Journal of Chemistry,
Год журнала:
2023,
Номер
47(19), С. 8997 - 9034
Опубликована: Янв. 1, 2023
We
have
tried
to
demonstrate
[3+2]
cycloaddition
of
azomethine
ylides
for
the
synthesis
several
bioactive
compounds.
Different
methodologies,
including
metal-catalyzed
as
well
metal-free
asymmetric
and
racemic
synthesis,
been
explained.
Язык: Английский
Visible‐Light‐Mediated Cycloaddition of Azobenzenes and Nonstabilized Azomethine Ylides to Access 1,2,4‐Triazolidines
Advanced Synthesis & Catalysis,
Год журнала:
2023,
Номер
365(23), С. 4303 - 4309
Опубликована: Окт. 24, 2023
Abstract
A
visible‐light‐mediated
cycloaddition
of
azobenzenes
and
nonstabilized
azomethine
ylides
has
been
developed
to
access
1,2,4‐triazolidines.
With
readily
available
organic
dye
rose
bengal
as
a
photocatalyst
alkyl
tertiary
amines
precursors
for
ylides,
the
reaction
proceeded
smoothly
under
visible
light
irradiation
at
room
temperature,
affording
various
4‐alkyl‐1,2‐diaryl‐1,2,4‐triazolidines
with
yields
up
96%.
Preliminarily
mechanistic
studies
suggest
that
are
formed
in
situ
through
photoredox
catalysis.
Язык: Английский
Recent advances in the synthesis of highly substituted imidazolidines
RSC Advances,
Год журнала:
2024,
Номер
14(42), С. 30758 - 30806
Опубликована: Янв. 1, 2024
In
this
highlight,
recent
advances
in
the
synthesis
of
highly
substituted
imidazolidines,
chiral
imidazolidines
with
high
diastereoselectivities
and
enantioselectivities,
bis-imidazolidines,
spiro-imidazolidines
are
presented.
Язык: Английский