Materials Containing Single‐, Di‐, Tri‐, and Multi‐Metal Atoms Bonded to C, N, S, P, B, and O Species as Advanced Catalysts for Energy, Sensor, and Biomedical Applications

Advanced Science, Год журнала: 2024, Номер 11(33)

Опубликована: Июль 1, 2024

Abstract Modifying the coordination or local environments of single‐, di‐, tri‐, and multi‐metal atom (SMA/DMA/TMA/MMA)‐based materials is one best strategies for increasing catalytic activities, selectivity, long‐term durability these materials. Advanced sheet supported by metal atom‐based have become a critical topic in fields renewable energy conversion systems, storage devices, sensors, biomedicine owing to maximum utilization efficiency, precisely located centers, specific electron configurations, unique reactivity, precise chemical tunability. Several offer excellent support are attractive applications energy, medical research, such as oxygen reduction, production, hydrogen generation, fuel selective detection, enzymatic reactions. The strong metal–metal metal–carbon with metal–heteroatom (i.e., N, S, P, B, O) bonds stabilize optimize electronic structures atoms due interfacial interactions, yielding activities. These provide models understanding fundamental problems multistep This review summarizes substrate structure‐activity relationship different active sites based on experimental theoretical data. Additionally, new synthesis procedures, physicochemical characterizations, biomedical discussed. Finally, remaining challenges developing efficient SMA/DMA/TMA/MMA‐based presented.

Язык: Английский

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Atomically Dispersed Cu Active Centers: Local Structure and Mechanism Modulation for Carbon Dioxide Reduction

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 10, 2025

Abstract Reducing carbon dioxide （CO 2 ）to high‐value products using green renewable energy is a promising approach for addressing and greenhouse effect issues. Consequently, electrocatalytic CO reduction reaction (CO RR) technology has become current research hotspot. Since the discovery of high activity selectivity copper in RR, atomically dispersed Cu catalysts have garnered widespread attention due to their efficient atom utilization, unique electronic structure, outstanding catalytic performance. However, great challenge remains providing rational catalyst design principles achieve regulation product distribution. A clear understanding materials an in‐depth interpretation mechanism as well elucidation strategy progress toward different are keys building solving above problem. Therefore, this review starts with introduction advanced characterization techniques reveal structure mechanisms. Then, various optimization strategies applications producing targeted summarized discussed. Finally, perspectives on RR field future development offered.

Язык: Английский

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Recent progress in Cu-based electrocatalysts for CO2 reduction

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159210 - 159210

Опубликована: Янв. 1, 2025

Язык: Английский

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Synergistic effect of oxygen vacancies and doped sulfur over BiOBr for efficient visible photocatalytic removal of dyes

Applied Surface Science, Год журнала: 2023, Номер 649, С. 159169 - 159169

Опубликована: Дек. 19, 2023

Язык: Английский

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Rational design of highly efficient carbon-based materials for electrochemical CO2 reduction reaction

Fuel, Год журнала: 2023, Номер 357, С. 129760 - 129760

Опубликована: Сен. 26, 2023

Язык: Английский

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Single atom Cu-N-C catalysts for the electro-reduction of CO2 to CO assessed by rotating ring-disc electrode

Journal of Energy Chemistry, Год журнала: 2023, Номер 88, С. 169 - 182

Опубликована: Сен. 20, 2023

The electrochemical CO2 reduction reaction (CO2RR) to controllable chemicals is considered as a promising pathway store intermittent renewable energy. Herein, set of catalysts based on copper-nitrogen-doped carbon xerogel (Cu-N-C) are successfully developed varying the copper amount and nature precursor, for efficient CO2RR. electrocatalytic performance Cu-N-C materials assessed by rotating ring-disc electrode (RRDE), technique still rarely explored For comparison, products also characterized online gas chromatography in H-cell. as-synthesized found be active highly CO selective at low overpotentials (from −0.6 −0.8 V vs. RHE) 0.1 M KHCO3, while H2 from competitive water appears larger (−0.9 RHE). optimum acetate-derived catalyst containing Cu-N4 moieties exhibits CO2-to-CO turnover frequency 997 h−1 −0.9 RHE with H2/CO ratio 1.8. These results demonstrate that RRDE configuration can used feasible approach identifying electrolysis

Язык: Английский

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Machine learning accelerates the screening of single-atom catalysts towards CO2 electroreduction

Applied Catalysis A General, Год журнала: 2024, Номер 676, С. 119674 - 119674

Опубликована: Март 13, 2024

Язык: Английский

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Engineering CuIn microenvironment for efficient acidic electrochemical CO2 reduction to CO

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125244 - 125244

Опубликована: Март 1, 2025

Язык: Английский

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Efficient Cu3 clusters on MXene (Ti2CO2) for CO electroreduction

Applied Surface Science, Год журнала: 2025, Номер unknown, С. 163118 - 163118

Опубликована: Март 1, 2025

Язык: Английский

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C−C Coupling in CO₂ Electroreduction on Single Cu‐Modified Covalent Triazine Frameworks: A Static and Dynamic Density Functional Theory Study

ChemElectroChem, Год журнала: 2024, Номер 11(6)

Опубликована: Янв. 26, 2024

Abstract The electrochemical reduction of CO 2 into C 2+ products represents a promising solution to completing the carbon cycle, thereby fostering sustainable energy supply. Single‐atom electrocatalysts (SAECs) have garnered significant attention as efficient for reaction. Herein, we carried out first‐principles study on mechanism C−C bond formation single‐Cu‐atom‐modified covalent triazine frameworks (Cu‐CTFs), which are platform SAECs. Static density functional calculations indicated that dimerization CO, is main bulk Cu metals, was not favorable Cu‐CTFs because lack adjacent sites co‐adsorption molecules. Rather than dimerization, reaction between adsorbed *CHO and produce *COCHO has relatively low barrier. Constrained ab initio molecular dynamics analyses revealed bond‐forming proceeds via insertion at intermediate, modest activation 0.09 eV. Specifically, when molecule constrained be brought close *CHO, occurs distance 1.8 Å. This transition step this formation.

Язык: Английский

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