Journal of Materials Chemistry C,
Год журнала:
2024,
Номер
13(5), С. 2172 - 2182
Опубликована: Дек. 3, 2024
Carbon
polymer
dots
(CPDs)
have
favourable
properties
such
as
broad
spectral
absorption,
strong
photoluminescence,
low
toxicity,
and
high
specific
surface
area.
Molecules,
Год журнала:
2025,
Номер
30(4), С. 774 - 774
Опубликована: Фев. 7, 2025
Carbon
dots
(CDs),
a
versatile
class
of
fluorescent
carbon-based
nanomaterials,
have
attracted
widespread
attention
due
to
their
exceptional
optical
properties,
biocompatibility,
and
cost-effectiveness.
Their
applications
span
biomedicine,
optoelectronics,
smart
food
packaging,
yet
large-scale
synthesis
remains
significant
challenge.
This
review
categorizes
methods
into
liquid-phase
(hydrothermal/solvothermal,
microwave-assisted,
magnetic
hyperthermia,
aldol
condensation
polymerization),
gas-phase
(plasma
synthesis),
solid-phase
(pyrolysis,
oxidation/carbonization,
ball
milling),
emerging
techniques
(microfluidic,
ultrasonic,
molten-salt).
Notably,
microwave-assisted
solid-state
show
promise
for
industrial
production
scalability
efficiency.
Despite
these
advances,
challenges
persist
in
optimizing
reproducibility,
reducing
energy
consumption,
developing
purification
quality
control
strategies.
Addressing
issues
will
be
critical
transitioning
CDs
from
laboratory
research
real-world
applications.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(48)
Опубликована: Авг. 20, 2024
Abstract
Carbon
dots
(CDs)
have
rapidly
emerged
as
a
new
family
of
carbon‐based
nanomaterials
since
their
initial
discovery
two
decades
ago.
Numerous
appealing
properties,
such
precursor
and
synthesis
process
flexibility,
tunable
photoluminescence,
good
biocompatibility,
enabled
widespread
applications
in
sensing,
catalysis,
energy,
biomedical
fields.
As
the
field
expands,
notable
efforts
recently
focused
on
mechanistically
elucidating
structural
formation
optical
behavior
CDs.
However,
absence
“clean”
CDs
presents
major
obstacle
to
achieving
solid
understanding
these
aspects.
Often,
claimed
are,
fact,
mixture
small
molecules,
oligomers,
nano‐sized
aggregates,
or
even
microparticles.
Such
coexistence
impurities
markedly
impacts
physicochemical
properties
resulting
CD‐based
mixtures,
hampering
resolution
key
mechanistic
questions.
Here,
we
aim
address
this
fundamental
shortcoming
field,
going
beyond
customary
focus
existing
reviews
that
predominantly
cover
synthesis,
performance,
application
prospects.
We
begin
with
an
overview
CD
then
thoroughly
examine
purification
methods,
including
filtration,
dialysis,
electrophoresis,
chromatography.
The
insights
provided
here
will
guide
researchers
towards
obtaining
high‐quality
CDs,
employing
proper
combinations
available
tools,
ultimately
paving
way
for
more
demanding
applications.
C – Journal of Carbon Research,
Год журнала:
2024,
Номер
10(3), С. 60 - 60
Опубликована: Июль 5, 2024
Carbon
dots
(CDs)
have
emerged
as
a
promising
class
of
carbon-based
nanomaterials
due
to
their
unique
properties
and
versatile
applications.
(CDs),
also
known
carbon
quantum
(CQDs)
or
graphene
(GQDs),
are
nanoscale
materials
with
dimensions
typically
less
than
10
nanometers.
They
exhibit
intriguing
optical,
electronic,
chemical
properties,
making
them
attractive
for
wide
range
applications,
including
sensing,
imaging,
catalysis,
energy
conversion,
among
many
others.
Both
bottom-up
top-down
synthesis
approaches
utilized
the
dots,
each
method
impacting
physicochemical
characteristics.
can
diverse
structures,
amorphous,
crystalline,
hybrid
depending
on
precursor
used.
CDs
structures
modified
oxygen,
polymer-based,
amino
groups
surface.
These
influence
optical
electronic
such
photoluminescence,
bandgap,
charge
carrier
mobility,
tunable
specific
Various
characterization
methods
HRTEM,
XPS,
analysis
(PL,
UV)
used
determine
structure
CDs.
cutting-edge
fluorescent
remarkable
qualities
biocompatibility,
low
toxicity,
environmental
friendliness,
high
water
solubility,
photostability.
easily
adjustable
in
terms
highly
various
fields.
find
applications
bio-imaging,
nanomedicine,
drug
delivery,
solar
cells,
photocatalysis,
electrocatalysis,
other
related
areas.
hold
great
promise
field
cell
technology
yield
(CQY),
excellent
separation.
Molecules,
Год журнала:
2024,
Номер
29(21), С. 5138 - 5138
Опубликована: Окт. 30, 2024
Approximately
one-third
of
the
world's
food
production,
i.e.,
1.43
billion
tons,
is
wasted
annually,
resulting
in
economic
losses
nearly
USD
940
and
undermining
system
sustainability.
This
waste
depletes
resources,
contributes
to
greenhouse
gas
emissions,
negatively
affects
security
prices.
Although
traditional
packaging
preserves
quality,
it
cannot
satisfy
demands
extended
shelf
life,
safety,
Consequently,
active
using
biopolymer
matrices
containing
antioxidants
antimicrobials
a
promising
solution.
review
examines
current
advancements
integration
carbon
quantum
dots
(CQDs)
into
biopolymer-based
packaging,
focusing
on
their
antioxidant
antimicrobial
properties.
CQDs
provide
unique
advantages
over
nanoparticles
natural
compounds,
including
high
biocompatibility,
tunable
surface
functionality,
environmental
explores
mechanisms
through
which
impart
activities,
synthesis
methods,
functionalization
optimize
efficacy
matrices.
Recent
studies
have
highlighted
that
CQD-enhanced
biopolymers
maintain
biodegradability
with
enhanced
functions.
Additionally,
potential
challenges,
such
as
toxicity,
regulatory
considerations,
scalability
are
discussed,
offering
insights
future
research
directions
industrial
applications.
demonstrates
CQD-incorporated
transform
aligning
sustainability
goals
advancing
preservation
technologies.
Nanotechnology
sparks
discussions
and
concerns
about
the
impacts
of
new
nanomaterials
on
health
environment.
It
holds
importance
in
various
domains
due
to
its
unique
struc-tures.
Carbon
dots
(C-dots)
are
versatile
with
applications
bioimaging,
sensing,
catalysis,
polymers,
solar
cells,
more.
They
offer
desirable
characteristics
such
as
stability,
cost-effectiveness,
biocompatibility,
high
photoluminescent
quantum
yield.
C-dots
have
potential
replace
expensive
fluorophores
cells.
catego-rized
carbon
dots,
graphene
carbonized
polymer
dots.
outstanding
optical
photoelectric
properties
low
toxicity.
Bottom-up
top-down
approaches
used
for
synthesis
(CDs),
each
method
im-pacting
their
physicochemical
characteristics.
The
choice
depends
de-sired
application
requirements.
Researchers
combine
these
methods
ex-plore
enhance
efficiency
tailor
CD
properties.
CDs
di-verse
chemical
structures
modified
oxygen,
polymer-based,
or
amino
groups
surface.
Various
characterization
HRTEM,
XPS,
analysis
(PL,
UV)
determine
structure.
(CDs)
cutting-edge
fluorescent
nano-materials
remarkable
qualities
toxicity,
environmental
friendliness,
water
solubility,
photo-stability.
easily
adjustable
terms
properties,
making
them
highly
fields.
find
bio-imaging,
nanomedicine,
drug
delivery,
LEDs,
photo-catalysis,
elec-tro-catalysis,
other
related
areas.
Carbon
dots
(CDs)
are
a
type
of
carbon-based
nanoparticle
(NP)
that
have
risen
in
popularity
due
to
their
unique
tuneable
physicochemical
and
optical
properties.