Pushing Boundaries: What’s Next in Metal-Free C–H Functionalization for Sulfenylation?

Topics in Current Chemistry, Год журнала: 2024, Номер 382(2)

Опубликована: Апрель 12, 2024

Язык: Английский

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Purple‐Light Promoted Thiol‐ene Reaction of Alkenes

Advanced Synthesis & Catalysis, Год журнала: 2023, Номер 365(24), С. 4623 - 4633

Опубликована: Ноя. 2, 2023

Abstract Here we present a catalyst‐free protocol for the purple light‐mediated anti ‐Markovnikov functionalization of alkenes with thiols. Crucial to generation thiyl radical was formation key photo‐active complex. More than 30 thioether products were obtained, demonstrating tolerance towards different functional groups and scalability up 5 mmol alkene. Two reaction conditions have been developed, varying both solvent amount thiol. Depending on alkene structure, water can be used as an alternative dichloromethane solvent, thus increasing sustainability whole process.

Язык: Английский

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Visible-light-induced hydrosulfonylation of alkynes driven by electron-donor–acceptor (EDA) complexes

Tetrahedron Letters, Год журнала: 2024, Номер 153, С. 155368 - 155368

Опубликована: Ноя. 16, 2024

Язык: Английский

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Synthetic developments on the preparation of thioethers via photocatalysis

New Journal of Chemistry, Год журнала: 2024, Номер 49(3), С. 651 - 668

Опубликована: Дек. 10, 2024

Sulfide is a widely occurring natural product and pharmaceutically active compound. This review highlights the photochemically mediated thioether synthesis reactions, with emphasis on catalytic mechanism.

Язык: Английский

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