Inorganic Chemistry,
Год журнала:
2024,
Номер
63(26), С. 12089 - 12099
Опубликована: Июнь 20, 2024
The
stabilization
of
simple,
highly
reactive
cationic
species
in
molecular
complexes
represents
an
important
strategy
to
isolate
and
characterize
compounds
with
uncommon
or
even
unprecedented
structural
motifs
properties.
Here
we
report
the
synthesis,
isolation,
full
characterization
chlorido-bismuth
dications,
stabilized
only
by
monodentate
dimethylsulfoxide
(dmso)
ligands:
[BiCl(dmso)
Angewandte Chemie,
Год журнала:
2024,
Номер
136(41)
Опубликована: Июль 11, 2024
Abstract
Establishing
unprecedented
types
of
bonding
interactions
is
one
the
fundamental
challenges
in
synthetic
chemistry,
paving
way
to
new
(electronic)
structures,
physicochemical
properties,
and
reactivity.
In
this
context,
unsupported
element‐element
are
particularly
noteworthy
since
they
offer
pristine
scientific
information
about
newly
identified
structural
motif.
Here
we
report
synthesis,
isolation,
full
characterization
heterobimetallic
Bi/Pt
compound
[Pt(PCy
3
)
2
(BiMe
)(SbF
6
)]
(
1
),
bearing
first
transition
metal→bismuth
donor/acceptor
interaction
as
its
key
surprisingly
robust,
electronic
spectra
interpreted
a
fully
relativistic
approach,
it
reveals
an
reactivity
towards
H
.
Dalton Transactions,
Год журнала:
2024,
Номер
54(3), С. 915 - 919
Опубликована: Дек. 13, 2024
A
hydrogen-bridged
bis(silylene)
complex
showed
high
performance
in
the
activation
of
small
molecules
via
dehydrogenative
O–H
bond
cleavage
or
hydro-bis(silylation).
Royal Society of Chemistry eBooks,
Год журнала:
2024,
Номер
unknown, С. 193 - 253
Опубликована: Дек. 6, 2024
Main
group
elements
have
recently
emerged
as
benign
and
cost-effective
alternatives
to
transition
metals
in
organometallic
chemistry.
By
finely
tuning
their
electronic
structure,
these
can
engage
substrate
coordination,
activate
small
molecules,
even
catalyse
redox
reactions,
mirroring
the
behaviour
of
metals.
This
book
chapter
aims
summarize
a
relatively
underexplored
area
within
main
metal
chemistry:
ability
undergo
photoinduced
processes
such
reactivity,
rearrangements,
radical
formation.
