Russian Journal of Physical Chemistry A, Год журнала: 2024, Номер 98(13), С. 3107 - 3115
Опубликована: Дек. 1, 2024
Язык: Английский
Dalton Transactions, Год журнала: 2024, Номер 53(25), С. 10403 - 10415
Опубликована: Янв. 1, 2024
Metal-organic frameworks (MOFs) have emerged as promising electrode materials for supercapacitors (SCs) due to their highly porous structures, tunable chemical compositions, and diverse morphologies. However, applications are hindered by low conductivity poor cycling performance. A novel approach resolving this issue involves the growth of layered double hydroxides (LDHs) using MOFs efficient templates or precursors material preparation. This method effectively enhances stability, electrical conductivity, mass transport ability MOFs. The MOF-derived LDH exhibits a well-defined micro-/nano-structure, facilitating dispersion active sites preventing aggregation LDHs. Firstly, paper introduces synthesis strategies converting into Subsequently, recent research progress in LDHs encompassing pristine powders, composites, LDH-based arrays, along with SCs, is overviewed. Finally, challenges associated potential solutions discussed.
Язык: Английский
Процитировано
16
Industrial & Engineering Chemistry Research, Год журнала: 2025, Номер 64(4), С. 1907 - 1932
Опубликована: Янв. 14, 2025
Metal–organic frameworks (MOFs) have been shown to be great alternatives traditional porous materials in various chemical applications, and they very widely studied for biomedical applications the past decade specifically drug storage. After our review published 2011 [Keskin Kızılel, Ind. Eng. Chem. Res. 2011, 50 (4), 1799–1812, 10.1021/ie101312k], we witnessed a fast growth not only number variety of MOFs but also their usage across broad spectrum fields. With recent integration molecular modeling data science approaches experimental studies, significantly accelerated positioning them as pivotal components regenerative medicine, medical imaging, diagnostics. In this review, visited diverse considering computational efforts on storage delivery, bioimaging, biosensing. We focused underlying mechanisms governing interactions between biological systems discussed both opportunities challenges field highlight potential advanced therapeutics cancer neurological diseases.
Язык: Английский
Процитировано
1
ACS Applied Materials & Interfaces, Год журнала: 2024, Номер 16(37), С. 49640 - 49650
Опубликована: Сен. 6, 2024
Hydrophilic metal-organic frameworks (MOFs) are promising for solar steam generation from waste or seawater. In this study, we propose a MOF-based Janus membrane efficient generation. We selected MOF-303 its hydrophilic properties and 1D channels with 6.5 Å cavity diameter, making it an excellent water-absorbing layer. Characterization via Raman spectroscopy differential scanning calorimetry indicates that the nanoconfinement within can reduce water evaporation enthalpy, thereby boosting production efficiency. When deposited on various substrates, aimed to optimize enhanced performance by incorporating carbon black (CB), polydopamine (PDA), perfluoro-functionalized poly(3,4-ethylenedioxythiophene) (PEDOT-F), materials known their solar-to-thermal energy conversion capabilities. PEDOT-F, in particular, also served as hydrophobic layer, preventing salt recrystallization during seawater operation. Under one sun irradiation, flux deionized increased 0.31 0.79 kg h
Язык: Английский
Процитировано
6
Journal of environmental chemical engineering, Год журнала: 2023, Номер 11(6), С. 111419 - 111419
Опубликована: Ноя. 7, 2023
Язык: Английский
Процитировано
15
Journal of environmental chemical engineering, Год журнала: 2024, Номер 12(5), С. 113783 - 113783
Опубликована: Авг. 6, 2024
Язык: Английский
Процитировано
4
Advances in Colloid and Interface Science, Год журнала: 2025, Номер 340, С. 103444 - 103444
Опубликована: Фев. 20, 2025
Язык: Английский
Процитировано
0
Inorganic Chemistry Communications, Год журнала: 2025, Номер 176, С. 114194 - 114194
Опубликована: Фев. 25, 2025
Язык: Английский
Процитировано
0
Bulletin of the Korean Chemical Society, Год журнала: 2025, Номер unknown
Опубликована: Март 1, 2025
Abstract The conventional synthesis of metal‐organic framework (MOF) materials generates high amounts waste solvents, which are directly associated with human and environmental issues. Developing green affordable MOF is necessary since this strategy based on methods that prioritize sustainability minimize impact. In scenario, less toxic metals such as Zn, Zr, Al, Fe can be applied in addition to linkers from renewable sources. This review discusses eco‐friendly pathways, hydrothermal, mechanochemical, at room temperature, ionic liquid, resources. current methodologies specific low‐toxicity highlighted. Applications include water treatment, sensing, drug delivery, catalysis, gas storage, mentioned examined. Interestingly, developing low‐impact platforms for diverse applications a remarkable opportunity achieve sustainable future the quality planet.
Язык: Английский
Процитировано
0
Energy & Fuels, Год журнала: 2025, Номер unknown
Опубликована: Март 20, 2025
Automobile exhaust gases are major contributors to air pollution, leading severe challenges in environmental protection and public health. Metal–organic frameworks (MOFs) have emerged as promising adsorbents selectively capture gaseous pollutants due their highly tunable structures, large surface areas, abundant binding sites. This review delves into the diverse sites within MOFs for selective adsorption separation of automobile state-of-the-art technologies situ structural characterization. The roles metal centers, organic linkers, pore environments determining efficiency selectivity systematically analyzed. work provides foundation insights design construction next-generation MOF-based solid sorbents, representing innovative solutions automotive emission control promoting more sustainable transportation systems.
Язык: Английский
Процитировано
0
Polyhedron, Год журнала: 2025, Номер unknown, С. 117519 - 117519
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0