Transition-metal-free phosphorylation of polyfluoroarenes with P(O)H compounds DOI

Bingqian Sun,

Yongqiang Liang,

Meng-Ting Xiang

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2025, Номер 23(10), С. 2358 - 2361

Опубликована: Янв. 1, 2025

Herein, a base-promoted C-P(O) bond formation method has been developed for the phosphorylation of polyfluoroarenes through selective C-F cleavage. The high selectivity and mild, transition-metal-free conditions this underscore its potential sustainable synthesis applications. This expands scope polyfluoroarene functionalization, providing valuable tool incorporating phosphorus motifs in complex aromatic frameworks.

Язык: Английский

Transition-metal-free phosphorylation of polyfluoroarenes with P(O)H compounds DOI

Bingqian Sun,

Yongqiang Liang,

Meng-Ting Xiang

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2025, Номер 23(10), С. 2358 - 2361

Опубликована: Янв. 1, 2025

Herein, a base-promoted C-P(O) bond formation method has been developed for the phosphorylation of polyfluoroarenes through selective C-F cleavage. The high selectivity and mild, transition-metal-free conditions this underscore its potential sustainable synthesis applications. This expands scope polyfluoroarene functionalization, providing valuable tool incorporating phosphorus motifs in complex aromatic frameworks.

Язык: Английский

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