Frontiers of Chemical Science and Engineering, Год журнала: 2024, Номер 19(1)
Опубликована: Сен. 20, 2024
Язык: Английский
Frontiers of Chemical Science and Engineering, Год журнала: 2024, Номер 19(1)
Опубликована: Сен. 20, 2024
Язык: Английский
Chemical Engineering Journal, Год журнала: 2025, Номер 512, С. 162706 - 162706
Опубликована: Апрель 16, 2025
Язык: Английский
Процитировано
0Desalination, Год журнала: 2024, Номер unknown, С. 118334 - 118334
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
2Journal of Membrane Science, Год журнала: 2024, Номер unknown, С. 123568 - 123568
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
2Macromolecular Rapid Communications, Год журнала: 2024, Номер 45(21)
Опубликована: Авг. 14, 2024
Abstract ‘On‐water’ catalysis entails the significant enhancement of a chemical reaction by water, even when those reactions are known to be water‐sensitive. Here, findings about anionic ring opening polymerization epoxides at static interface between oil and alkaline water shared. Unexpectedly, high molar mass fractions observed with interfacial system presented herein, albeit very low conversions (< 5%). Styrene oxide, notably unreactive epoxide, is chosen as model compound investigate influence several parameters (i.e., pH, type initiator salt, time, area, solvent, shaking) on polymerization. Poly(styrene oxide) (PSO) an M n 5300 g mol −1 via MALDI‐ToF MS, species least 8000 . The feasibility expanding (cyclic) aliphatic aromatic epoxides, glycidyl ethers also explored. appears promote that position interface, in such way initiation propagation can occur. A mechanistic interpretation suggested. surprising results obtained this work urge revisit role ionic polymerizations.
Язык: Английский
Процитировано
1Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2024, Номер 705, С. 135713 - 135713
Опубликована: Ноя. 8, 2024
Язык: Английский
Процитировано
1Опубликована: Янв. 1, 2024
Download This Paper Open PDF in Browser Add to My Library Share: Permalink Using these links will ensure access this page indefinitely Copy URL DOI
Язык: Английский
Процитировано
0Soft Matter, Год журнала: 2024, Номер 20(34), С. 6822 - 6833
Опубликована: Янв. 1, 2024
Polymer association at liquid-liquid interfaces is a promising way to spontaneously obtain soft self-healing membranes. In the case of reversible bonding between two polymers, macromolecules are mobile everywhere within membrane and they can be absorbed into it both boundaries due binding other type. this work, we develop theoretical model growth based on these assumptions. The asymptotic dependence thickness time as
Язык: Английский
Процитировано
0Frontiers of Chemical Science and Engineering, Год журнала: 2024, Номер 19(1)
Опубликована: Сен. 20, 2024
Язык: Английский
Процитировано
0