Green Chemistry Tools in Mechanochemistry DOI

Andrea Casagrande,

Allan Niidu, Riina Aav

и другие.

Elsevier eBooks, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Язык: Английский

Intermediates in Mechanochemical Reactions DOI
Karen J. Ardila‐Fierro, José G. Hernández

Angewandte Chemie International Edition, Год журнала: 2024, Номер 63(14)

Опубликована: Янв. 5, 2024

Abstract Mechanochemical reactions offer methodological and environmental advantages for chemical synthesis, constantly attracting attention within the scientific community. Besides unmistakable sustainability advantages, conditions under which mechanochemical occur, namely solventless conditions, sometimes facilitate isolation of otherwise labile or inaccessible products. Despite these limited knowledge exists regarding mechanisms types intermediates involved. Nevertheless, in an expanding number cases, ex situ monitoring techniques have allowed observation, characterization, reaction transformations. In this Minireview, we present a series examples reactive been detected spanning organic, organometallic, inorganic, materials chemistry. Many were stabilized by non‐covalent interactions, played pivotal role guiding We believe that uncovering understanding such instances, growing mechanochemistry community could find novel opportunities catalysis discover new while achieving simplification design.

Язык: Английский

Процитировано

29

Building a cost-effective mechanochemical Raman system: improved spectral and time resolution for in situ reaction and rheology monitoring DOI Creative Commons
Goran Zgrablić, Ana Senkić,

Noa Vidović

и другие.

Physical Chemistry Chemical Physics, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

We present mcRS, a high-sensitivity free-space optics Raman system for in situ mechanochemical monitoring. It improves spectral and time resolution, costs five times less than commercial systems, uniquely enables simultaneous rheology

Язык: Английский

Процитировано

1

Protecting-group-free mechanosynthesis of amides from hydroxycarboxylic acids: application to the synthesis of imatinib DOI Creative Commons
Tatsiana Nikonovich, Tatsiana Jarg, Jevgenija Martõnova

и другие.

RSC Mechanochemistry, Год журнала: 2024, Номер 1(2), С. 189 - 195

Опубликована: Янв. 1, 2024

The mechanochemical protecting-group-free amidation of hydroxycarboxylic acids is presented. transformation applied to the synthesis imatinib via a two-fold C–N bond construction sequence that bypasses chlorinated genotoxic intermediate.

Язык: Английский

Процитировано

5

Moving Mechanochemistry Forward: Mechanochemistry and the non-covalent bond DOI Creative Commons
Adam A. L. Michalchuk∞, Tomislav Friščić

RSC Mechanochemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Adam Michalchuk and Tomislav Friščić outline the importance of research into non-covalent bonds their implications in mechanochemistry.

Язык: Английский

Процитировано

0

Intermediates in Mechanochemical Reactions DOI
Karen J. Ardila‐Fierro, José G. Hernández

Angewandte Chemie, Год журнала: 2024, Номер 136(14)

Опубликована: Янв. 5, 2024

Abstract Mechanochemical reactions offer methodological and environmental advantages for chemical synthesis, constantly attracting attention within the scientific community. Besides unmistakable sustainability advantages, conditions under which mechanochemical occur, namely solventless conditions, sometimes facilitate isolation of otherwise labile or inaccessible products. Despite these limited knowledge exists regarding mechanisms types intermediates involved. Nevertheless, in an expanding number cases, ex situ monitoring techniques have allowed observation, characterization, reaction transformations. In this Minireview, we present a series examples reactive been detected spanning organic, organometallic, inorganic, materials chemistry. Many were stabilized by non‐covalent interactions, played pivotal role guiding We believe that uncovering understanding such instances, growing mechanochemistry community could find novel opportunities catalysis discover new while achieving simplification design.

Язык: Английский

Процитировано

3

Comparison of traditional and mechanochemical production processes for nine active pharmaceutical ingredients (APIs) DOI Creative Commons
Emília Leitão

RSC Sustainability, Год журнала: 2024, Номер 2(12), С. 3655 - 3668

Опубликована: Янв. 1, 2024

The pharmaceutical industry plays a crucial role in enhancing life expectancy and the quality of life.

Язык: Английский

Процитировано

2

A novel polyetherimide hydrogel proton exchange membrane DOI
Yingnan Ma, Shaohua Tang,

Zugan Zou

и другие.

New Journal of Chemistry, Год журнала: 2024, Номер 48(21), С. 9414 - 9418

Опубликована: Янв. 1, 2024

This study reported a novel rapidly formed hydrogel membrane with polyetherimide as the backbone and polyethyleneimine crosslinker. The membranes exhibited excellent proton conductivity.

Язык: Английский

Процитировано

1

Green Chemistry Tools in Mechanochemistry DOI

Andrea Casagrande,

Allan Niidu, Riina Aav

и другие.

Elsevier eBooks, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0