Visible-light induced direct C(sp³)–H functionalization: recent advances and future prospects

Organic Chemistry Frontiers, Год журнала: 2024, Номер 11(18), С. 5278 - 5305

Опубликована: Янв. 1, 2024

This review summarizes the latest methodological advances in photocatalytic C(sp 3 )–H functionalization, with a particular emphasis on formation of C–P, C–B, C–S bonds, etc ., and some prominent efforts asymmetric C–H functionalization.

Язык: Английский

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Unleashing the potentiality of metals: synergistic catalysis with light and electricity

Organic Chemistry Frontiers, Год журнала: 2024, Номер 11(14), С. 4024 - 4040

Опубликована: Янв. 1, 2024

This review provides a comprehensive overview of metal catalysis in photo-electrochemical systems, discussing reaction mechanisms and offering prospects for this triadic catalytic mode.

Язык: Английский

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Photoinduced decatungstate-catalyzed C(sp³)–H thioetherification by sulfinate salts

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(17), С. 3420 - 3424

Опубликована: Янв. 1, 2024

A visible light photoinduced decatungstate-catalyzed C(sp 3 )–H thioetherification of hydrocarbons by sodium sulfite is herein reported.

Язык: Английский

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CO‐Boosted Protocol for the Photocatalytic C−H Thiolation of Aldehydes Using Phenylthiobenzenesulfonate

European Journal of Organic Chemistry, Год журнала: 2024, Номер 27(28)

Опубликована: Март 13, 2024

Abstract The formyl C−H thiolation of aldehydes using thiosulfonates and the decatungstate anion as a photocatalyst is reported. Using this photocatalytic protocol together with CO atmosphere, both aromatic aliphatic thioesters can be synthesized in good yields. transformation consists cascade double S H 2 reactions, HAT an ArS group transfer. atmosphere effectively limits extent decarbonylation acyl radicals that are generated reaction.

Язык: Английский

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Visible-Light-Mediated Azidation of α-Diazoesters with TMSN₃ via Direct Photoexcitation and S_H2 Mechanism

The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(16), С. 11707 - 11715

Опубликована: Июль 30, 2024

A visible light-mediated azidation of α-diazoesters with TMSN

Язык: Английский

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Nickel(II)‐Catalyzed Reductive Coupling of Xanthate Esters with Sulfur‐Containing and Selenium‐Containing Compounds: Synthesis of Unsymmetric Sulfides and Selenides

Chinese Journal of Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Июнь 3, 2024

Comprehensive Summary Unsymmetric sulfides and selenides have great applications in the pharmaceutical field. Herein, we describe reductive coupling reaction of xanthate esters with sulfur‐containing selenium‐containing compounds (thio(seleno)sulfonates disulfides(selenides)) under nickel‐catalyzed condition. It provides a mild effective method for synthesis unsymmetric which has advantages conditions, high yields wide range substrates.

Язык: Английский

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Visible-light Induced Decarboxylative Coupling of Phenoxyacetic Acid with Disulfides: Synthesis of α-Arylthioanisole Derivatives

Chemical Communications, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Photoredox-catalyzed cross-coupling reaction is an efficient strategy for the construction of organic molecules.

Язык: Английский

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Iodine/TBHP‐Promoted Cross Coupling of N‐Hydroxy Aryl Sulfonamides and Disulfides to Synthesize Unsymmetrical Thiosulfonates

ChemistrySelect, Год журнала: 2024, Номер 9(46)

Опубликована: Дек. 1, 2024

Abstract An efficient and novel method has been developed for the synthesis of structurally diverse unsymmetrical thiosulfonates via oxidative coupling reactions N ‐hydroxy aryl sulfonamides disulfides. The iodine TBHP system enables transformations to afford a variety with good high yields. Furthermore, large‐scale practical application access sulfonamide have investigated. Notably, present protocol offers easily accessible materials, wide range substrates, radical pathways, metal‐free conditions.

Язык: Английский

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Synthetic developments on the preparation of thioethers via photocatalysis

New Journal of Chemistry, Год журнала: 2024, Номер 49(3), С. 651 - 668

Опубликована: Дек. 10, 2024

Sulfide is a widely occurring natural product and pharmaceutically active compound. This review highlights the photochemically mediated thioether synthesis reactions, with emphasis on catalytic mechanism.

Язык: Английский

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