Опубликована: Янв. 1, 2023
Язык: Английский
Опубликована: Янв. 1, 2023
Язык: Английский
Chemistry of Materials, Год журнала: 2024, Номер 36(9), С. 4654 - 4663
Опубликована: Май 1, 2024
Materials emitting near-infrared (NIR) light play a crucial role in the development of phosphor-converted light-emitting diodes (pc-LEDs) for applications ranging from fundamental science like spectroscopic analysis to highly applied uses night vision and biological imaging. One class materials that has garnered significant interest these technical spaces is Cr3+-activated garnets due their high efficiency ability operate at relatively temperatures. However, limited emission beyond 800 nm impedes use as optimal blue LED-pumped NIR-emitting materials. In this study, we present new garnet-type NIR phosphor, Na2CaZr2Ge3O12:Cr3+, addresses challenge─the material exhibits long-wavelength (λem,max = 832 nm) good thermal quenching resistance while maintaining an excellent internal quantum (IQE 98%). These properties are attributed crystal environment reconstruction, where structure distortion coupled weak field, which uncommon most rigid phosphors. Furthermore, fabricated pc-LED devices using demonstrate superior performance compared with employing well-known efficient phosphors operating range. The source subsequently demonstrated spanning vision, bioimaging, nondestructive analysis. This study not only provides insights into luminescence garnet desirable but also highlights practical application
Язык: Английский
Процитировано
29ACS Applied Optical Materials, Год журнала: 2025, Номер unknown
Опубликована: Март 6, 2025
Язык: Английский
Процитировано
1Dalton Transactions, Год журнала: 2023, Номер 52(36), С. 12892 - 12898
Опубликована: Янв. 1, 2023
An efficient broadband NIR garnet-type Mg 3 Gd 2 Ge O 12 :Cr 3+ phosphor with relatively long emission wavelength was developed, which demonstrates an excellent performance in pc-LED applications.
Язык: Английский
Процитировано
16Laser & Photonics Review, Год журнала: 2024, Номер 18(8)
Опубликована: Март 24, 2024
Abstract Phosphor‐converted light‐emitting diodes (pc‐LEDs) are efficient and cost‐effective ultrabroadband light sources for miniaturizing various optical systems, but they exhibit poor performance due to the lack of near‐infrared (NIR) phosphors with a wide spectral coverage 700−1100 nm. Although germanate oxides promising class host materials Cr 3+ generate broadband NIR light, preferred formation [CrO 4 ] 4− high vapor pressure Ge element cause these activated suffer from low internal quantum efficiency (IQE) thermal stability. Here, highly (IQE > 90%) thermally stable emission in germinate garnet Ca 2 LuMgScGe 3 O 12 (CLMSG) obtained by exploiting two‐step sintering method achieve full reduction 4+ . Further, energy transfer Yb is leveraged significantly improve intensity CLMSG:Cr shortwave infrared range 900−1100 Finally, an pc‐LED conversion (21.5%@10 mA) power (116.4 mW@350 demonstrated verify strong capability , blue‐to‐NIR conversion. The results open up new ways realize NIR‐emitting materials.
Язык: Английский
Процитировано
5Chemical Physics, Год журнала: 2024, Номер 580, С. 112215 - 112215
Опубликована: Янв. 27, 2024
Язык: Английский
Процитировано
4Journal of Luminescence, Год журнала: 2023, Номер 263, С. 120139 - 120139
Опубликована: Авг. 16, 2023
Язык: Английский
Процитировано
9Inorganic Chemistry, Год журнала: 2024, Номер 63(38), С. 17418 - 17428
Опубликована: Сен. 4, 2024
Near-infrared phosphor-converted light emitting diodes (NIR pc-LEDs) are considered as desirable NIR sources to satisfy current needs owing their numerous remarkable features. Nevertheless, an essential component, previously reported phosphors with broadband emission often suffer from inferior efficiency or thermal stability, therefore restricting use and promotion. Herein, a novel Cr
Язык: Английский
Процитировано
3Science China Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 2, 2025
Язык: Английский
Процитировано
0Journal of Alloys and Compounds, Год журнала: 2025, Номер unknown, С. 179966 - 179966
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0Journal of Alloys and Compounds, Год журнала: 2025, Номер unknown, С. 181235 - 181235
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0