Heterobimetallic Cu(I)/Fe(Ii) Azomethine Bridged Coordination-Organo Metallic Hybrid Complexes: Synthesis, Luminescence, Electrochemical and Catalytic Properties DOI
S.S. Chavan, Ganesh B. Kumbhar

Опубликована: Янв. 1, 2024

Язык: Английский

Coordination complexes of Bipyridines (CCBs): Chemistry, bonding and applications DOI
Chandrabhan Verma, Ibrahim Y. Yaagoob,

Lipiar K.M.O. Goni

и другие.

Coordination Chemistry Reviews, Год журнала: 2025, Номер 529, С. 216433 - 216433

Опубликована: Янв. 13, 2025

Язык: Английский

Процитировано

1
Synthesis, Photophysical, Electrochemical, and Catalytic Properties of Heterobimetallic Azomethine-Bridged Cu(I)/Fe(Ii) Complexes Containing Chelating Phosphine Ligand DOI
Ganesh B. Kumbhar, S.S. Chavan

Опубликована: Янв. 1, 2025

A new series of hybrid Cu(I)/Fe(II) complexes with the formula [Cu(Fc-HC=NC11H11N2O)(dppe)]X (1b-4b) [where dppe = 1,2-bis(diphenylphosphino)ethane and X NO3− (1b), ClO4− (2b), BF4− (3b), PF6− (4b)] was synthesized by reacting Fc-HC=NC11H11N2O [Cu(MeCN)4]X in presence one equivalent dppe. The coordination chemistry these investigated, their structures were characterized using elemental analysis, FTIR, 1H NMR, 31P UV-visible spectroscopy, mass spectrometry. Thermal stability evaluated through thermogravimetric analysis (TGA), crystal structure representative complex 2b clarified X-ray powder diffraction. Electrochemical studies revealed quasireversible redox behaviour associated Cu(I)/Cu(II) Fe(II)/Fe(III) couples, which influenced chelating phosphine ligand. All exhibited red-shifted emission attributed to ligand-ligand charge transfer (LLCT), metal-ligand (MLCT), or both, varied significantly counter anion Catalytic activity tests for C-N coupling aryl amines halides showed that ancillary ligand superior performance compared those PPh3. Additionally, ions played a critical role determining yield products.

Язык: Английский

Процитировано

0
Synthesis, characterization, luminescence and catalytic properties of heterobimetallic quinoline based Cu(I)/Fe(II) hybrid complexes. DOI

Ganesh M. Kumbhar,

Ashwini Patil,

S.S. Chavan

и другие.

Journal of Organometallic Chemistry, Год журнала: 2025, Номер unknown, С. 123574 - 123574

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0
Synthesis, characterization and catalytic study of heterobimetallic Cu(I)/Fe(II) hybrid complexes for C–C and C–N coupling reactions DOI

Ganesh M. Kumbhar,

S.S. Chavan

Polyhedron, Год журнала: 2025, Номер unknown, С. 117521 - 117521

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Heterobimetallic Cu(I)/Fe(II) azomethine bridged coordination-organometallic hybrid complexes : Synthesis, luminescence, electro chemical and catalytic properties. DOI

Ganesh M. Kumbhar,

Ajit H. Deshmukh,

S.S. Chavan

и другие.

Journal of Organometallic Chemistry, Год журнала: 2024, Номер 1021, С. 123351 - 123351

Опубликована: Авг. 30, 2024

Язык: Английский

Процитировано

2
Heterobimetallic Cu(I)/Fe(Ii) Azomethine Bridged Coordination-Organo Metallic Hybrid Complexes: Synthesis, Luminescence, Electrochemical and Catalytic Properties DOI
S.S. Chavan, Ganesh B. Kumbhar

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0