Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 1, 2024
Abstract
Rechargeable
aqueous
zinc
batteries
(AZBs)
utilizing
water‐borne
electrolytes
are
intrinsically
safe
electrochemical
devices
that
promising
in
next‐generation
energy
storage.
Such
application
requires
adaptivity
to
global
climate,
especially
at
grid‐scale,
thus
their
stability
of
performance
varying
temperatures
is
critical.
Many
essential
properties
AZBs,
i.e.,
ion
transfer,
redox
kinetics,
etc.,
largely
governed
by
the
because
relatively
limited
stable
phase
temperature
water.
This
limitation
extremely
vital
cold
regions
since
charging
and
discharging
become
more
difficult
sub‐zero
range
due
water
freezing.
Despite
development
various
electrolyte
strategies
recent
years,
comprehensive
reviews
focusing
on
this
topic
remain
limited.
research
diverse
reasons
underneath
failure
AZBs
extreme
provides
a
thorough
analysis
possible
resolutions
from
an
perspective.
It
starts
with
challenges
faced
both
high
low
concerning
electrolytes.
Different
addressing
these
discussed,
providing
insights
into
under
conditions.
Finally,
review
concludes
summary
outlook
design
structure
for
all‐weather
integrating
innovative
non‐aqueous
battery
systems.
Advanced Energy Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Июль 14, 2024
Abstract
Lithium‐ion
batteries
(LIBs)
have
emerged
as
vital
elements
of
energy
storage
systems
permeating
every
facet
modern
living,
particularly
in
portable
electronic
devices
and
electric
vehicles.
However,
with
the
sustained
economic
social
development,
new‐generation
LIBs
high
density,
wide
operating
temperature
range,
fast
charge,
safety
are
eagerly
expected,
while
conventional
ethylene
carbonate
(EC)‐based
electrolytes
fail
to
satisfy
corresponding
requirements.
Comparatively,
ether‐based
electrolyte
fascinating
properties
recently
been
revived
fields,
many
advanced
exciting
performances
under
developed.
This
review
provides
an
extensive
overview
latest
breakthroughs
concerning
applied
intercalation
cathodes.
To
systematically
outline
progression
electrolytes,
this
is
categorized
from
perspective
anodes
follows:
i)
graphite
anode‐based
LIBs;
ii)
silicon
iii)
lithium
metal
LIBs.
ACS Energy Letters,
Год журнала:
2024,
Номер
9(6), С. 2960 - 2980
Опубликована: Май 28, 2024
Rechargeable
batteries
are
considered
to
be
one
of
the
most
feasible
solutions
energy
crisis
and
environmental
pollution.
As
a
bridge
between
cathode
anode
battery,
electrolytes
play
critical
roles
in
improving
battery
performance.
Recently,
high-entropy
(HEEs)
with
unique
properties
were
proposed.
Specifically,
HEEs
can
accelerate
ionic
diffusion
kinetics
promote
dissolution
salts
as
well
broaden
operating
temperature
batteries.
This
Review
provides
comprehensive
summary
application
working
mechanisms
rechargeable
First,
motivation,
history,
definitions
introduced.
Then,
enhancing
electrochemical
performance
liquid
solid-state
presented,
especially
conductivity
achieving
wide
range.
Finally,
current
issues
possible
future
directions
new
perspective
on
design
high-performance
electrolytes.
Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Июнь 10, 2024
Abstract
The
development
of
lithium–metal
batteries
(LMBs)
has
emerged
as
a
mainstream
approach
for
achieving
high‐energy‐density
energy
storage
devices.
stability
electrochemical
interfaces
plays
an
essential
role
in
realizing
stable
and
long‐life
LMBs.
Despite
extensive
comprehensive
research
on
the
lithium
anode
interface,
there
is
limited
focus
cathode
particularly
regarding
high‐voltage
transition
metal
oxide
materials.
In
this
review,
challenges
associated
with
developing
materials
are
first
discussed.
Characterization
techniques
understanding
composition
structure
cathode–electrolyte
interphase
(CEI)
then
introduced.
Subsequently,
recent
developments
electrolyte
design
interface
modification
constructing
CEI
summarized.
Finally,
perspectives
future
trends
This
review
can
offer
valuable
guidance
designing
CEI,
pushing
forward
Energy & Environmental Science,
Год журнала:
2024,
Номер
17(19), С. 7281 - 7293
Опубликована: Янв. 1, 2024
Ultrastable
(>3500
h)
electrolyte
at
high
current
density
by
high-entropy
solvation
for
AZIBs.
With
increasing
configuration
entropy,
O–H
bond
order
in
active
H
2
O
and
ionic
conductivity
are
increased,
realizing
highly
reversible
Zn
anode.
