Closing the Loop: Low‐Waste Phosphorus Functionalization Enabled by Simple Disulfides DOI Creative Commons
Thomas M. Horsley Downie, Ajdin Velić, Laís Vanessa Sousa Coelho

и другие.

ChemSusChem, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 11, 2024

Abstract Useful monophosphorus products are obtained from both white and red phosphorus via a simple strategy involving initial oxidation by aryl disulfides followed quenching with nucleophiles. Direct transformations of elemental usually very challenging, forcing chemists to instead rely on inefficient hazardous multi‐step methods. However, here they achieved using inexpensive easy‐to‐handle reagents, providing access diverse P−C, P−N P−O bonded in good yields. By isolating the thiolate byproducts these reactions, simple, closed loop can be that produces only minimal, benign waste byproducts, contrast other direct This even elaborated into true (electro)catalytic cycle, which is extremely rare field functionalization.

Язык: Английский

Closing the Loop: Low‐Waste Phosphorus Functionalization Enabled by Simple Disulfides DOI Creative Commons
Thomas M. Horsley Downie, Ajdin Velić, Laís Vanessa Sousa Coelho

и другие.

ChemSusChem, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 11, 2024

Abstract Useful monophosphorus products are obtained from both white and red phosphorus via a simple strategy involving initial oxidation by aryl disulfides followed quenching with nucleophiles. Direct transformations of elemental usually very challenging, forcing chemists to instead rely on inefficient hazardous multi‐step methods. However, here they achieved using inexpensive easy‐to‐handle reagents, providing access diverse P−C, P−N P−O bonded in good yields. By isolating the thiolate byproducts these reactions, simple, closed loop can be that produces only minimal, benign waste byproducts, contrast other direct This even elaborated into true (electro)catalytic cycle, which is extremely rare field functionalization.

Язык: Английский

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