Tools of Green Synthesis: Electrochemistry DOI
Elisabeth K. Oehl,

Marola S. Lenhard,

Siegfried R. Waldvogel

и другие.

Elsevier eBooks, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Язык: Английский

Peroxodicarbonate – A Renaissance of an Electrochemically Generated Green Oxidizer DOI Creative Commons
Theresa Rücker, Niclas Schupp, Fiona Sprang

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(56), С. 7136 - 7147

Опубликована: Янв. 1, 2024

Peroxodicarbonate, accessible from direct anodic conversion of alkali carbonates, has experienced a renaissance in the past two decades. An overview its history, synthesis, characteristics and reactivity is provided.

Язык: Английский

Процитировано

4
Pilot Scale Electrolysis of Peroxodicarbonate as an Oxidizer for Lignin Valorization DOI Creative Commons
Theresa Rücker, Torbjørn Pettersen,

Hannah Graute

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2024, Номер 12(30), С. 11283 - 11296

Опубликована: Июль 18, 2024

A pilot scale plant at Technology Readiness Level (TRL) 6 comprising an electrochemical ex-cell continuous production of sodium peroxodicarbonate and a thermal depolymerization plug flow reactor for kraft lignin conversion is established. Due to the labile nature "green" oxidizer peroxodicarbonate, special attention must be paid parameters in order optimize its use. simplified design model describing steady-state transient operations formulated finally validated against experimental data from electrolysis setup. Design trade-offs are visualized, their impact on specific energy consumption evaluated. The was operated 20-month period more than 1200 h on-stream. Optimized process conditions result vanillin yields 8 wt % thus prove successful scale-up.

Язык: Английский

Процитировано

4
Trendbericht: Organische Chemie 2025 DOI Open Access
Martin Breugst, Jennifer N. Andexer,

Lena Barra

и другие.

Nachrichten aus der Chemie, Год журнала: 2025, Номер 73(3), С. 40 - 70

Опубликована: Фев. 28, 2025

Abstract Highlights von November 2023 bis 2024: die erste Einelektron‐C–C‐σ‐Bindung und Anti‐Bredt‐Verbindung; gesättigte Heterocyclen elektrochemisch funktionalisieren; Ausrichten diskotischer Flüssigkristalle; enantioselektive Wagner‐Meerwein‐Umlagerung reiner Aliphaten; photokatalytisch Furanen zu Pyrrolen; mit Ammoniak primären Arylaminen; Metallschrott recyceln ionischen Flüssigkeiten; terminale Alkene Ni‐Katalysatoren zum (Z)‐ oder (E)‐Alken isomerisieren;neue Fungizide, Medikamente Alkaloide.

Процитировано

0
Electrohydrogenation of Benzonitrile into Benzylamine under Mild Aqueous Conditions DOI Creative Commons
José A. Solera‐Rojas,

Carles Forés,

Guillem Beltrán-Gargallo

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2025, Номер unknown

Опубликована: Июнь 5, 2025

Язык: Английский

Процитировано

0
Halogen-Free Bleaching of Shellac Using Electrochemically Generated Peroxodicarbonate DOI Creative Commons
Tomas Horsten, Siegfried R. Waldvogel

RSC Sustainability, Год журнала: 2024, Номер 2(7), С. 1963 - 1968

Опубликована: Янв. 1, 2024

A halogen-free bleaching of shellac was developed using electrochemically generated peroxodicarbonate with acetonitrile as an activator. reduced damage is obtained compared to previous reports.

Язык: Английский

Процитировано

1
Electrochemical Synthesis of Quinones and Hydroquinones DOI Creative Commons
Fiona Sprang, Siegfried R. Waldvogel

ACS electrochemistry., Год журнала: 2024, Номер unknown

Опубликована: Окт. 3, 2024

Язык: Английский

Процитировано

0
Tools of Green Synthesis: Electrochemistry DOI
Elisabeth K. Oehl,

Marola S. Lenhard,

Siegfried R. Waldvogel

и другие.

Elsevier eBooks, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0