Modified-liquid-liquid phase separation: A novel technique to synthesize 2-dimensional CuO nanosheets DOI Creative Commons

Abha Mahajan,

Ajay Piriya Vijaya Kumar Saroja, Sundara Ramaprabhu

и другие.

Research Square (Research Square), Год журнала: 2024, Номер unknown

Опубликована: Авг. 9, 2024

Abstract The 2-dimensional materials are seeing an upsurge in research and various applications. In this work, the growth of cupric oxide (CuO) nanostructures different morphologies is reported by employing modified-liquid-liquid phase separation (m-LLPS) technique. Here, two binary phases copper sulphate-polyethylene glycol (PEG) i.e. C&P sodium hydroxide-PEG N&P used tandem reduction salt employed. Sheet-like agglomerated could be restrained into nice flattened disks merely modifying interaction time. X-ray diffraction (XRD) for structural information, UV-Visible spectroscopy optical bandgap estimation, micro-Raman vibrational levels investigation, Fourier Transform Infrared (FTIR) as fingerprint bond/ compound formation have been flat-disk CuO sample was detection glucose. Limit limit quantification were estimated found to 4 mM 13 mM, respectively. mechanism modified-LLPS method leading oriented from disoriented discussed. By taking example, a very simple concept has demonstrated prepare materials.

Язык: Английский

Self-assembly of stabilized droplets from liquid–liquid phase separation for higher-order structures and functions DOI Creative Commons
Mehwish Naz,

Lin Zhang,

Chong Chen

и другие.

Communications Chemistry, Год журнала: 2024, Номер 7(1)

Опубликована: Апрель 9, 2024

Dynamic microscale droplets produced by liquid-liquid phase separation (LLPS) have emerged as appealing biomaterials due to their remarkable features. However, the instability of limits construction population-level structures with collective behaviors. Here we first provide a brief background in context materials properties. Subsequently, discuss current strategies for stabilizing including physical and chemical modulation. We also recent development LLPS various applications such synthetic cells biomedical materials. Finally, give insights on how stabilized can self-assemble into higher-order displaying coordinated functions fully exploit potentials bottom-up biology applications.

Язык: Английский

Процитировано

17
Modeling drop deformations and rheology of dilute to dense emulsions DOI Creative Commons
Rodrigo B. Rebouças,

Nadia N. Nikolova,

Vivek Sharma

и другие.

Current Opinion in Colloid & Interface Science, Год журнала: 2025, Номер unknown, С. 101904 - 101904

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1
Advancements in Aqueous Two-Phase Systems for Enzyme Extraction, Purification, and Biotransformation DOI Creative Commons

Nikša Bekavac,

Maja Benković, Tamara Jurina

и другие.

Molecules, Год журнала: 2024, Номер 29(16), С. 3776 - 3776

Опубликована: Авг. 9, 2024

In recent years, the increasing need for energy conservation and environmental protection has driven industries to explore more efficient sustainable processes. Liquid–liquid extraction (LLE) is a common method used in various sectors separating components of liquid mixtures. However, traditional use toxic solvents poses significant health risks, prompting shift toward green solvents. This review deals with principles, applications, advantages aqueous two-phase systems (ATPS) as an alternative conventional LLE. ATPS, which typically utilize water nontoxic components, offer benefits such high purity single-step biomolecule extraction. paper explores thermodynamic principles factors influencing enzyme partitioning, advancements field. Specific emphasis placed on ATPS extraction, showcasing its potential improving yields while minimizing impact. The also highlights role ionic liquids deep eutectic enhancing efficiency making them viable industrial applications. discussion extends challenges integrating into biotransformation processes, including stability process optimization. Through comprehensive analysis, this aims provide insights future prospects practices biotechnological

Язык: Английский

Процитировано

5
Towards electrospray-assisted production of lipid-based synthetic cell assemblies DOI Creative Commons
P. Vink, Lawrence W. Honaker, Siddharth Deshpande

и другие.

Soft Matter, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This study reports the development of an electrospray-based technique (ATLAES) using all-aqueous systems to form a rich variety microscopic vesicles, with nebulous smooth lipid coatings, providing new platform for engineering synthetic cells.

Язык: Английский

Процитировано

0
Carboxymethyl cellulose/alginate/chitosan-based polyelectrolyte complex hydrogel with irregularly shaped multi-metallic nanowires for efficient continuous-flow Cr(VI) remediation DOI

Astrini Pradyasti,

Myeong Joo Lee,

Hyeon Jeong Kim

и другие.

International Journal of Biological Macromolecules, Год журнала: 2025, Номер unknown, С. 142863 - 142863

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
Modified-liquid-liquid phase separation: a novel technique to synthesize 2-dimensional CuO nanosheets DOI

Abha Mahajan,

Ajay Piriya Vijaya Kumar Saroja, Sundara Ramaprabhu

и другие.

Journal of Sol-Gel Science and Technology, Год журнала: 2025, Номер unknown

Опубликована: Апрель 16, 2025

Процитировано

0
Quantitative turbidimetric characterization of stabilized complex coacervate dispersions DOI
Advait Holkar, Shang Gao,

Kathleen Elizabeth Villaseñor

и другие.

Soft Matter, Год журнала: 2024, Номер 20(26), С. 5060 - 5070

Опубликована: Янв. 1, 2024

The stabilization of complex coacervate microdroplets can be modulated by the concentrations cPE stabilizer and salt, enabling their various applications, such as bioreactors, drug delivery vehicles, encapsulants.

Язык: Английский

Процитировано

3
Affinity‐Controlled Partitioning of Biomolecules at Aqueous Interfaces and Their Bioanalytic Applications DOI Creative Commons
Yang Cao, Youchuang Chao,

Ho Cheung Shum

и другие.

Advanced Materials, Год журнала: 2024, Номер 36(44)

Опубликована: Авг. 22, 2024

Abstract All‐aqueous phase separation systems play essential roles in bioanalytical and biochemical applications. Compared to conventional oil organic solvent‐based systems, these are characterized by their rich bulk interfacial properties, offering superior biocompatibility. In particular, all‐aqueous facilitates the creation of compartments with specific physicochemical therefore largely enhances accessibility systems. addition, have diverse affinities, an important property known as partitioning, which can concentrate (bio)molecules toward distinct immiscible phases. This partitioning affinity imparts interfaces selective permeability, enabling controlled enrichment target (bio)molecules. review introduces basic principles applications partitioning‐induced phenomena a typical system, namely aqueous two‐phase (ATPSs); include chemical reactions, bioprinting, assembly, well bio‐sensing detection. The primary challenges associated designing several future directions also discussed, such stabilization interfaces, handling low‐volume samples, exploration suitable ATPSs compositions efficient protocol.

Язык: Английский

Процитировано

2
Coacervate Droplets as Biomimetic Models for Designing Cell‐Like Microreactors DOI Creative Commons
Tsvetomir Ivanov, Thao P. Doan‐Nguyen,

Mohammed A. Belahouane

и другие.

Macromolecular Rapid Communications, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 26, 2024

Abstract Coacervates are versatile compartments formed by liquid–liquid phase separation. Their dynamic behavior and molecularly crowded microenvironment make them ideal materials for creating cell‐like systems such as synthetic cells microreactors. Recently, combinations of natural molecules have been exploited via simple or complex coacervation to create that can be used build hierarchical chemical with life‐like properties. This review highlights recent advances in the design coacervate their application biomimetic reactors cell mimicking systems. It first explores variety influence structure on controlled behavior. Then, applications coacervates reviewed, focusing how they microreactors through ability sequester provide a distinct regulatory reactions aqueous media.

Язык: Английский

Процитировано

2
Predictive design of multimonomeric polyelectrolytes enables lung-specific gene delivery DOI
Jeffrey M. Ting, John D. Fisher,

Tyler Conyers

и другие.

Polymer Chemistry, Год журнала: 2024, Номер 15(26), С. 2627 - 2633

Опубликована: Янв. 1, 2024

With a discovery engine combining polymer chemistry, biology, and AI, lung-specific pDNA delivery is demonstrated with single multimonomeric polyelectrolyte.

Язык: Английский

Процитировано

1