Cited by PVPP-p-TSA catalyzed one-step synthesis of novel aryldiazenyl-2-hydroxybenzylidene-cyanoarylhydrazide analogs

Recent Application of Clay-Based Heterogeneous Catalyst in Organic Reactions DOI

Khadijeh Rabiei

Journal of Inorganic and Organometallic Polymers and Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 13, 2025

Язык: Английский

Процитировано

A sustainable protocol for selective alcohols oxidation using a novel iron-based metal organic framework (MOF-BASU1) DOI

Mahtab Yaghubzadeh,

Sedigheh Alavinia,

Ramin Ghorbani‐Vaghei

и другие.

RSC Advances, Год журнала: 2023, Номер 13(35), С. 24639 - 24648

Опубликована: Янв. 1, 2023

The selective oxidation of active and inactive alcohol substrates is a highly versatile conversion that poses challenge in controlling the functionality adjustments on MOFs. On other hand, it offers an attractive opportunity to expand their applications designing next generation catalysts with improved performance. Herein, novel iron-based MOF containing sulfonamide (MOF-BASU1) has been fabricated by reaction 1,3-benzene disulfonylchloride linker FeCl3·6H2O. Based results, surface area synthesized large, which highlights its unique catalytic activity. Optimum conditions were reached after 0.5-2 h, 15 mg loading under optimal conditions. Furthermore, turnover frequency was 18-77.6 h-1, comparable values previously reported for this process. Overall, high activity observed MOF-BASU1 might be because obtained Lewis acidic Fe nodes. revealed remarkable chemoselectivity aldehydes presence aliphatic alcohols. product yields, facile recovery nanocatalysts, short times, broad substrate range make process environmentally friendly, practical, economically justified.

Язык: Английский

Процитировано

Direct synthesis of anilines using copper immobilized on triazine-aminopyridine -modified MIL-101(Cr) MOF DOI