DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction

RSC Advances, Год журнала: 2024, Номер 14(48), С. 35475 - 35489

Опубликована: Янв. 1, 2024

The mechanism and origin of stereoselectivity for the synthesis asymmetric organosilanes using NHC are theoretically investigated.

Язык: Английский

Mechanisms and Origins of Regio- and Stereoselectivities in NHC-Catalyzed [3 + 3] Annulation of α-Bromoenals and 5-Aminoisoxazoles: A DFT Study

The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(15), С. 10748 - 10759

Опубликована: Июль 12, 2024

Density functional theory (DFT) calculations were conducted to explore the mechanisms and origins of regio- stereoselectivities underlying [3 + 3] annulation reaction between α-bromoenals 5-aminoisoxazoles with

Язык: Английский