Rhodium(II)‐Catalyzed Denitrogenative Transformations of N‐Sulfonyl‐1,2,3‐triazoles

European Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Окт. 21, 2024

Abstract N ‐Sulfonyl‐1,2,3‐triazoles are valuable precursors for the generation of α‐imino carbene intermediates in presence metal catalysts, especially rhodium(II) complexes. Due to electrophilic and nucleophilic nitrogen, these reactive can easily be incorporated into many annulations, cycloadditions, C−H or O/N/S−H bond insertions functionalization reactions. A large number pharmaceutically important nitrogen‐based building blocks constructed via this direct atom‐economical strategy. In review, we have described transformations ‐sulfonyl‐1,2,3‐triazoles based on intermediates.

Язык: Английский

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Five-membered ring systems: With more than 1 N atom

Progress in heterocyclic chemistry, Год журнала: 2024, Номер unknown, С. 211 - 257

Опубликована: Янв. 1, 2024

Язык: Английский

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