Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(39), С. 26528 - 26535
Опубликована: Янв. 1, 2024
We
constructed
a
core–shell
heterostructure
FeMoS@CoFe
LDH
bifunctional
electrode
to
promote
large
current
density
water
splitting,
achieving
multifunctional
green
applications.
Advanced Energy Materials,
Год журнала:
2024,
Номер
14(45)
Опубликована: Окт. 28, 2024
Abstract
High‐current‐density
water
electrolysis
is
considered
a
promising
technology
for
industrial‐scale
green
hydrogen
production,
which
of
significant
value
to
energy
decarbonization
and
numerous
sustainable
industrial
applications.
To
date,
substantial
research
advancements
are
achieved
in
catalyst
design
laboratory‐based
electrolysis.
While
the
designed
catalysts
demonstrate
remarkable
performance
at
low
current
densities,
they
suffer
from
marked
deteriorations
both
activity
long‐term
stability
under
industrial‐level
high‐current‐density
operations.
provide
timely
assessment
that
helps
bridge
gap
between
laboratory‐scale
fundamental
practical
technology,
here
various
commercial
electrolyzers
first
systematically
analyzed,
then
key
parameters
including
work
temperature,
density,
lifetime
stacks,
cell
efficiency,
capital
cost
stacks
critically
evaluated.
In
addition,
impact
high
density
on
electrocatalytic
behavior
catalysts,
intrinsic
activity,
stability,
mass
transfer,
discussed
advance
design.
Therefore,
by
covering
range
critical
issues
material
principles
parameters,
future
directions
development
highly
efficient
low‐cost
presented
procedure
screening
laboratory‐designed
outlined.
Advanced Sustainable Systems,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 10, 2025
Abstract
Hydrogen
production
by
electrochemical
water
splitting
is
considered
to
be
a
key
strategic
energy
technology,
and
proton
exchange
membrane
electrolyzers
(PEMWEs)
anion
(AEMWEs)
are
ideal
technologies
for
green
hydrogen
in
recent
years.
However,
PEMWEs
AEMWEs
lack
low‐cost
high‐performance
acidic
oxygen
evolution
reaction
(OER)
alkaline
(HER)
electrocatalysts
respectively,
limiting
their
large‐scale
development.
Recently,
ruthenium
(Ru)‐based
have
received
lot
of
attention
because
activity
better
than
that
commercial
catalysts
price
more
affordable,
showing
great
potential
OER
HER.
there
still
obstacles
Ru‐based
practical
applications
industrial
electrolyzers,
regulatory
strategies
need
developed
further
optimize
its
performance.
Herein,
comprehensive
review
presented
concerning
it.
First,
fundamental
principles
focus
the
basic
content
application
discussed.
Then,
summarized,
providing
detailed
analysis
elucidate
mechanisms,
properties,
electrolyzers.
Finally,
outlooks
prospects
challenges
future
proposed.
Abstract
Hydrogen
evolution
reaction
(HER)
under
alkaline
conditions
is
determined
by
the
water
dissociation
process.
Strengthening
adsorption
ability
of
electrocatalyst
crucial
to
promoting
in
HER,
whereas
too‐intense
will
poison
active
sites.
Herein,
NiFeP
modulated
nonmetal
F
doping
for
an
efficient
and
durable
HER.
incorporation
(NiFePF)
tailors
electronic
structure
Ni,
Fe,
P,
optimizing
*
OH/
H
on
The
balanced
facilitates
hydrogen
NiFePF,
exhibiting
smaller
overpotential
233
mV
at
100
mA
cm
−2
.
Furthermore,
NiFePF
achieves
1
A
only
231
30
wt%
KOH.
desorption
OH
alleviates
poisoning
center,
limiting
surface
hydroxylation
a
few
nanometers.
This
enables
remain
stable
360
h,
demonstrating
its
commercial
potential.