Recent Progress in Metal-Catalyzed C(sp³)-P Bond Formation DOI
Jia‐Lin Tu, Zhengjia Shen, Binbin Huang

и другие.

Tetrahedron, Год журнала: 2024, Номер 168, С. 134352 - 134352

Опубликована: Ноя. 1, 2024

Язык: Английский

Palladium‐Catalyzed Carbonylation of ortho‐Alkenyl Iodobenzenes for the Construction of 3‐Arylindenones DOI Open Access
Min Qian, Lingyun Yao, Zhi Li

и другие.

Chinese Journal of Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Фев. 14, 2025

Comprehensive Summary We developed a novel Pd‐catalyzed carbonylation of ortho ‐alkenyl iodobenzenes with CO, affording diverse array 3‐arylindenones in good to excellent yields (up 94% yield). This methodology exhibits broad substrate scope and functional group compatibility. The synthetic utility was demonstrated by gram‐scale reaction, product derivatizations, the preparation an intermediate for PPARγ agonist.

Язык: Английский

Процитировано

1
Highly Stereoselective Synthesis of 1,3‐Enynes via Aryl to Vinyl 1,4‐Palladium Migration/Sonogashira Coupling Sequence DOI
Zhengyu Chen, Xiaoming Ji, Xue Wang

и другие.

ChemCatChem, Год журнала: 2024, Номер 16(16)

Опубликована: Апрель 12, 2024

Abstract Alkynylation of alkenyl bromoarenes via aryl to vinyl 1,4‐palladium migration/copper‐free Sonogashira coupling sequence has been developed. This approach provides a facile methodology for the highly stereoselective synthesis multi‐substituted 1,3‐enynes in good excellent yields and regioselectivities.

Язык: Английский

Процитировано

4
Palladium-catalyzed intermolecular formal [3+2] cyclization/C-H alkylation of polyfluoroarenes DOI
Zhongyao Jiang, Chenglin Liu,

Mingxia Wu

и другие.

Chemical Communications, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A sequential three-component intermolecular carbopalladation/Heck cyclization/intermolecular C–H bond functionalization for versatile alkylated polyfluoroarenes containing an indene skeleton is presented.

Язык: Английский

Процитировано

0
Stereoselective Construction of Trisubstituted 1,3‐Enynes <i>via</i> Aryl to Vinyl 1,4‐Palladium Migration DOI Open Access
Jie Lin, Juan Ma, Liandi Wang

и другие.

Advanced Synthesis & Catalysis, Год журнала: 2024, Номер 366(21), С. 4509 - 4514

Опубликована: Авг. 2, 2024

Abstract Palladium‐catalyzed stereoselective olefinic C−H alkynylation of gem ‐diarylsubstituted ethylenes with propargylic alcohols was achieved to access diverse unsymmetrical 1,3‐enynes. The regio‐ and stereoselectivities were established through a 1,4‐palladium migration from aryl vinyl in the presence 2‐FC 6 H 4 OH as additive. Mechanistic investigations suggest that cleavage bond might not be involved rate‐determining step catalytic process.

Язык: Английский

Процитировано

2
Recent Progress in Metal-Catalyzed C(sp³)-P Bond Formation DOI
Jia‐Lin Tu, Zhengjia Shen, Binbin Huang

и другие.

Tetrahedron, Год журнала: 2024, Номер 168, С. 134352 - 134352

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

2