DMSO/SOCl₂‐Mediated Synthesis of Thiomethylnaphthalenes from Propargyl Alcohols

Advanced Synthesis & Catalysis, Год журнала: 2024, Номер unknown

Опубликована: Окт. 9, 2024

Abstract Herein, we reported the straightforward synthesis of thiomethylnaphthalenes via reaction propargyl alcohols with dimethyl sulfoxide/thionyl chloride (DMSO/SOCl 2 ), which also provided easy access to deuterated thiomethyl and other thioalkyl scaffolds when sulfoxide dialkyl sulfoxides were used, respectively. In addition, group can be readily derivatized corresponding sulfoxide, sulfone, sulfoximine interesting photophysical properties.

Язык: Английский

Cobalt-Catalyzed Dithiolation of Unactivated Alkenes with Thiols: A Facile Access to Diverse Vicinal Dithioethers

Chemical Communications, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

A simple cobalt-catalytic aerobic approach for the direct dithiolation of unactivated alkenes with thiols has been established, enabling efficient access to symmetric and unsymmetric vicinal dithioethers under mild reaction conditions.

Язык: Английский