Chinese Chemical Letters, Год журнала: 2023, Номер 35(3), С. 109300 - 109300
Опубликована: Ноя. 15, 2023
Язык: Английский
Coordination Chemistry Reviews, Год журнала: 2025, Номер 540, С. 216770 - 216770
Опубликована: Май 7, 2025
Язык: Английский
Процитировано
0
European Journal of Medicinal Chemistry, Год журнала: 2025, Номер unknown, С. 117754 - 117754
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0
Polymers, Год журнала: 2023, Номер 15(23), С. 4543 - 4543
Опубликована: Ноя. 27, 2023
Supramolecular chemistry enables the manipulation of functional components on a molecular scale, facilitating "bottom-up" approach to govern sizes and structures supramolecular materials. Using dynamic non-covalent interactions, polymers can create materials with reversible degradable characteristics abilities self-heal respond external stimuli. Pillar[n]arene represents novel class macrocyclic hosts, emerging after cyclodextrins, crown ethers, calixarenes, cucurbiturils. Its significance lies in its distinctive structure, comparing an electron-rich cavity two finely adjustable rims, which has sparked considerable interest. Furthermore, straightforward synthesis, uncomplicated functionalization, remarkable properties pillar[n]arene based interactions make it excellent candidate for material construction, particularly generating interpenetrating polymers. Polymers resulting from involving find potential various applications, including fluorescence sensors, substance adsorption separation, catalysis, light-harvesting systems, artificial nanochannels, drug delivery. In this context, we provide overview these recent frontier research fields use pillar[n]arene-based polymers, serves as source inspiration creation innovative polymer derived derivatives.
Язык: Английский
Процитировано
7
ChemPlusChem, Год журнала: 2024, Номер 89(6)
Опубликована: Янв. 30, 2024
Abstract Over the past decades, supramolecular luminescent materials (SLMs) have attracted considerable attention due to their dynamic noncovalent interactions, versatile functions, and intriguing applications in many research fields. From construction application, great efforts progress been made color‐tunable SLMs recent years. In order realize multicolor luminescence, various design strategies proposed. Macrocyclic chemistry, one of brightest jewels field has played a crucial role stimuli‐responsive emission‐tunable SLMs. Moreover, flexible tunable conformation multiple complexation sites macrocyclic arenes (MAs) afford new opportunity create such smart materials. Inspired by our reported work on crystalline assemblies modulated naphth[4]arene, this Concept provides summary latest developments MA‐based SLMs, accompanied strategies. The aim is provide researchers with perspective construct fascinating functions.
Язык: Английский
Процитировано
2
Journal of Materials Chemistry C, Год журнала: 2024, Номер 12(29), С. 10759 - 10774
Опубликована: Янв. 1, 2024
This review introduces the response mechanism of photoresponsive lanthanide luminescent materials. In particular, various applications in actuators, photoswitches, intelligent anticounterfeiting, and theranostics are highlighted.
Язык: Английский
Процитировано
2
Dyes and Pigments, Год журнала: 2024, Номер 223, С. 111934 - 111934
Опубликована: Янв. 1, 2024
Язык: Английский
Процитировано
1
Deleted Journal, Год журнала: 2024, Номер unknown, С. 35 - 91
Опубликована: Янв. 1, 2024
In this chapter, we present combinations of lanthanide ions with organic photochromic units within molecular systems that exhibit either luminescence photoswitching or single-molecule magnet (SMM) behavior photoswitching. The common challenge for and SMM is to maximize the impact a ligand-based photoreaction on property mainly based f orbitals, which are known be inner orbitals quite insensitive their environment. Section 2, focus main families compounds used in literature 4f complexes magnetism control parameters characterize reaction. 3 outlines strategies towards switching covers successively red emitting europium(III), green terbium(III) NIR emitters such as ytterbium(III) neodymium(III). It also illustrates non-destructive readout well mechanistic aspects. Typical applications luminescent bar codes imaging tools discussed. 4 extensively lanthanide-based magnets, highlighting efficient isomerization at single-crystal state achieving improved "ON" state. scope review concerns discrete extended coordination compounds, including metal-organic frameworks (MOF), does not include hybrid organic/inorganic architectures. By focusing how reaction can affect complex, presenting together, reveal specificities each topic.
Язык: Английский
Процитировано
1
CrystEngComm, Год журнала: 2024, Номер 26(29), С. 3954 - 3963
Опубликована: Янв. 1, 2024
A supramolecular approach for emission control.
Язык: Английский
Процитировано
1
Chinese Chemical Letters, Год журнала: 2024, Номер unknown, С. 110600 - 110600
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
1
Polymer International, Год журнала: 2023, Номер 73(5), С. 359 - 367
Опубликована: Дек. 7, 2023
Abstract The derivatization of pillar[ n ]arenes is a prerequisite for endowing them with functions, as well enriching the application ]arene materials in advanced material science. Herein, we report self‐assembly amphiphilic rim‐differentiated pillar[5]arene ( H 1 ). One side composed hydrophilic poly(ethylene oxide) chains, benzene and azobenzene groups connected ether bonds, other ethoxy groups. In CHCl 3 solvent, amphiphile self‐assembled into spherical micelles, while 2 O/THF mixed solvent nanorod‐like assemblies. Interestingly, addition guest molecule tetraphenylethene hexanenitrile G ) to solution produces large sheet aggregates via strong π – stacking rod segments. reversible transformation between nanosheet assemblies host–guest complexes nanoparticles achieved by 1,4‐butylamine competitive molecules. Notably, worm‐like nanorod micelles were constructed triggered light irradiation, which can be used photosensitive erasable writing materials. © 2023 Society Industrial Chemistry.
Язык: Английский
Процитировано
2