Chiral Amplification and Regulation: Design and Applications of Circularly Polarized Luminescence‐Active Materials Derived From Macrocyclic Compounds DOI Creative Commons
Wei Zhang,

Mao‐Qin Liu,

Yang Luo

и другие.

Aggregate, Год журнала: 2025, Номер unknown

Опубликована: Май 9, 2025

ABSTRACT Chirality is a fundamental property in molecules and biological systems, characterized by asymmetric configurational features. Circularly polarized luminescence (CPL) materials have gained significant attention due to their unique optical activities, with applications 3D displays, chiral sensors, catalysis, more. Chiral transfer amplification typically involve the generation of chirality excited state, facilitated interactions like energy transfer, electron or induction. Supramolecular self‐assembly strategies, particularly macrocyclic compounds, enable linking achiral luminescent units through intermolecular interactions. Macrocyclic hosts—cyclodextrins, calix[ n ]arenes, pillar[ cyclophanes, cucurbit[ ]urils—are especially promising stable structures adjustable cavities for guest encapsulation. These compounds induce photophysical properties host–guest complexation, making them ideal constructing amplification, CPL‐active materials. This review summarizes advancements multicolor CPL materials, sensing, induction, separation, highlighting potential supramolecular material design. The challenges future directions this field are also discussed, aiming guide further research application systems.

Язык: Английский

A Portable Electrochemical Biosensor Based on an Amino-Modified Ionic Metal–Organic Framework for the One-Site Detection of Multiple Organophosphorus Pesticides DOI
Qi Wu, Yifei Wang, Linxia Wang

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown

Опубликована: Окт. 3, 2024

Constructing stable, portable sensors and revealing their mechanisms is challenging. Ion metal-organic frameworks (IMOFs) are poised to serve as highly effective electrochemical for detecting organophosphorus pesticides (OPs), leveraging unique charge properties. In this work, an amino-modified IMOF was constructed combined with near-field communication (NFC) technology develop a portable, touchless, battery-free biosensor

Язык: Английский

Процитировано

4
Homochiral versus Racemic 2D Covalent Organic Frameworks DOI Creative Commons

José del Refugio Monroy,

Tejas Deshpande,

Joël Schlecht

и другие.

Journal of the American Chemical Society, Год журнала: 2025, Номер unknown

Опубликована: Май 15, 2025

The synthesis of homochiral two-dimensional covalent organic frameworks (2D COFs) from chiral π-conjugated building blocks is challenging, as units often lead to misaligned stacking interactions. In this work, we introduce helical chirality into 2D COFs using configurationally stable enantiopure and racemic [5]helicenes linkers in the backbone [5]HeliCOFs powders films. Through condensation with 1,3,5-triformylbenzene (TFB) or 1,3,5-triformylphloroglucinol (TFP), our approach enables efficient formation a set [5]HeliCOFs. resulting carbon-based crystalline porous exhibit distinct structural features different properties between counterparts. Propagation leads observation advanced chiroptical far-red visible spectrum, along less compact structure compared frameworks. Homogeneous thin films disclosed photoluminescent arising controlled growth highly ordered lattices. present study offers insight general framework extends Liebisch-Wallach rule COFs.

Язык: Английский

Процитировано

0
Chiral Hydrogen‐Bonded Organic Frameworks: Design, Synthesis, and Applications† DOI
Jialin Cui,

Qingyan Pan,

Xiaotao Wang

и другие.

Chinese Journal of Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 12, 2025

Comprehensive Summary Chiral framework materials, such as chiral metal‐organic frameworks (MOFs) and covalent organic (COFs), have been extensively reported studied. However, research on hydrogen‐bonded (HOFs) is far behind. HOFs present a novel approach for creating thanks to their mild synthesis conditions, solution processability, ease of repair regeneration. This review provides comprehensive overview the design strategies HOFs, highlighting recent advancements exploring applications emerging materials. Key Scientists In 1990s, Wuest his collaborators advanced development HOF field through porous networks. 2011, Chen co‐workers one first examples microporous achieved permanent porosity. 2014, Ward developed series two‐dimensional guanidine‐sulfonate with tunable crystal structures, whose flexibility allowed them be used structural detection. Further, in 2015, Chen, Li constructed example derived from building block. 2017, Yuan, Wu, synthesized an ultrastable, easily regenerated molecular 2018, Cao, Liu crystalline, recyclable synergistic chemo photodynamic therapy. 2021, Zhang ethylene/ethane separation stable gating mechanism. 2022, Liu, innovative mechanochemical strategy synthesis. The story still unfolding.

Язык: Английский

Процитировано

0
Chiral Amplification and Regulation: Design and Applications of Circularly Polarized Luminescence‐Active Materials Derived From Macrocyclic Compounds DOI Creative Commons
Wei Zhang,

Mao‐Qin Liu,

Yang Luo

и другие.

Aggregate, Год журнала: 2025, Номер unknown

Опубликована: Май 9, 2025

ABSTRACT Chirality is a fundamental property in molecules and biological systems, characterized by asymmetric configurational features. Circularly polarized luminescence (CPL) materials have gained significant attention due to their unique optical activities, with applications 3D displays, chiral sensors, catalysis, more. Chiral transfer amplification typically involve the generation of chirality excited state, facilitated interactions like energy transfer, electron or induction. Supramolecular self‐assembly strategies, particularly macrocyclic compounds, enable linking achiral luminescent units through intermolecular interactions. Macrocyclic hosts—cyclodextrins, calix[ n ]arenes, pillar[ cyclophanes, cucurbit[ ]urils—are especially promising stable structures adjustable cavities for guest encapsulation. These compounds induce photophysical properties host–guest complexation, making them ideal constructing amplification, CPL‐active materials. This review summarizes advancements multicolor CPL materials, sensing, induction, separation, highlighting potential supramolecular material design. The challenges future directions this field are also discussed, aiming guide further research application systems.

Язык: Английский

Процитировано

0