Facile Generation of Trideuteromethyl Radical from Alkylsilyl Peroxide and Subsequent Functionalization DOI
Jiahao Liu,

J. Nie,

Zhe Wang

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2024, Номер 13(11)

Опубликована: Авг. 23, 2024

Abstract Cu‐ and Fe‐ catalyzed trideuteromethylation reactions using alkylsilyl peroxide as trideuteromethyl radical precursor are reported. The was synthesized from acetone‐d6 in a three‐step sequence, the with various coupling partners afforded efficiently corresponding N−CD 3 , O−CD C−CD bond formation products. heptadeuteriopropylation prepared butyric acid‐d7 is also described.

Язык: Английский

Three-Component Reaction of Cyclopropanols, DABSO, and N-(Sulfonyl)acrylamides: Preparation of Sulfone-Bridged 1,7-Dicarbonyl Compounds DOI
Fei Chen, Li Xiao,

Ke-Ying Liu

и другие.

Organic Letters, Год журнала: 2024, Номер 26(34), С. 7170 - 7175

Опубликована: Авг. 19, 2024

A cascade reaction of cyclopropyl alcohols, DABSO (1,4-diazoniabicyclo[2.2.2]octane-1,4-disulfinate), and N-(sulfonyl)acrylamides has been developed. This tandem process went through a cyclopropanol ring opening Michael addition sequence. The γ-keto sulfinate generated from the between serves as nucleophilic reagent, N-(sulfonyl)acrylamide is used acceptor. By utilizing this strategy, multitudinous sulfone-bridged 1,7-dicarbonyl compounds that contain both β-sulfonyl amide unit sulfone skeleton were conveniently synthesized.

Язык: Английский

Процитировано

4
Recent synthetic methodology advancements towards all-carbon quaternary center formation and applications DOI

Taotao Ling,

Jose M Garfias,

S. Lawson

и другие.

Tetrahedron, Год журнала: 2025, Номер 183, С. 134711 - 134711

Опубликована: Май 14, 2025

Язык: Английский

Процитировано

0
Carbon-Chain Elongation by Co-Catalyzed Selective C–C Bond Cleavage and Subsequent Silylperoxylation of Alkene Substrates DOI
Jia‐Hao Xie, Terumasa Kato, Keiji Maruoka

и другие.

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 14754 - 14761

Опубликована: Сен. 20, 2024

Язык: Английский

Процитировано

1
Facile Generation of Trideuteromethyl Radical from Alkylsilyl Peroxide and Subsequent Functionalization DOI
Jiahao Liu,

J. Nie,

Zhe Wang

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2024, Номер 13(11)

Опубликована: Авг. 23, 2024

Abstract Cu‐ and Fe‐ catalyzed trideuteromethylation reactions using alkylsilyl peroxide as trideuteromethyl radical precursor are reported. The was synthesized from acetone‐d6 in a three‐step sequence, the with various coupling partners afforded efficiently corresponding N−CD 3 , O−CD C−CD bond formation products. heptadeuteriopropylation prepared butyric acid‐d7 is also described.

Язык: Английский

Процитировано

0