Advanced Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 26, 2024
Abstract
Reticular
materials
rely
on
a
unique
building
concept
where
inorganic
and
organic
units
are
stitched
together
giving
access
to
an
almost
limitless
number
of
structured
ordered
porous
materials.
Given
the
versatility
chemical
elements,
underlying
nets,
topologies,
reticular
provide
platform
design
for
timely
technological
applications.
have
now
found
their
way
in
important
societal
applications,
like
carbon
capture
address
climate
change,
water
harvesting
extract
atmospheric
moisture
arid
environments,
clean
energy
Combining
predictions
from
computational
chemistry
with
advanced
experimental
characterization
synthesis
procedures
unlocks
strategy
synthesize
new
desired
properties
functions.
Within
this
review,
current
status
modeling
is
addressed
supplemented
topical
examples
highlighting
necessity
molecular
This
review
as
templated
study
starting
structure
realistic
material
towards
prediction
functions
At
end,
authors
perspective
past,
present
future
formulate
open
challenges
inspire
model
method
developments.
Advanced Functional Materials,
Год журнала:
2023,
Номер
34(11)
Опубликована: Ноя. 27, 2023
Abstract
Covalent
organic
frameworks
(COFs)
are
crystalline
porous
polymers
that
can
be
precisely
integrated
by
building
blocks
to
achieve
pre‐designed
composition,
components,
and
functions,
making
them
a
powerful
platform
for
the
development
of
molecular
devices
in
field
electrocatalysis.
The
precise
control
channel/dopant
positions
highly
ordered
network
structures
COFs
provide
an
ideal
material
system
applications
advanced
In
this
paper,
topological
structure
design
synthesis
methods
reviewed
detail,
their
principles
deeply
analyzed.
addition,
derivatives
electrocatalysis
systematically
summarized
optimization
strategies
proposed.
Finally,
application
prospects
challenges
may
encountered
future
prospected,
providing
helpful
guidance
research.
Green Chemistry,
Год журнала:
2024,
Номер
26(18), С. 9619 - 9651
Опубликована: Янв. 1, 2024
This
review
focuses
on
advances
in
covalent
organic
framework
(COF)
photocatalysts
for
cross-coupling
reactions,
which
provide
a
greener
catalytic
route
transformations.
Advanced Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 9, 2024
Abstract
The
global
energy
crisis
and
environmental
concerns
are
driving
research
into
renewable
sustainable
conversion
storage
technologies.
Solar
energy,
as
an
ideal
resource,
has
significant
potential
to
contribute
the
goal
of
net‐zero
carbon
emissions
if
effectively
harnessed
converted
a
reliable
storable
form
energy.
Photocatalysts
have
convert
sunlight
chemical
carriers.
In
this
respect,
covalent
organic
frameworks
(COFs)
shown
great
promise
due
their
tunable
structure
on
different
length
scales,
high
surface
areas,
beneficial
optical
properties
such
broad
visible
light
absorption.
This
review
offers
comprehensive
overview
key
developments
in
COF‐based
photocatalysts
for
various
applications,
including
water
splitting,
hydrogen
peroxide
generation,
transformations,
dioxide
nitrogen
reduction.
underlying
mechanisms,
essential
principles
material
design,
structure‐function
relationships
COFs
photocatalytic
applications
discussed.
challenges
faced
by
also
summarized
strategies
enhance
performance
explained,
improving
crystallinity,
regulating
molecular
structures,
tailoring
linkages,
incorporating
cocatalysts.
Finally,
critical
proposed
utilization
photocatalytically
generated
chemicals
value‐added
products.
Materials Horizons,
Год журнала:
2024,
Номер
unknown
Опубликована: Янв. 1, 2024
The
processing
of
conjugated
organic
materials
into
films,
nanoparticles,
and
nanofibers,
presents
significant
opportunities
to
increase
their
activity
for
photocatalytic
hydrogen
evolution
scaled-up
systems
real
world
applications.
