Highly Porous 3D Ni-MOFs as an Efficient and Enzyme-Mimic Electrochemical Sensing Platform for Glucose in Real Samples of Sweat and Saliva in Biomedical Applications DOI Creative Commons
Rajaji Pavadai,

Mani Arivazhagan,

Jaroon Jakmunee

и другие.

ACS Omega, Год журнала: 2024, Номер 10(1), С. 1610 - 1623

Опубликована: Дек. 27, 2024

Nickel-based metal–organic frameworks, denoted as three-dimensional nickel trimesic acid frameworks (3D Ni-TMAF), are gaining significant attention for their application in nonenzymatic glucose sensing due to unique properties. Ni-MOFs possess a high surface area, tunable pore structures, and excellent electrochemical activity, which makes them ideal facilitating electron transfer enhancing the catalytic oxidation of glucose. This research describes new enzyme-mimic biosensor biological solutions that utilizes 3D nanospheres Ni-TMAF created layer-by-layer on highly porous substrate. The based represent promising approach, leveraging properties provide efficient, stable, potentially more cost-effective alternatives traditional sensors. MOF is synthesized from (TMA) nitrate hexahydrate through solvothermal reaction process. resulting crystalline structure with large area numerous active sites toward indeed known electrocatalytic particularly context under alkaline conditions. centers facilitate efficient redox reactions, leading sensitivity 203.89 μA μM–1 cm–2 lower LOD 0.33 μM fast response time <3 s Their stability, cost-effectiveness, performance make material

Язык: Английский

A new approach to non-enzymatic glucose sensing with real blood sample analysis: Utilizing nickel-cobalt tungstate DOI

Rakesh Anandrao Mohite,

Sohel B. Shaikh, Satish B. Jadhav

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 158982 - 158982

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1

Modern screen-printed carbon electrodes modified with multilayered double transition metals carbides (MXenes) for Ascorbic Acid Detection in Urine and sweat samples DOI

Cittrarasu Vetrivel,

Mani Durai, Daochen Zhu

и другие.

Journal of Molecular Structure, Год журнала: 2025, Номер 1342, С. 142738 - 142738

Опубликована: Май 27, 2025

Язык: Английский

Процитировано

0

Recent advances and future perspectives in electrochemical sensing of biomarkers by using MOF- based electrode materials DOI Creative Commons

Mani Arivazhagan,

Samikannu Prabu,

Mari Elancheziyan

и другие.

Emergent Materials, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 28, 2024

Abstract Metal-organic frameworks (MOF) are an extraordinarily versatile class of porous nanostructured materials that have gained popularity in several scientific fields. Organic ligands coupled to the inorganic metal centers or clusters produce MOFs. This frontier review paper critically summarizes most recent developments MOF-based for electrochemical (EC) detection key biomarkers, including glucose, dopamine, lactic acid, L-tryptophan, uric and ascorbic acids, H 2 O , nicotine. Various techniques, such as cyclic voltammetry (CV), chronoamperometry, differential pulse (DPV) been employed enhance sensitivity specificity. EC sensing systems hold promise medical diagnostics, particularly diseases diabetes, neurodegenerative cardiovascular disorders, cancer. These sensors offer distinctive features like extensive specific surface area, tunable pore sizes, exceptional catalytic performance, abundant active sites, enabling sensitive, rapid, cost-effective biomarker detection. The construction different nanostructures, nanoparticles, nanorods, nanowires, three-dimensional networks, has further improved electro-catalytic efficiency materials. We also assess performance advanced MOF-derived sensor platforms, discuss future challenges potential improvements, enzyme-free clinical diagnostics. work underscores effective tools detecting a wide range compounds biomolecules relevant human health. Graphical abstract

Язык: Английский

Процитировано

2

Point-of-Care Detection of Carcinoembryonic Antigen (CEA) Using a Smartphone-Based, Label-Free Electrochemical Immunosensor with Multilayer CuONPs/CNTs/GO on a Disposable Screen-Printed Electrode DOI Creative Commons
Supada Khonyoung,

Praphatsorn Mangkronkaew,

Puttaporn Klayprasert

и другие.

Biosensors, Год журнала: 2024, Номер 14(12), С. 600 - 600

Опубликована: Дек. 7, 2024

In order to identify carcinoembryonic antigen (CEA) in serum samples, an innovative smartphone-based, label-free electrochemical immunosensor was created without the need for additional labels or markers. This technology presents a viable method on-site cancer diagnostics. The novel smartphone-integrated, immunosensing platform constructed by nanostructured materials that utilize layer-by-layer (LBL) assembly technique, allowing meticulous control over interface. Detection relies on direct interactions extra tagging agents, where ordered graphene oxide (GO), carbon nanotubes (CNTs), and copper nanoparticles (CuONPs) were sequentially deposited onto screen-printed electrode (SPCE), designated as CuONPs/CNTs/GO/SPCE. significantly amplifies signal, detection of low concentrations target molecules CEA. LBL approach enables precise construction multi-layered structures sensor surface, enhancing their activity optimizing performance CEA detection. These serve efficient carriers increase surface area, conductivity, structural support antibody loading, thus improving sensitivity this transducer is based decrease current response [Fe(CN)

Язык: Английский

Процитировано

0

Highly Porous 3D Ni-MOFs as an Efficient and Enzyme-Mimic Electrochemical Sensing Platform for Glucose in Real Samples of Sweat and Saliva in Biomedical Applications DOI Creative Commons
Rajaji Pavadai,

Mani Arivazhagan,

Jaroon Jakmunee

и другие.

ACS Omega, Год журнала: 2024, Номер 10(1), С. 1610 - 1623

Опубликована: Дек. 27, 2024

Nickel-based metal–organic frameworks, denoted as three-dimensional nickel trimesic acid frameworks (3D Ni-TMAF), are gaining significant attention for their application in nonenzymatic glucose sensing due to unique properties. Ni-MOFs possess a high surface area, tunable pore structures, and excellent electrochemical activity, which makes them ideal facilitating electron transfer enhancing the catalytic oxidation of glucose. This research describes new enzyme-mimic biosensor biological solutions that utilizes 3D nanospheres Ni-TMAF created layer-by-layer on highly porous substrate. The based represent promising approach, leveraging properties provide efficient, stable, potentially more cost-effective alternatives traditional sensors. MOF is synthesized from (TMA) nitrate hexahydrate through solvothermal reaction process. resulting crystalline structure with large area numerous active sites toward indeed known electrocatalytic particularly context under alkaline conditions. centers facilitate efficient redox reactions, leading sensitivity 203.89 μA μM–1 cm–2 lower LOD 0.33 μM fast response time <3 s Their stability, cost-effectiveness, performance make material

Язык: Английский

Процитировано

0