Advanced Microporous Framework Membranes for Sustainable Separation

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 24, 2025

Abstract Advancements in membrane‐based separation hinge on the design of materials that transcend conventional limitations. Microporous materials, including metal–organic frameworks (MOFs), covalent–organic (COFs), macrocycles, and porous organic cages (POCs) offer unprecedented control over pore architecture, chemical functionality, transport properties, making them promising candidates for next‐generation membrane technologies. The well‐defined tunable micropores provide a pathway to directly address permeability‐selectivity trade‐off inherent polymer membranes. Here, this review explores latest advancements these four representative microporous membranes, emphasizing their breakthroughs hydrocarbon separation, liquid‐phase molecular sieving, ion‐selective transport, particularly focusing structure‐performance relationships. While tailored structures enable exceptional performance, practical adoption requires overcoming hurdles scalability, durability, compatibility with industrial processes. By offering insights into structure optimization innovative strategies, provides roadmap advancing membranes from laboratory innovation real‐world implementation, ultimately supporting global sustainability goals through energy‐efficient

Язык: Английский

Smart membranes for separation and sensing

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

This review summarizes the advancements in smart membrane applications for sensing and separation, along with fabrication methods types of stimuli involved.

Язык: Английский