Homochiral layered indium phosphonates: solvent modulation of morphology and chiral discrimination adsorption
Qian Teng,
Song‐Song Bao,
Ran Gao
и другие.
Dalton Transactions,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
A
solvothermal
reaction
of
In(NO
3
)
and
R
-,
S
-pempH
2
in
isopropanol/water
solvent
results
compounds
-[In
(pempH)
(μ
-OH)
(H
O)
](NO
with
a
spiral
microflower
structure,
which
show
enantioselective
adsorption
behaviour.
Язык: Английский
Supremely high turnover numbers with a simple porphyrin photosensitizer: Kinetic and mechanistic insights into the oxidation of sulfides with singlet oxygen
Journal of Catalysis,
Год журнала:
2025,
Номер
unknown, С. 116008 - 116008
Опубликована: Фев. 1, 2025
Язык: Английский
Indium Imidazo[4,5,-b]porphyrins as Photocatalysts for Oxidation of Sulfides
Molecules,
Год журнала:
2025,
Номер
30(4), С. 864 - 864
Опубликована: Фев. 13, 2025
Over
the
past
two
decades,
application
of
photocatalytic
reactions
in
organic
synthesis
has
increased
remarkably.
Porphyrins,
renowned
for
their
exceptional
photophysical
properties,
photostability,
and
prevalence
natural
catalytic
processes,
are
attracting
significant
attention
as
promising
photocatalysts
proceeding
through
energy
transfer
one-electron
transfer.
In
this
work,
we
synthesized
indium(III)
complex
2-[4-(diethoxyphosphoryl)phenyl]-1H-imidazo[4,5-b]-5,10,15,20-tetramesitylporphyrin
(InTMPIP)
explored
its
a
photocatalyst
oxidation
sulfides
by
dioxygen
or
air.
Complex
InTMPIP
was
found
to
generate
singlet
oxygen
with
quantum
yield
0.92
(toluene)
enables
efficient
photooxidation
sulfoxides
"green"
acetonitrile/water
(4:1
v/v)
methanol/chloroform
(2:1
solvent
mixtures
almost
quantitative
yield.
Furthermore,
grafted
onto
hydrated
mesoporous
titania
materials
InTMPIP/TiO2-1
InTMPIP/TiO2-2
different
In/Ti
ratios
were
obtained
investigated.
The
composition
structure
studied
using
combination
elemental
analysis,
various
spectroscopic
methods,
gas
adsorption
measurements,
SEM
imaging.
Finally,
efficiency
aerobic
sulfides.
heterogenized
selective
under
conditions;
however,
it
is
prone
leaching
into
solution
when
irradiated
both
blue
red
LEDs.
Язык: Английский
Sought gold, found a diamond: Outstanding photocatalytic performance of porpholactones
Journal of Photochemistry and Photobiology A Chemistry,
Год журнала:
2025,
Номер
unknown, С. 116389 - 116389
Опубликована: Март 1, 2025
Язык: Английский
Self-assembly of azulene-based metallacycles for efficient sulfide photooxidation
Inorganic Chemistry Communications,
Год журнала:
2025,
Номер
unknown, С. 114407 - 114407
Опубликована: Март 1, 2025
Язык: Английский
Synthesis of Porphyrin(2.1.2.1) Pd(II) Complexes Embedded with Various π Units and Their Singlet Oxygen Generation Capacity
Dalton Transactions,
Год журнала:
2024,
Номер
53(34), С. 14433 - 14437
Опубликована: Янв. 1, 2024
Porphyrin(2.1.2.1)
Pd(
ii
)
complexes
embedded
with
various
π
units
have
been
synthesized
and
well
verified.
The
1
O
2
generation
study
indicated
that
porphyrin(2.1.2.1)
are
a
novel
series
of
porphyrinoid
photo
sensitizers.
Язык: Английский
Phenylphosphonic acid corroles: corroles that link, corroles that bind
Dalton Transactions,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 30, 2024
Thanks
to
the
presence
of
a
phosphonic
acid
group,
A
2
B-corroles
were
covalently
linked
Zr
clusters
PCN-222
MOF.
After
insertion
Co,
cobalt
corroles
are
able
bind
CO
with
high
selectivity
vs.
,
N
and
O
.
Язык: Английский