Phenylphosphonic acid corroles: corroles that link, corroles that bind DOI

Gaëlle Divoux,

Margerie Loze,

Yoann Rousselin

и другие.

Dalton Transactions, Год журнала: 2024, Номер unknown

Опубликована: Дек. 30, 2024

Thanks to the presence of a phosphonic acid group, A 2 B-corroles were covalently linked Zr clusters PCN-222 MOF. After insertion Co, cobalt corroles are able bind CO with high selectivity vs. , N and O .

Язык: Английский

Homochiral layered indium phosphonates: solvent modulation of morphology and chiral discrimination adsorption DOI

Qian Teng,

Song‐Song Bao,

Ran Gao

и другие.

Dalton Transactions, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A solvothermal reaction of In(NO 3 ) and R -, S -pempH 2 in isopropanol/water solvent results compounds -[In (pempH) (μ -OH) (H O) ](NO with a spiral microflower structure, which show enantioselective adsorption behaviour.

Язык: Английский

Процитировано

2
Supremely high turnover numbers with a simple porphyrin photosensitizer: Kinetic and mechanistic insights into the oxidation of sulfides with singlet oxygen DOI
Stepan M. Korobkov, Kirill P. Birin, А. Yu. Tsivadze

и другие.

Journal of Catalysis, Год журнала: 2025, Номер unknown, С. 116008 - 116008

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

2
Indium Imidazo[4,5,-b]porphyrins as Photocatalysts for Oxidation of Sulfides DOI Creative Commons
Inna A. Abdulaeva, Mikhail A. Filatov,

Azhar Kechiche

и другие.

Molecules, Год журнала: 2025, Номер 30(4), С. 864 - 864

Опубликована: Фев. 13, 2025

Over the past two decades, application of photocatalytic reactions in organic synthesis has increased remarkably. Porphyrins, renowned for their exceptional photophysical properties, photostability, and prevalence natural catalytic processes, are attracting significant attention as promising photocatalysts proceeding through energy transfer one-electron transfer. In this work, we synthesized indium(III) complex 2-[4-(diethoxyphosphoryl)phenyl]-1H-imidazo[4,5-b]-5,10,15,20-tetramesitylporphyrin (InTMPIP) explored its a photocatalyst oxidation sulfides by dioxygen or air. Complex InTMPIP was found to generate singlet oxygen with quantum yield 0.92 (toluene) enables efficient photooxidation sulfoxides "green" acetonitrile/water (4:1 v/v) methanol/chloroform (2:1 solvent mixtures almost quantitative yield. Furthermore, grafted onto hydrated mesoporous titania materials InTMPIP/TiO2-1 InTMPIP/TiO2-2 different In/Ti ratios were obtained investigated. The composition structure studied using combination elemental analysis, various spectroscopic methods, gas adsorption measurements, SEM imaging. Finally, efficiency aerobic sulfides. heterogenized selective under conditions; however, it is prone leaching into solution when irradiated both blue red LEDs.

Язык: Английский

Процитировано

1
Sought gold, found a diamond: Outstanding photocatalytic performance of porpholactones DOI

Alina D. Oparina,

Ekaterina S. Shremzer, Daria A. Polivanovskaia

и другие.

Journal of Photochemistry and Photobiology A Chemistry, Год журнала: 2025, Номер unknown, С. 116389 - 116389

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Self-assembly of azulene-based metallacycles for efficient sulfide photooxidation DOI
Ziyan Chen,

Longyi Ding,

Xin Huang

и другие.

Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 114407 - 114407

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Synthesis of Porphyrin(2.1.2.1) Pd(II) Complexes Embedded with Various π Units and Their Singlet Oxygen Generation Capacity DOI
Xiaojuan Lv, Feng Chen,

Mingbo Zhou

и другие.

Dalton Transactions, Год журнала: 2024, Номер 53(34), С. 14433 - 14437

Опубликована: Янв. 1, 2024

Porphyrin(2.1.2.1) Pd( ii ) complexes embedded with various π units have been synthesized and well verified. The 1 O 2 generation study indicated that porphyrin(2.1.2.1) are a novel series of porphyrinoid photo sensitizers.

Язык: Английский

Процитировано

2
Phenylphosphonic acid corroles: corroles that link, corroles that bind DOI

Gaëlle Divoux,

Margerie Loze,

Yoann Rousselin

и другие.

Dalton Transactions, Год журнала: 2024, Номер unknown

Опубликована: Дек. 30, 2024

Thanks to the presence of a phosphonic acid group, A 2 B-corroles were covalently linked Zr clusters PCN-222 MOF. After insertion Co, cobalt corroles are able bind CO with high selectivity vs. , N and O .

Язык: Английский

Процитировано

0