Chemical Communications, Год журнала: 2024, Номер unknown
Опубликована: Янв. 1, 2024
Recent advances in the development of multiple classes materials applied to buried interface engineering for highly efficient and stable perovskite solar cells, including organic, inorganic, polymeric materials.
Язык: Английский
Nano Energy, Год журнала: 2024, Номер unknown, С. 110406 - 110406
Опубликована: Окт. 1, 2024
Язык: Английский
Процитировано
4
Small, Год журнала: 2024, Номер unknown
Опубликована: Ноя. 17, 2024
Adjusting the hole transport layer (HTL) to optimize its interface with perovskite is crucial for minimizing recombination, enhancing carrier extraction, and achieving efficient stable inverted solar cells (PSCs). However, as a commonly used HTL, self-assemble (SAM) of [2-(3,6-dimethoxy-9H-carbazol-9-yl)ethyl] phosphonic acid (MeO-2PACz) tends form clusters micelles during deposition process, leading inadequate coverage ITO substrate. Here, Co-SAM strategy employed by incorporating 4-mercaptobenzoic (SBA) 4-trifluoromethyl benzoic (TBA) additives into MeO-2PACz fabricate Co-SAM-based HTL. The introduced additive can interact MeO-2PACz, facilitating cluster dispersion thereby enabling better on improved HTL coverage. Moreover, exhibits superior energy level alignment enhance interfacial contact improve extraction efficiency well promote growth bottom grains. As result, an impressive increase power conversion (PCE) from 21.34% 23.31% achieved in device based MeO-2PACz+TBA while maintaining ≈90% initial under continuous operation at 1-sun.
Язык: Английский
Процитировано
3
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 2, 2025
Abstract Interface engineering has emerged as an effective strategy for optimizing the charge carrier dynamics in perovskite solar cells, and design of modulators plays a crucial role improving interface effects. Here, halogenated ethylamine hydrochloride (XEA), such 2‐fluoroethylamine (FEA), 2‐chloroethylamine (CEA), or (EA), is incorporated into buried between layer (PVK) SnO 2 electron transport (ETL) to assist crystal growth, tune energy level passivate defects. Pre‐embedded XEA interacts with PbI form 2D mesophase. The mesophase assists growth orientation epitaxial perovskite, resulting uniform films larger grains higher densification, effectively reducing defects caused by excess at interface. NH 3 + cation X − anion ions on fill coordinate vacancies, passivating perovskite. Meanwhile, introduction adjusts match PVK/ETL, compensating loss Consequently, FEA‐modified devices exhibited power conversion efficiency 24.7%, featuring exceptionally high open‐circuit voltage 1.19 V remarkable stability.
Язык: Английский
Процитировано
0
Nano Energy, Год журнала: 2025, Номер unknown, С. 110652 - 110652
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0
Advanced Materials, Год журнала: 2025, Номер unknown
Опубликована: Март 10, 2025
Stability testing protocols from the International Summit on Organic and Hybrid Solar Cell (ISOS) are essential for standardizing studies photothermally operational stability of perovskite solar cells (PSCs). Under photothermal conditions, migration oxygen SnO2 layer induces cationic dehydrogenation at A-site perovskite, accelerating degradation to PbI2. This leads formation photoinduced I2 Pb0 defects, significantly compromising long-term stability. In this study, ordonezite (ZnSb2O6-x) as a multifunctional electron transport (ETL) that captures migrating atoms SnO2/perovskite interface is introduced, effectively preventing buried interface. Additionally, lattice match between ZnSb2O6-x facilitates well-ordered film growth. As result, PSCs featuring ETLs achieved high power conversion efficiency 25.02% retained 90.62% their initial performance after 1000 h under ISOS-D-2 protocol. Furthermore, devices demonstrated remarkable thermal stability, maintaining 83.69% original 800 maximum point tracking 85 °C, meeting stringent ISOS-L-2 protocol requirements.
Язык: Английский
Процитировано
0
ACS Applied Materials & Interfaces, Год журнала: 2025, Номер 17(19), С. 27651 - 27670
Опубликована: Май 2, 2025
Currently, the latest photovoltaic technology based on perovskite solar cells (PSCs) has attracted much attention due to low cost, exciting power conversion efficiency of over 26%, large scalability, and flexibility PSCs. During development course, optimization electron transport layer (ETL) plays an important role in boosting performance PSCs, where use modification SnO2 with high chemical stability, low-temperature processability, suitable energy band levels substantially are shown solve problems poor charge transport, crystallization, inferior stability at PSC interface. Herein, we dedicate ourselves providing a comprehensive review advanced ETL for realizing efficient The fundamental properties its key as PSCs summarized first. Then, typical preparation methods introduced, including routes physical routes. Sequentially, state-of-the-art strategies optimizing quality discussed, such defect regulation, self-assembled monolayer modification, double construction. Finally, shed some light existing challenges future research directions large-scale SnO2-based
Язык: Английский
Процитировано
0
Nano Energy, Год журнала: 2025, Номер unknown, С. 111145 - 111145
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0
ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown
Опубликована: Май 30, 2025
Cesium lead iodide perovskite (CsPbI3) is a class of promising photovoltaic materials while prone to undergo spontaneous transformation from the photoactive black phase nonphotoactive yellow under ambient conditions, posing significant challenge long-term applications. Herein, buried interface regulation strategy reported, where crystalline seeds containing bromide ions are formed on substrates through treatment with cesium prior growth CsPbI3. This results in initial construction thin CsPbI3-xBrx layer high lattice matching at interface, which enables subsequent highly oriented CsPbI3 perovskites that effectively enhances their stability. Furthermore, modified substrate reveals greater wettability, leading accelerated crystallization kinetics, reduced defect density, and favorable interfacial charge transfer. Consequently, corresponding device exhibits simultaneous promotion both photoelectric performance operational
Язык: Английский
Процитировано
0
Nano Energy, Год журнала: 2024, Номер unknown, С. 110310 - 110310
Опубликована: Сен. 1, 2024
Язык: Английский
Процитировано
2
Journal of Alloys and Compounds, Год журнала: 2024, Номер 1010, С. 177653 - 177653
Опубликована: Ноя. 19, 2024
Язык: Английский
Процитировано
2