Recent advance in Mn-based Li-rich cathode materials: Oxygen release mechanism and its solution strategies based on electronic structure perspective, spanning from commercial liquid batteries to all-solid-state batteries DOI Creative Commons
Ning Wang,

Jiaxuan Yin,

Haoran Li

и другие.

Next Materials, Год журнала: 2024, Номер 6, С. 100408 - 100408

Опубликована: Окт. 21, 2024

Язык: Английский

In2O3 modification mitigates Jahn-Teller effect in LiMn2O4 enhancing lithium extraction efficiency and stability DOI
Linlin Chen,

Linjing Fan,

Delin Lan

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159815 - 159815

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

6

Ductile Inorganic Solid Electrolytes for All-Solid-State Lithium Batteries DOI
Tao Yu,

Yuankai Liu,

Haoyu Li

и другие.

Chemical Reviews, Год журнала: 2025, Номер unknown

Опубликована: Фев. 11, 2025

Solid electrolytes, as the core of all-solid-state batteries (ASSBs), play a crucial role in determining kinetics ion transport and interface compatibility with cathodes anodes, which can be subdivided into catholytes, bulk anolytes based on their functional characteristics. Among various inorganic solid ductile distinguished from rigid oxide exhibit excellent properties even under cold pressing, thus holding greater promise for industrialization. However, challenge lies finding electrolyte that simultaneously serve catholyte, electrolyte, anolyte. Fortunately, due to immobility combining multiple types electrolytes allows leveraging respective advantages. In this review, we discuss five sulfides, halides, nitrides, antiperovskite-type, complex hydrides, challenges superiorities these are also addressed. The impact pressure ASSBs has been systematically discussed. Furthermore, suitability anolyte is discussed characteristics physicochemical properties. This discussion aims deepen our understanding enabling us harness advantages develop practical, high-performance ASSBs.

Язык: Английский

Процитировано

1

Fundamentals, Status and Promise of Li‐Rich Layered Oxides for Energy‐Dense Li‐Ion Batteries DOI Open Access
Xiaoqiong Li,

Shunli Yu,

Jiming Peng

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Март 17, 2025

Abstract Li‐ion batteries (LIBs) are the dominant electrochemical energy storage devices in global society, which cathode materials key components. As a requirement for higher energy‐dense LIBs, Li‐rich layered oxides (LLO) cathodes that can provide specific capacity urgently needed. However, LLO still face several significant challenges before bringing these to market. In this Review, fundamental understanding of is described, with focus on physical structure‐electrochemical property relationships. Specifically, various strategies toward reversible anionic redox discussed, highlighting approaches take basic structure battery into account. addition, application all‐solid‐state and consider prospects assessed.

Язык: Английский

Процитировано

1

Hybrid heterojunction containing rich oxygen vacancies for suppressing lattice oxygen release of Li-rich Mn-based layered oxides cathodes DOI
Huai Chen,

Huachun Si,

Jun Ma

и другие.

Journal of Colloid and Interface Science, Год журнала: 2025, Номер unknown, С. 137392 - 137392

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

1

Construction of high chemical and electrochemical compatible interface of Li-rich Mn-based cathode for all-solid-state lithium batteries DOI
Zichen Zhang, J. Ping Liu, Nan Chen

и другие.

Journal of Energy Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

1

High-entropy perovskite fluoride ultrasmall nanoparticles embedded in carbon nanofibers enable accelerated redox kinetic for K storage DOI
Jiaying Liao,

Caoyang Shao,

Jingchen Han

и другие.

Energy & Environmental Science, Год журнала: 2024, Номер 17(19), С. 7362 - 7371

Опубликована: Янв. 1, 2024

Ultrasmall high-entropy perovskite fluoride nanoparticles impregnated in carbon nanofibers are prepared by electrospinning and pyrolysis. The unique structure prevents the conversion reaction shows a low-strain intercalation mechanism.

Язык: Английский

Процитировано

7

Promoting Layered Oxide Cathodes Based on Structural Reconstruction for Sodium‐Ion Batteries: Reversible Phase Transition, Stable Interface Regulation, and Multifunctional Intergrowth Structure DOI
Xinyu Liu, Shi Li,

Yan‐Fang Zhu

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер unknown

Опубликована: Окт. 21, 2024

Abstract Layered transition‐metal oxides (Na x TMO 2 ) are one of the most promising cathode materials for sodium‐ion batteries due to their high theoretical specific capacities, good conductivity, and environmental friendliness. However, several key scientific issues Na still persist in practical applications: i) complex phase transitions during charge/discharge process owing slip layer; ii) tendency interface react with electrolyte, resulting structure degradation, iii) reactions between active H O as well CO on exposure air environment form alkaline substances surface. To understand electrochemical storage mechanisms solve these problems, modification strategies have been reported recently, including bulk doping, concentration gradient design, regulation, intergrowth construction. This review focuses reversible transitions, stable multifunctional material from inside outside. The future research directions also analyzed, providing guidance development commercial layered next‐generation energy systems.

Язык: Английский

Процитировано

7

Recent Progress and Challenges of Li‐Rich Mn‐Based Cathode Materials for Solid‐State Lithium‐Ion Batteries DOI Open Access
Qing Huang, Jinquan Liu, Xinman Chen

и другие.

Advanced Materials, Год журнала: 2024, Номер unknown

Опубликована: Дек. 17, 2024

Li-rich Mn-based (LRM) cathode materials, characterized by their high specific capacity (>250 mAh g

Язык: Английский

Процитировано

5

Boosting Anionic Redox Reactions of Li‐Rich Cathodes through Lattice Oxygen and Li‐Ion Kinetics Modulation in Working All‐Solid‐State Batteries DOI Open Access
Shuo Sun, Chen‐Zi Zhao,

Guilin L. Liu

и другие.

Advanced Materials, Год журнала: 2024, Номер unknown

Опубликована: Дек. 18, 2024

The use of lithium-rich manganese-based oxides (LRMOs) as the cathode in all-solid-state batteries (ASSBs) holds great potential for realizing high energy density over 600 Wh kg

Язык: Английский

Процитировано

5

Cation migration of layered oxide cathodes for sodium-ion batteries: fundamental failure mechanisms and practical modulation strategies DOI Creative Commons

Zhuang‐Chun Jian,

Jun-Xu Guo,

Yi‐Feng Liu

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

We comprehensively review the research advances in cation migration of sodium layered oxides, systematically revealing fundamental mechanisms and practical modulation strategies for irreversible leading to battery failure.

Язык: Английский

Процитировано

4