
Next Materials, Год журнала: 2024, Номер 6, С. 100408 - 100408
Опубликована: Окт. 21, 2024
Язык: Английский
Next Materials, Год журнала: 2024, Номер 6, С. 100408 - 100408
Опубликована: Окт. 21, 2024
Язык: Английский
Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 159815 - 159815
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
6Chemical Reviews, Год журнала: 2025, Номер unknown
Опубликована: Фев. 11, 2025
Solid electrolytes, as the core of all-solid-state batteries (ASSBs), play a crucial role in determining kinetics ion transport and interface compatibility with cathodes anodes, which can be subdivided into catholytes, bulk anolytes based on their functional characteristics. Among various inorganic solid ductile distinguished from rigid oxide exhibit excellent properties even under cold pressing, thus holding greater promise for industrialization. However, challenge lies finding electrolyte that simultaneously serve catholyte, electrolyte, anolyte. Fortunately, due to immobility combining multiple types electrolytes allows leveraging respective advantages. In this review, we discuss five sulfides, halides, nitrides, antiperovskite-type, complex hydrides, challenges superiorities these are also addressed. The impact pressure ASSBs has been systematically discussed. Furthermore, suitability anolyte is discussed characteristics physicochemical properties. This discussion aims deepen our understanding enabling us harness advantages develop practical, high-performance ASSBs.
Язык: Английский
Процитировано
1Small, Год журнала: 2025, Номер unknown
Опубликована: Март 17, 2025
Abstract Li‐ion batteries (LIBs) are the dominant electrochemical energy storage devices in global society, which cathode materials key components. As a requirement for higher energy‐dense LIBs, Li‐rich layered oxides (LLO) cathodes that can provide specific capacity urgently needed. However, LLO still face several significant challenges before bringing these to market. In this Review, fundamental understanding of is described, with focus on physical structure‐electrochemical property relationships. Specifically, various strategies toward reversible anionic redox discussed, highlighting approaches take basic structure battery into account. addition, application all‐solid‐state and consider prospects assessed.
Язык: Английский
Процитировано
1Journal of Colloid and Interface Science, Год журнала: 2025, Номер unknown, С. 137392 - 137392
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
1Journal of Energy Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
1Energy & Environmental Science, Год журнала: 2024, Номер 17(19), С. 7362 - 7371
Опубликована: Янв. 1, 2024
Ultrasmall high-entropy perovskite fluoride nanoparticles impregnated in carbon nanofibers are prepared by electrospinning and pyrolysis. The unique structure prevents the conversion reaction shows a low-strain intercalation mechanism.
Язык: Английский
Процитировано
7Advanced Functional Materials, Год журнала: 2024, Номер unknown
Опубликована: Окт. 21, 2024
Abstract Layered transition‐metal oxides (Na x TMO 2 ) are one of the most promising cathode materials for sodium‐ion batteries due to their high theoretical specific capacities, good conductivity, and environmental friendliness. However, several key scientific issues Na still persist in practical applications: i) complex phase transitions during charge/discharge process owing slip layer; ii) tendency interface react with electrolyte, resulting structure degradation, iii) reactions between active H O as well CO on exposure air environment form alkaline substances surface. To understand electrochemical storage mechanisms solve these problems, modification strategies have been reported recently, including bulk doping, concentration gradient design, regulation, intergrowth construction. This review focuses reversible transitions, stable multifunctional material from inside outside. The future research directions also analyzed, providing guidance development commercial layered next‐generation energy systems.
Язык: Английский
Процитировано
7Advanced Materials, Год журнала: 2024, Номер unknown
Опубликована: Дек. 17, 2024
Li-rich Mn-based (LRM) cathode materials, characterized by their high specific capacity (>250 mAh g
Язык: Английский
Процитировано
5Advanced Materials, Год журнала: 2024, Номер unknown
Опубликована: Дек. 18, 2024
The use of lithium-rich manganese-based oxides (LRMOs) as the cathode in all-solid-state batteries (ASSBs) holds great potential for realizing high energy density over 600 Wh kg
Язык: Английский
Процитировано
5Chemical Science, Год журнала: 2024, Номер unknown
Опубликована: Янв. 1, 2024
We comprehensively review the research advances in cation migration of sodium layered oxides, systematically revealing fundamental mechanisms and practical modulation strategies for irreversible leading to battery failure.
Язык: Английский
Процитировано
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