ACS Catalysis, Год журнала: 2024, Номер unknown, С. 15088 - 15095
Опубликована: Сен. 29, 2024
Язык: Английский
ACS Catalysis, Год журнала: 2024, Номер unknown, С. 15088 - 15095
Опубликована: Сен. 29, 2024
Язык: Английский
ChemElectroChem, Год журнала: 2025, Номер unknown
Опубликована: Апрель 28, 2025
The activation of CO 2 is essential for efficient electrochemical conversion, yet its weak physisorption on pristine Cu surfaces severely hinders catalytic performance. To overcome this limitation, we designed stepped structures to create highly reactive sites enhanced adsorption and further doped the edges with 3 d transition metals (V, Cr, Mn, Fe, Co, Ni) improve reduction. Density functional theory calculations reveal that these dopants significantly reduce OCO angles elongate CO bonds, transforming from original linear configuration into a bent geometry at interface. Notably, dual‐V dual‐Fe doping demonstrates strong interaction , leading high degree activation. computational results demonstrate modifications enhance favor methane generation. This study provides valuable insights design advanced Cu‐based electrocatalysts selective activation, offering pathway toward sustainable utilization.
Язык: Английский
Процитировано
0Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер unknown, С. 124839 - 124839
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
3Journal of Material Science and Technology, Год журнала: 2024, Номер unknown
Опубликована: Сен. 1, 2024
Язык: Английский
Процитировано
2Chemical Society Reviews, Год журнала: 2024, Номер unknown
Опубликована: Дек. 4, 2024
This review explores the latest developments in CO 2 electroreduction based systems, including coupling reaction co-reduction cascade and integrated capture conversion systems.
Язык: Английский
Процитировано
2ACS Catalysis, Год журнала: 2024, Номер unknown, С. 15088 - 15095
Опубликована: Сен. 29, 2024
Язык: Английский
Процитировано
1